Method of using shaped compressed pellets in treating a well

• US 9,010,430 B2
• Filed: 07/19/2010
• Issued: 04/21/2015
• Est. Priority Date: 07/19/2010
• Status: Active Grant

• Current Assignee: Baker Hughes Holdings LLC (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Darby, John Gregory, Gupta, D. V. Satyanarayana, Shen, Dong
• Primary Examiner(s): DiTrani, Angela M
• Application Number:
  US12/839,047
• Publication Number:
  US 20120012326A1
• Time in Patent Office: 1,737 Days
• Field of Search: None
• US Class Current: 166/311
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: E21B 37/06 using chemical means for preventing or limiting , e.g. eliminating, the deposition of paraffins or like substances

Abstract

Shaped particulates which have been compressed from a composite of a well treatment agent and adsorbent in a matrix may be introduced into horizontal or deviated oil or gas wells. The well treatment agent of the shaped pellets may be used to prevent and/or control the formation of deposits in a production well.

Claims

1. A method of inhibiting or controlling the rate of release of a well treatment agent in a well during production of fluids from the well, the method comprising:

(a) introducing into the well a shaped pellet produced by compressing a mixture into a desired shape, the mixture comprising a (i) binder and (ii) a composite of a well treatment agent adsorbed onto a water-insoluble adsorbent wherein the surface area of the adsorbent of the well treating composite is between from about 1 m²/g to about 100 m²/g and wherein the binder holds the composite together during compression of the mixture; and

(b) releasing the adsorbed well treatment agent from the composite into produced fluids within the well.

2. The method of claim 1, wherein the amount of well treatment agent released from the composite into the well is from about 0.05 to about 5 weight percent based on the total weight of produced fluid.

3. The method of claim 2, wherein the shaped pellet is spherical.

4. The method of claim 3, wherein the shaped pellet is directly dropped into the well from the well head.

5. The method of claim 4, wherein the shaped pellet is directly dropped into the production tubing within the well.

6. The method of claim 4, wherein the shaped pellet is spherical and has a diameter between from about ½

inch to about 3 inches.

7. The method of claim 2, wherein the amount of well treatment agent released from the composite into the well is between from about 0.1 to about 2 weight percent based on the total weight of produced fluid.

8. The method of claim 1, wherein the specific gravity of the shaped pellet is between from about 1.1 to about 3.

9. The method of claim 1, wherein the well is a horizontal or deviated well.

10. The method of claim 9, wherein the well is a deviated well and wherein the deviations in the well are between from 45°

to about 89°

or wherein the deviations in the well are S-shaped.

11. The method of claim 1, wherein the shaped pellet further contains a weighting agent.

12. The method of claim 1, wherein the pellet is coated with a resin.

13. The method of claim 1, wherein the shaped pellet is introduced into the well in a receptacle and further wherein the receptacle is suspended in the well to a targeted area.

14. The method of claim 13, wherein the shaped pellet is cylindrically shaped.

15. The method of claim 13, wherein the receptacle is a wire basket.

16. The method of claim 13, wherein the receptacle is suspended at the bottom of the well by a wireline.

17. The method of claim 13, wherein the receptacle is hung to the bottom of a rod pump.

18. The method of claim 1, wherein the well treatment agent is selected from the group consisting of corrosion inhibitors, scale inhibitors, paraffin inhibitors, gas hydrate inhibitors, salt formation inhibitors, asphaltene dispersants, foaming agents, oxygen scavengers, biocides and surfactants.

19. The method of claim 18, wherein the well treatment agent is a scale inhibitor.

20. The method of claim 1, wherein the adsorbent is diatomaceous earth.

21. The method of claim 1, wherein the binder is an epoxy resin or a phenolic resin.

22. A method of inhibiting or controlling the formation of unwanted deposits in a deviated well by:

(a) introducing into tubing within the well a shaped pellet produced by compressing a mixture into a desired shape, the mixture comprising a binder and a composite of a well treatment agent adsorbed onto a water-insoluble adsorbent wherein the surface area of the adsorbent is between from about 1 m²/g to about 100 m²/g and further wherein the binder holds the composite together during compression of the mixture;

(b) flowing the shaped pellet over obstructions within the tubing and deviations in the well into a targeted area in the well where deposits are undesired and where hydrocarbons within the well are unable to flow; and

(c) continuously releasing from the shaped pellet the well treatment agent in the targeted area.

23. The method of claim 22, wherein the adsorbent is diatomaceous earth.

24. A method of inhibiting or controlling the formation of unwanted deposits in a producing well by:

(a) introducing into tubing within the well a receptacle containing a spherical pellet of a mixture of (i) a binder and (ii) a composite of a well treatment agent adsorbed onto a water-insoluble adsorbent wherein the surface area of the adsorbent is between from about 1 m²/g to about 100 m²/g, the spherical pellet having been prepared by compressing the mixture into a sphere wherein, during compressing the binder holds the composite together;

(b) lowering the receptacle to a targeted area in the well where deposits are undesired; and

(c) continuously releasing from the adsorbent the well treatment agent in the targeted area, wherein the amount of well treatment agent released from the adsorbent into the well is from about 0.05 to about 5 weight percent based on the total weight of produced fluid.

25. The method of claim 24, wherein the adsorbent is diatomaceous earth.