Electrolyzer apparatus and method of making it

• US 9,017,529 B2
• Filed: 10/14/2014
• Issued: 04/28/2015
• Est. Priority Date: 01/22/2013
• Status: Active Grant

• Current Assignee: GTA, Inc.
• Original Assignee: GTA, Inc.
• Inventors: Greenbaum, Elias Stanley
• Primary Examiner(s): Lin, James
• Assistant Examiner(s): Cohen, Brian W
• Application Number:
  US14/514,152
• Publication Number:
  US 20150026968A1
• Time in Patent Office: 196 Days
• Field of Search: 204/252, 204/280, 204/282, 205628-639
• US Class Current: 204/252
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 11/02 characterised by shape or form
• CPC Class Codes: C25B 13/00 Diaphragms; Spacing elements
• CPC Class Codes: C25B 13/02 characterised by shape or form
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: C25B 9/73 of the filter-press type
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

An apparatus for the electrolytic splitting of water into hydrogen and oxygen gases is disclosed. The apparatus comprises: (i) a first hemi-enclosure; (ii) a second hemi-enclosure; (iii) a diaphragm electrode array positioned between the first hemi-enclosure and the second hemi-enclosure comprising: (a) a diaphragm, that passes ions and impedes the passage of gases, comprising a first side and a second opposed side; (b) a first plurality of electrodes in a first vicinity of the first side of the diaphragm; and (c) a second plurality of electrodes in a second vicinity of the second opposed side of the diaphragm; (iv) a fastener, for leak-tight fastening of the first hemi-enclosure, the diaphragm electrode array, and the second hemi-enclosure, whereby a leak-tight enclosure is formed; (v) contacts, for electrically powering the first and second pluralities of electrodes, and; (vi) pathways, configured to remove hydrogen and oxygen gases from the enclosure.

Claims

1. A method for making a diaphragm electrode array suitable for use in an electrolysis apparatus using a plurality of individual wire strands for an anode and a plurality of individual wire strands for a cathode that each have two opposing ends and using a diaphragm, the diaphragm having opposing and substantially planar surfaces that each have a surrounding perimeter and is made of a material that passes ions but impedes the passage of gas through the opposing surfaces of the diaphragm, the method comprising:

placing the plurality of individual wire strands that comprise the anode while unattached to one another against one surface of the diaphragm such that the opposing ends of each of the individual wire strands are at or beyond the perimeter of the one surface of the diaphragm;

placing the plurality of individual wire strands that comprise the cathode while unattached to one another against the other surface of the diaphragm such that the opposing ends of each of the individual wire strands are at or beyond the opposing perimeter of the other surface of the diaphragm; and

after placing the individual wire strands against one of the surfaces of the diaphragm, and before any of the individual wire strands are affixed to the diaphragm, pressing each individual wire strand against the perimeter of the diaphragm surface against which the individual wires strands have been placed in a manner that makes a diaphragm electrode array suitable for use in the electrolyzer apparatus.

2. The method of claim 1, wherein the diaphragm has a width, each individual wire strand is longer than the width, and further comprising trimming at least one of the ends of each individual wire strand after the pressing so that at least one end of each individual wire strand does not protrude beyond the width of the diaphragm.

3. The method of claim 1, further comprising mounting the diaphragm on a wire applying machine and using the wire-applying machine to place each individual wire strand against one of the surfaces of the diaphragm while unattached to the other strands.

4. The method of claim 1, further comprising wrapping one end of each individual wire strand around a feed bobbin and the other end of each individual wire strand around a take-up bobbin, affixing each wire strand to the diaphragm, un-affixing each individual wire strand from the diaphragm, pulling fresh individual wire strands across the surfaces of the diaphragm using the take-up bobbins, and affixing the fresh individual wire strands to the diaphragm.

5. The method of claim 1, wherein the pressing is performed by placing the diaphragm and the individual wire strands between two hemi-enclosures and fastening the two hemi-enclosures together.

6. The method of claim 5, wherein:

the two hemi-enclosures each have an outer surface; and

following the pressing, at least one end of each of the individual wire strands protrude beyond the outer surfaces of the two hemi-enclosures and are suitable for use as electrical contacts.

7. The method of claim 6, further comprising placing the diaphragm in a frame, wherein the individual wire strands extend beyond the perimeter of the diaphragm.

8. The method of claim 5, further comprising:

contacting at least one end of each of the individual wire strands that are against one surface of the diaphragm with an electrical contact located between abutting faces of the hemi-enclosures; and

contacting at least one end of each of the individual wire strands that are against the other surface of the diaphragm with a different electrical contact located between abutting faces of the hemi-enclosures.

9. The method of claim 5, wherein each hemi-enclosure forms a substantially rectangular cross section that includes single-piece mid-zones.

10. The method of claim 5, further comprising one or more heat sinks outside the enclosure formed by the fastened-together hemi-enclosures, each heat sink comprising a plurality of fins.

11. The method of claim 1, wherein the diaphragm is a PEM membrane.

12. The method of claim 1 wherein the individual wire strands are straight and parallel after the pressing.

13. A method for making a diaphragm electrode array suitable for use in an electrolysis apparatus using wire electrodes that each have two opposing ends and using a diaphragm, the diaphragm having opposing and substantially planar surfaces that each have a surrounding perimeter and is made of a material that passes ions but impedes the passage of gas through the opposing surfaces of the diaphragm, the method comprising:

placing one or more of the electrodes against one surface of the diaphragm such that the opposing ends of each of the one or more electrodes are at or beyond the perimeter of the one surface of the diaphragm;

placing one or more of the other electrodes against the other surface of the diaphragm such that the opposing ends of each of the one or more other electrodes are at or beyond the opposing perimeter of the other surface of the diaphragm;

after placing the electrodes against one of the surfaces of the diaphragm, affixing each electrode at substantially the perimeter of the diaphragm surface against which the electrode has been placed in a manner that makes a diaphragm electrode array suitable for use in the electrolyzer apparatus; and

wrapping one end of each wire electrode around a feed bobbin and the other end of each wire electrode around a take-up bobbin, affixing each wire electrode to the diaphragm, un-affixing each wire electrode from the diaphragm, pulling fresh wire electrodes across the surfaces of the diaphragm using the take-up bobbins, and affixing the fresh wire electrodes to the diaphragm.