Dry grind ethanol production process and system with front end milling method

• US 9,012,191 B2
• Filed: 03/23/2012
• Issued: 04/21/2015
• Est. Priority Date: 03/24/2011
• Status: Active Grant

• Current Assignee: Lee Tech LLC
• Original Assignee: Lee Tech LLC
• Inventors: Lee, Chie Ying
• Primary Examiner(s): Leith, Patricia A
• Assistant Examiner(s): Bowers, Erin M
• Application Number:
  US13/428,263
• Publication Number:
  US 20120244590A1
• Time in Patent Office: 1,124 Days
• Field of Search: None
• US Class Current: 435/161
• CPC Class Codes: C12M 21/12 for producing fuels or solvents C12M21/04 takes precedence; liquid carbonaceous fuels C10L1/00, solid fuels C10L5/00
• CPC Class Codes: C12M 45/02 by mechanical forces; Stirring; Trituration; Comminuting crushing, pulverizing, disintegrating in general B02C
• CPC Class Codes: C12M 45/04 Phase separators; Separation of non fermentable material; Fractionation
• CPC Class Codes: C12M 45/09 by enzymatic treatment
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 2203/00 Fermentation products obtained from optionally pretreated or hydrolyzed cellulosic or lignocellulosic material as the carbon source
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C12P 7/14 Multiple stages of fermentation; Multiple types of microorganisms or re-use of microorganisms
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A dry grind ethanol production process and system with front end milling method is provided for improving alcohol and/or by-product yields, such as oil and/or protein yields. In one example, the process includes grinding corn kernels into particles then mixing the corn particles with a liquid to produce a slurry including oil, protein, starch, fiber, germ, and grit. Thereafter, the slurry is subjected to a front end milling method, which includes separating the slurry into a solids portion, including fiber, grit, and germ, and a liquid portion, including oil, protein, and starch, then milling the separated solids portion to reduce the size of the germ and grit and release bound starch, oil, and protein from the solids portion. The starch is converted to sugar, and alcohol is produced therefrom then recovered. Also, the fiber can be separated and recovered. Oil and protein may be separated and recovered as well.

Claims

1. A dry grind ethanol production process, the process comprising:

(A) grinding dry corn kernels into corn flour;

(B) mixing the ground corn flour with a liquid to produce a slurry including free oil, protein, starch, and fiber, germ, and grit particles;

(C) subjecting the slurry of step (B) to the start of liquefaction, which includes adding an enzyme to the slurry;

(D) after step (C), separating the slurry, via particle sizes alone, into a solids portion, separately including the fiber, grit, and germ particles of the slurry, and a liquid portion, including the free oil, protein, and starch of the slurry;

(E) milling the separated solids portion of step (D) to reduce the size of the fiber, grit, and germ particles and release starch, oil, and protein therefrom;

(F) recombining at least the starch from the separated liquid portion of step (D) with at least the released starch of step (E) to form a second slurry;

(G) converting the starches in the second slurry of step (F) to sugar;

(H) producing alcohol from the sugar of step (G) via fermentation; and

(I) recovering the alcohol after fermentation.

2. The process of claim 1 further comprising separating and recovering the fiber from any of steps (A) through (I).

3. The process of claim 2, wherein the fiber of any of steps (A) through (G) is separated and recovered prior to step (H).

4. The process of claim 2 wherein separating remaining fiber after step (H) further comprises subjecting said remaining fiber to a caustic treatment and recovering the treated fiber.

5. The process of claim 1 further comprising, prior to producing alcohol from the sugar and recovering the alcohol, separating and recovering the free oil from the liquid portion of step (D).

6. The process of claim 5 wherein separating and recovering the free oil from the liquid portion of step (D) includes extracting the oil from the liquid portion of step (D) via solvent extraction.

7. The process of claim 1 wherein said process comprises counter-current washing.

8. The process of claim 1 wherein step (E) further comprises the following:

(E1) separating the milled solids portion of step (E) into a second solids portion, including the fiber, grit, and germ particles of the milled solids portion of step (E), and a second liquid portion, including the released oil, protein, and starch of the milled solids portion of step (E).

9. The process of claim 8 wherein step (E1) further comprises the following:

(E2) after separating the milled solids portion of step (E) into the second solids portion and the second liquid portion, further separating the second solids portion into an additional solids portion, including the fiber, grit, and germ particles of the second solids portion, and an additional liquid portion, including the released oil, protein, and starch of the second solids portion.

10. The process of claim 9 further comprising separating and recovering the released oil from the additional liquid portion prior to producing alcohol from the sugar and recovering the alcohol.

11. The process of claim 8 wherein step (E1) further comprises the following:

(E3) milling the second solids portion of step (E1) to reduce the size of the fiber, grit, and germ particles and release starch, oil, and protein therefrom.

12. The process of claim 11 wherein step (E3) further comprises the following:

(E4) separating the milled second solids portion of step (E3) into a third solids portion, including the fiber, grit, and germ particles of the milled second solids portion of step (E3), and a third liquid portion, including the released oil, protein, and starch of the milled second solids portion of step (E3).

13. The process of claim 12 wherein step (E4) further comprises the following:

(E5) milling the third solids portion of step (E4) to reduce the size of the fiber, grit, and germ particles and release starch, oil, and protein therefrom.

14. The process of claim 1 further comprising separating and recovering the protein from the liquid portion of step (D) and/or the protein from the milled solids portion of step (E).

15. The process of claim 14 wherein the protein from the liquid portion of step (D) and/or the protein from the milled solids portion of step (E) is separated and recovered after step (I).

17. The process of claim 1, wherein the alcohol is ethanol.

16. A dry grind ethanol production process, the process comprising:

(A) grinding dry corn kernels into corn flour;

(B) mixing the ground corn flour with a liquid to produce a slurry including free oil, protein, starch, and fiber, germ, and grit particles;

(C) subjecting the slurry of step (B) to the start of liquefaction, which includes adding an enzyme to the slurry;

(D) after step (C), separating the slurry, via particle sizes alone, into a solids portion, separately including the fiber, grit, and germ particles of the slurry, and a liquid portion, including the free oil, protein, and starch of the slurry;

(E) milling the separated solids portion of step (D) to reduce the size of the fiber, grit, and germ particles and release starch, oil, and protein therefrom;

(F) separating the milled solids portion of step (E) into a second solids portion, including the fiber, grit, and germ particles of the milled solids portion of step (E), and a second liquid portion, including the released oil, protein, and starch of the milled solids portion of step (E);

(G) recombining at least the starch from the separated liquid portion of step (D) with at least the released starch of step (E) to form a second slurry;

(H) converting the starches in the second slurry of step (G) to sugar;

(I) producing alcohol from the sugar of step (H) via fermentation;

(J) recovering the alcohol after fermentation;

(K) grinding a second portion of dry corn kernels into a second corn flour;

(L) mixing the second corn flour with the second liquid portion of step (F) to produce a third slurry including free oil, protein, starch, and fiber, germ, and grit particles;

(M) subjecting the third slurry of step (L) to the start of liquefaction, which includes adding an enzyme to the third slurry;

(N) after step (M), separating the third slurry, via particle sizes alone, into a third solids portion, separately including the fiber, grit, and germ particles of the third slurry, and a third liquid portion, including the free oil, protein, and starch of the third slurry;

(O) milling the separated third solids portion of step (N) to reduce the size of the fiber, grit, and germ particles and release starch, oil, and protein therefrom;

(P) recombining at least the starch from the separated third liquid portion of step (N) with at least the released starch of step (O) to form a fourth slurry;

(Q) converting the starches in the fourth slurry of step (P) to sugar;

(R) producing alcohol from the sugar of step (Q) via fermentation;

(S) recovering the alcohol after fermentation.

18. The process of claim 16, wherein the alcohol is ethanol.