Solid fast draining/drying rinse aid for high total dissolved solid water conditions

• US 9,011,610 B2
• Filed: 06/22/2012
• Issued: 04/21/2015
• Est. Priority Date: 06/22/2012
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Kieffer, Janel Marie, Man, Victor Fuk-Pong, Hunter, Melissa
• Primary Examiner(s): Douyon, Lorna M
• Application Number:
  US13/530,152
• Publication Number:
  US 20130345111A1
• Time in Patent Office: 1,033 Days
• Field of Search: 510/224, 510/445, 510/495, 510/514, 134/25.2
• US Class Current: 134/25.2
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/722 Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups C11D1/721 takes precedence
• CPC Class Codes: C11D 1/825 Mixtures of compounds all of which are non-ionic
• CPC Class Codes: C11D 17/0047 Detergents in the form of bars or tablets
• CPC Class Codes: C11D 2111/18 Glass; Plastics
• CPC Class Codes: C11D 3/0021 Dye-stain or dye-transfer inhibiting compositions
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/3418 Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates

Abstract

The present invention is a solid rinse aid composition and methods of making and using the same. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes an short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.

Claims

1. A method for rinsing ware which comprises plasticware in a warewashing application comprising:

(a) providing a solid rinse aid composition which comprises

from about 65 wt % to about 85 wt % of one or more short chain alkyl benzene sulfonates and/or alkyl naphthalene sulfonates, wherein said one or more short chain alkyl benzene sulfonates have between 7 and 10 carbon atoms, and wherein said alkyl naphthalene sulfonates have between 10 and 18 carbon atoms and solidifies the rinse aid composition;

a surfactant system comprising at least three surfactants including one or more association disruption agents, from about 15 wt % to about 30 wt % of a sheeting agent; and

a defoamer;

(b) contacting the rinse aid composition with water to form a use solution; and

(c) applying the use solution to the ware which comprises plasticware to provide effective sheeting action to said ware.

2. The method of claim 1 wherein said use solution comprises 2,000 ppm or less active materials.

3. The method of claim 1 wherein said contacting is by spraying water on to the solid rinse aid.

4. The method of claim 3 wherein said solid rinse aid is dissolved a use solution by said spraying.

5. The method of claim 1 wherein the ware dries within about 30 to about 90 seconds after the aqueous solution is applied to the ware.

6. The method of claim 1 wherein said short chain alkyl benzene sulfonates and/or alkyl naphthalene sulfonates include at least one of the following sodium xylene sulfonate, sodium toluene sulfonate, sodium cumene sulfonate, potassium toluene sulfonate, ammonium xylene sulfonate, calcium xylene sulfonate, sodium alkyl naphthalene sulfonate, or sodium butylnaphthalene sulfonate.

7. The method of claim 1 wherein said short chain alkyl benzene sulfonates and/or alkyl naphthalene sulfonates is present in an amount of from about 70 wt % to about 80 wt % and comprises sodium xylene sulfonate;

and wherein said composition further comprises water and/or a preservative.

8. The method of claim 1 wherein the defoamer is present from about 1 wt % to about 20 wt %.

9. The method of claim 1 wherein said association disruption agent is an alcohol alkoxylate and the alkoxylate is selected from the group consisting of ethylene oxides, propylene oxides, butylene oxides, pentylene oxides, hexylene oxides, heptylene oxides, octylene oxides, nonylene oxides, decylene oxides and mixtures and derivatives thereof.

10. The method of claim 1 wherein said sheeting agent comprises one or more alcohol ethoxylates of Formula (I):

R—

O—

(CH₂CH₂O)_n—

H 

 

(I);

wherein R is a (C₁-C₁₂) alkyl group, and wherein n is an integer in the range of 1 to 100.

11. The method of claim 10, wherein n is an integer in the range of 15 to 30.

12. The method of claim 1 wherein the sheeting agent comprises two or more alcohol ethoxylates.

13. The method of claim 1, wherein the sheeting agent does not include an alcohol ethoxylate with an alkyl group that has more than 12 carbon atoms.

14. The method of claim 1 wherein said defoamer component comprises a block copolymer compound including one or more ethylene oxide groups.

15. The method of claim 1 wherein the solid rinse aid composition further comprises an additional solidification agent of polyethylene glycol.

16. The method of claim 1 wherein

the sheeting agent comprises at least one compound having the structure represented by formula I:

R—

O—

(CH₂CH₂O)_n—

H wherein R is a (C₁-C₁₂) alkyl group, and n is an integer in the range of 1 to 100;

the defoamer comprises a polyoxypropylene-polyoxyethylene block copolymer surfactant;

the association disruption agents comprise

a first association disruption agent which is an alcohol alkoxylate EO/BO surfactant;

a second association disruption agent which is a C₁₂-C₁₄ fatty alcohol EO/PO surfactant; and

the short chain alkyl benzene sulfonate and/or alkyl naphthalene sulfonate is selected from the group consisting of sodium xylene sulfonate, sodium toluene sulfonate, sodium cumene sulfonate, potassium toluene sulfonate, ammonium xylene sulfonate, calcium xylene sulfonate, sodium alkyl naphthalene sulfonate, sodium butylnaphthalene sulfonate, and mixtures thereof.

17. The method of claim 16 wherein said short chain alkyl benzene sulfonate and/or alkyl naphthalene sulfonate is present in an amount of about 70 wt % to about 80 wt % and comprises sodium xylene sulfonate.

18. The method of claim 16 wherein said solid is a cast solid, extruded solid or pressed solid composition.