Use of fluorescent inks for document authentication

• US 9,012,871 B2
• Filed: 05/01/2014
• Issued: 04/21/2015
• Est. Priority Date: 05/02/2013
• Status: Active Grant

• Current Assignee: Delphax Technologies Inc.
• Original Assignee: Delphax Technologies Inc.
• Inventors: Foyle, Victor
• Primary Examiner(s): TANINGCO, MARCUS H
• Application Number:
  US14/267,815
• Publication Number:
  US 20140326864A1
• Time in Patent Office: 355 Days
• Field of Search: 250/271
• US Class Current: 250/459.1
• CPC Class Codes: B41M 3/144 using fluorescent, luminescent or iridescent effects
• CPC Class Codes: B42D 25/378 Special inks
• CPC Class Codes: B42D 25/387 absorbing or reflecting ultraviolet light
• CPC Class Codes: C09D 11/328 characterised by dyes
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: D21H 21/40 Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper watermarking B41M3/10, D21F1/44; security printing B41M3/14; securities or banknotes characterised by colour effects B42D25/29, B42D25/30; testing paper currency or valuable papers for genuineness G07D7/00
• CPC Class Codes: G07D 7/1205 Testing spectral properties

Abstract

In a method for introducing an authentication print characteristic in a visible image printed on paper, a part of the image is printed with an ink having first and second component dyes. The first component is less fast than the second component in response to an applied activator. The first component is normally masked by the second component but applying an activator stimulates a bleed of the first component beyond the area of the image part to create a predetermined unmasked area of the fluorescent component. The invention extends to paper on which the authentication print characteristic has been printed and to a method of detecting a forged image by analyzing paper to detect such an image bleed.

Claims

1. A method for introducing a print characteristic in a visible image printed on paper, comprising printing a part of the image with an ink having first and second components, the first component being less fast than the second component in response to an applied activator, and the first component being a fluorescent component having its fluorescence substantially masked in the presence of the second component in the absence of the applied activator, and applying the activator to stimulate a bleed of the first component beyond the area of said part to create a unmasked area of the fluorescent component at the area of the bleed.

2. A method as claimed in claim 1, further comprising using a regulator to modulate the nature of the bleed.

3. A method as claimed in claim 2, the regulator being combined with the activator.

4. A method as claimed in claim 2, further comprising controlling application of the regulator and activator to define the extent of the bleed.

5. A method as claimed in claim 2, further comprising using a third component in the ink, the third component being less fast than the second component and differing in fastness from the first component in response to the applied activator, and the first and third components being fluorescent components having different color and having their fluorescence substantially masked in the presence of the second component in the absence of the applied activator, the ratio of the first and third components selected to determine a desired color characteristic of the bleed.

6. A method as claimed in claim 2, the activator being at least partly water.

7. A method as claimed in claim 2, the regulator being a cationic material.

8. A method as claimed in claim 2, the regulator being a primer applied to the paper before the ink is printed on the paper.

9. A method as claimed in claim 2, further comprising applying the activator after applying the ink.

10. A method as claimed in claim 9, the activator being applied as a predetermined pattern to render selected parts of the printed two component ink subject to the bleed.

11. A method as claimed in claim 1, further comprising applying the ink as a pattern of halftone dots.

12. A method as claimed in claim 1, the first component being one of acid red 52, sodium fluorescein, and rhodamine B.

13. A method as claimed in claim 1, the second component being one of an azo pyridine class dye, a double azo class dye, tetrasodium copper phthlalocyanine tetrasulfonate and (lithium(1+) ion pentasodium 4-[(E)-2-{4-[(E)-2-{1,8-dihydroxy-7-[(E)-2-(4-nitro-2-sulfonatophenyl)diazen-1-yl]-3,6-disulfonatonaphthalen-2-yl}diazen-1-yl]-3-sulfonatophenyl}diazen-1-yl]-5-oxo-1-(4-sulfonatophenyl)-4,5-dihydro-1H-pyrazole-3-carboxylate).

14. A method as claimed in claim 1 wherein the printed characteristic is an authentication artefact for authenticating the paper, the method further comprising analyzing a paper subsequently purported to be the authentic paper under black light to detect whether the expected fluorescent bleed is present.

15. A method of determining whether a forged image is present on paper comprising using black light to examine the paper to determine whether a fluorescent print characteristic is present in the image, the print characteristic, if the image is not a forgery, contained in a part of the image printed with an ink having first and second components, the first component being less fast than the second component in response to an applied activator, and the first component being a fluorescent component having its fluorescence substantially masked in the presence of the second component, an activator having previously been applied to stimulate a bleed of the first component beyond the area of said part to create the print characteristic as an unmasked area of the fluorescent component in the area of the bleed, the fluorescent print characteristic, if the image is a forgery, not being present in the image.

16. A method as claimed in claim 15, the method further comprising, if a fluorescent print characteristic is determined to be present on the paper, determining at least one property of the fluorescent print characteristic and comparing the at least one property against a predetermined at least one reference property.

17. Paper bearing an authentication print characteristic in a visible image printed on the paper, a part of the image being printed with an ink having first and second components, the first component being less fast than the second component in response to an applied activator, and the first component being a fluorescent component having its fluorescence substantially masked in the presence of the second component, an activator having been applied to stimulate a predetermined bleed of the first component beyond the area of said part to create an unmasked area of the fluorescent component in the area of the bleed.

18. Paper as claimed in claim 17, the regulator being a cationic material for binding to itself anions of the two ink components.

19. Paper as claimed in claim 18, the regulator binding the first component less strongly than the second component.

20. Paper as claimed in claim 18, the cationic material being one component of a primer.

21. Paper as claimed in claim 17, the ink having a third component which is less fast than the second component and differs in fastness from the first component in response to the applied activator, the ratio of the first and third components determining a desired color characteristic of the bleed.

22. Paper as claimed in claim 17, the activator being at least partly water, the water subject to evaporation from the paper.

23. Paper as claimed in claim 20, the ink printed over the primer.

24. Paper as claimed in claim 22, the water applied over and substantially evaporated from the ink.

25. Paper as claimed in claim 24, the water applied as a predetermined pattern.

26. Paper as claimed in claim 17, the ink applied as a pattern of halftone dots.

27. Paper as claimed in claim 17, the first component being one of acid red 52, sodium fluorescein, and rhodamine B.

28. Paper as claimed in claim 17, the second component being one of an azo pyridine class dye, a double azo class dye, tetrasodium copper phthlalocyanine tetrasulfonate and (lithium(1+) ion pentasodium 4-[(E)-2-{4-[(E)-2-{1,8-dihydroxy-7-[(E)-2-(4-nitro-2-sulfonatophenyl)diazen-1-yl]-3,6-disulfonatonaphthalen-2-yl}diazen-1-yl]-3-sulfonatophenyl}diazen-1-yl]-5-oxo-1-(4-sulfonatophenyl)-4,5-dihydro-1H-pyrazole-3-carboxylate).