Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment

• US 9,016,370 B2
• Filed: 04/06/2012
• Issued: 04/28/2015
• Est. Priority Date: 04/08/2011
• Status: Expired due to Fees

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Keedy, Charles Robert, Fowler, Thomas David, Daub, Gerald Jacob, Fresky, Mariela Gertrudis Araujo, Holman, Matthew Lee
• Primary Examiner(s): Bates, Zakiya W
• Application Number:
  US13/441,166
• Publication Number:
  US 20120255730A1
• Time in Patent Office: 1,117 Days
• US Class Current: 166/272.1
• CPC Class Codes: C10G 2300/4037 In-situ processes
• CPC Class Codes: C10G 9/24 by heating with electrical means
• CPC Class Codes: E21B 36/04 using electrical heaters
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection
• CPC Class Codes: E21B 43/2401 by means of electricity
• CPC Class Codes: E21B 43/28 Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent E21B43/241 takes precedence

Abstract

A method for treating a hydrocarbon containing layer in a subsurface formation is described. The method may include removing at most about 20% by weight of the nahcolite from one or more intervals in the hydrocarbon containing layer that include at least about 40% by weight nahcolite. Heat may be provided from a plurality of heaters to the hydrocarbon containing layer such that at least some hydrocarbons in the hydrocarbon containing layer are mobilized. At least some mobilized hydrocarbons may be produced through at least one production well.

Claims

1. A method for treating a hydrocarbon containing layer in a subsurface formation, comprising:

removing between about 0.5% and about 20% by weight of the nahcolite from one or more intervals in the hydrocarbon containing layer that include at least about 40% by weight nahcolite, wherein removing the nahcolite from the intervals provides an accommodation space for nahcolite remaining in the hydrocarbon containing layer to expand into when the layer is heated by heat from a plurality of heaters;

providing heat from the plurality of heaters to the hydrocarbon containing layer such that at least some hydrocarbons in the hydrocarbon containing layer are mobilized;

allowing nahcolite remaining in the hydrocarbon layer to expand into the accommodation space; and

producing at least some mobilized hydrocarbons through at least one production well.

2. The method of claim 1, further comprising removing at most about 10% by weight of the nahcolite from the one or more intervals.

3. The method of claim 1, further comprising removing at most about 5% by weight of the nahcolite from the one or more intervals.

4. The method of claim 1, further comprising removing at most about 1% by weight of the nahcolite from the one or more intervals.

5. The method of claim 1, further comprising removing between about 0.5% and about 5% by weight of the nahcolite from the one or more intervals.

6. The method of claim 1, wherein at least one of the nahcolite intervals includes at least about 50% by weight nahcolite.

7. The method of claim 1, wherein at least one of the nahcolite intervals includes at least about 60% by weight nahcolite.

8. The method of claim 1, wherein at least one of the nahcolite intervals includes between about 40% and about 80% by weight nahcolite.

9. The method of claim 1, wherein at least one of the nahcolite intervals is at most about 6 m thick.

10. The method of claim 1, wherein at least one of the nahcolite intervals is at most about 3 m thick.

11. The method of claim 1, wherein at least one of the nahcolite intervals is at most about 2 m thick.

12. The method of claim 1, further comprising removing the nahcolite by providing a fluid through one or more injection wells located in the intervals, and removing the nahcolite along with the fluid through one or more production wells located in the hydrocarbon containing layer.

13. The method of claim 12, wherein the fluid comprises heated water or steam.

14. The method of claim 12, further comprising converting at least one of the injection wells to a heater well.

15. The method of claim 12, further comprising converting at least one of the injection wells to a production well for producing hydrocarbons from the layer.

16. The method of claim 12, further comprising using at least one of the production wells for producing hydrocarbons from the layer.

17. The method of claim 1, further comprising providing heat from a plurality of heaters to the hydrocarbon containing layer such that at least some hydrocarbons in the layer are pyrolyzed.

18. The method of claim 17, further comprising producing at least some pyrolyzed hydrocarbons.

19. The method of claim 1, further comprising converting at least some of the removed nahcolite to sodium bicarbonate.

20. The method of claim 19, further comprising using at least some carbon dioxide produced from the formation to convert the nahcolite to sodium bicarbonate.

21. The method of claim 1, wherein the hydrocarbon containing layer comprises oil shale.

22. The method of claim 1, further comprising, following treatment of the hydrocarbon containing layer, storing at least some carbon dioxide, hydrogen sulfide, or sulfur in the hydrocarbon containing layer.

23. The method of claim 22, wherein at least some of the carbon dioxide, hydrogen sulfide, or sulfur is produced during treatment of the hydrocarbon containing layer.

24. The method of claim 1, further comprising, following treatment of the hydrocarbon containing layer, storing at least some carbon dioxide, hydrogen sulfide, or sulfur in the accommodation space created by removing nahcolite from one or more of the intervals.