System and method for dense phase sorbent injection

• US 9,017,452 B2
• Filed: 11/14/2012
• Issued: 04/28/2015
• Est. Priority Date: 11/14/2011
• Status: Active Grant

• Current Assignee: ARQ Solutions Incorporated
• Original Assignee: ADA-ES, Inc. (Advanced Emissions Solutions, Inc.)
• Inventors: Hanson, Ronald D., Martin, Cameron E., Wewer, Robert W., Boerema, Randall J., Derritt, Tyler J., McCann, Nicole M.
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US13/676,365
• Publication Number:
  US 20130139683A1
• Time in Patent Office: 895 Days
• Field of Search: 951/07, 110/203, 110/345, 423/210
• US Class Current: 95/107
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2259/128 Solid reactants
• CPC Class Codes: B01D 53/08 according to the "moving bed" method
• CPC Class Codes: B01D 53/40 Acidic components B01D53/44 takes precedence
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: B01D 53/90 Injecting reactants

Abstract

The present disclosure is directed to a dense-phase additive transportation system for additive injection into a contaminated gas stream.

Claims

1. A method, comprising:

determining, by a controller, that an amount of additive in a vessel has dropped below a determined level in response to introduction of the additive into a contaminated gas stream;

closing, by the controller, an outlet valve to terminate supply of the additive to one or more injectors positioned in the contaminated gas stream;

opening, by the controller, an inlet valve to cause the additive to be introduced into the vessel; and

when the additive amount is at least the determined level, closing, by the controller, the inlet valve and opening, by the controller, the outlet valve to supply the additive to the one or more injectors.

2. The method of claim 1, wherein the vessel comprises multiple vessels, each with separate outlet and inlet valves, and further comprising:

in response to the determining step, closing, by the controller, a pressurization valve and opening a depressurization valve to reduce an operating pressure of the vessel; and

when the additive amount is at least the determined level, closing, by the controller, the depressurization valve and opening the pressurization valve to pressurize the vessel.

3. The method of claim 1, wherein the controller determines at a first time that an additive amount in a first vessel has dropped below a determined level in response to introduction of additive into the contaminated gas stream and at a later second time that an additive amount in a second vessel has dropped below a determined level in response to introduction of additive into the contaminated gas stream and wherein the controller performs the steps of claim 1 at different times with respect to the first and second vessels.

4. The method of claim 1, wherein the determination is made by receiving a signal from a level switch and/or sensor, by passage of time, and/or by an operating pressure of the vessel falling below a selected pressure set point.

5. The method of claim 1, wherein the additive is a sorbent, wherein the vessel is a transport storage vessel, and further comprising:

transporting, by dense-phase pneumatic conveyance, an additive from the transport storage vessel to the one or more injectors positioned in the contaminated gas stream; and

injecting the additive into the contaminated gas stream to cause removal of a contaminant.

6. The method of claim 5, wherein the contaminated gas stream is derived from combustion of a high alkali, high iron, and/or high sulfur coal, wherein the contaminant is one or more of a sulfur oxide, a nitrogen oxide, hydrogen sulfide, hydrochloric acid, hydrofluoric acid, mercury, a halogen, a particulate, and a carbon oxide, and wherein the additive is a sorbent that is one or more of an alkaline material, powdered activated carbon, trona, a halogen, a halide, and a metal oxide.

7. The method of claim 1, wherein the vessel is one or more of a storage vessel and hopper and further comprising:

conveying, by dilute-phase pneumatic conveyance, additive from the one or more of a storage vessel and hopper to an injection transport vessel; and

transporting the additive from the injection transport vessel to the transport storage vessel.

8. The method of claim 7, wherein a superficial operating gas flow velocity during dilute-phase pneumatic conveyance is at least the saltation velocity and, during dense-phase pneumatic conveyance, is less than the saltation velocity.

9. A system for performing the steps of claim 5, wherein the vessel is a transport storage vessel and wherein the sorbent is an additive, the system comprising:

the controller;

the transport storage vessel to store an additive;

the one or more injectors configured to introduce the additive into a contaminated gas stream to cause removal of a contaminant; and

a conduit in fluid communication with the transport storage vessel and the one or more injectors and configured to transport, by dense-phase pneumatic conveyance, the additive from the transport storage vessel to the one or more injectors for additive introduction into the contaminated gas stream.

10. The system of claim 9, further comprising:

one or more storage vessels for longer term storage of the additive;

a first feeder for transporting the additive from the one or more storage vessels into a hopper; and

a second feeder for transporting the additive from the hopper to a conduit for dilute-phase pneumatic conveyance of the additive to an injection storage hopper.

11. The system of claim 10, further comprising:

an isolation valve to enable and disable supply of additive to the injection storage hopper;

a first discharge valve to enable and disable supply of additive, via the conduit, to the transport storage vessel;

a bypass line to direct additive around the discharge valve and to the injection transport vessel; and

a second discharge valve to enable and disable supply of additive, via the bypass line, to the injection transport vessel.

12. The system of claim 11, further comprising:

the inlet valve, in fluid communication with the injection storage vessel, to enable and disable supply of additive to the transport storage vessel;

a vent line to depressurize the transport storage vessel;

a depressurization valve in fluid communication with the vent line to enable and disable depressurization of the transport storage vessel;

a pressurization line to pressurize the transport storage vessel;

a pressurization valve in fluid communication with the vent line to enable and disable pressurization of the transport storage vessel; and

the outlet valve to enable and disable supply to the one or more injectors.

13. A tangible, non-transient computer readable medium, comprising instructions that, when executed by a microprocessor, perform the steps of claim 1.

14. The medium of claim 13, further comprising the operations:

in response to the determining operation, closing a pressurization valve and opening a depressurization valve to reduce an operating pressure of the vessel; and

when the additive amount is at least the determined level, closing the depressurization valve and opening the pressurization valve to pressurize the vessel.

15. The medium of claim 13, wherein the vessel comprises multiple vessels, each with separate outlet and inlet valves, and wherein a microprocessor determines at a first time that an additive amount in a first vessel has dropped below a determined level in response to introduction of additive into the contaminated gas stream and at a later second time that an additive amount in a second vessel has dropped below a determined level in response to introduction of additive into the contaminated gas stream and wherein the microprocessor performs the operations of claim 1 at different times with respect to the first and second vessels.

16. The medium of claim 13, wherein the determination is made by receiving a signal from a level switch and/or sensor, by passage of time, and/or by an operating pressure of the vessel falling below a selected pressure set point.