Cleaning compositions for use in closed loop cleaning machines

• US 9,034,108 B2
• Filed: 02/27/2009
• Issued: 05/19/2015
• Est. Priority Date: 04/09/2008
• Status: Expired due to Fees

• Current Assignee: Safechem Europe GmbH (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Geissler, Konrad, Kuemin, Marius
• Primary Examiner(s): Kornakov, Michael
• Assistant Examiner(s): COLEMAN, RYAN L
• Application Number:
  US12/736,446
• Publication Number:
  US 20110088722A1
• Time in Patent Office: 2,272 Days
• Field of Search: None
• US Class Current: 134/12
• CPC Class Codes: B08B 3/08 the liquid having chemical or dissolving effect substances used, see the relevant classes
• CPC Class Codes: B08B 3/14 Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquidstreatment of water in general C02F
• CPC Class Codes: C11D 7/263 Ethers
• CPC Class Codes: C11D 7/5022 containing oxygen
• CPC Class Codes: D06F 43/007 Dry cleaning methods
• CPC Class Codes: D06L 1/02 using organic solvents
• CPC Class Codes: D06L 1/10 Regeneration of used chemical baths

Abstract

Embodiments of the present disclosure include cleaning processes, closed loop cleaning machines, and methods of cleaning an article. The cleaning process includes contacting a surface of an article with a cleaning composition in a cleaning chamber, where the cleaning composition includes at least about 85 percent by weight organic solvents, based on total weight of the cleaning composition, and where at least about 5 percent by weight of the organic solvents is propylene glycol, based on total weight of the organic solvents, to clean the surface of the article, collecting the cleaning composition including contaminants, and recovering the cleaning composition via distillation, where a distillation apparatus removes the contaminants from the cleaning composition and is connected to the cleaning chamber by a process stream.

Claims

1. A closed loop cleaning process, comprising:

loading an article to be cleaned into a cleaning chamber;

closing the cleaning chamber;

vaporizing a non-aqueous cleaning composition into a non-aqueous cleaning composition vapor, where the non-aqueous cleaning composition includes at least about 85 percent by weight organic solvents, based on total weight of the non-aqueous cleaning composition, and where at least about 5 percent by weight of the organic solvents is propylene glycol, based on total weight of the organic solvents;

directing the non-aqueous cleaning composition vapor into the cleaning chamber;

condensing the non-aqueous cleaning composition vapor into a liquid on a surface of the article, to clean the surface of the article;

collecting the non-aqueous cleaning composition including contaminants from the article;

recovering the non-aqueous cleaning composition via distillation from contaminants in the non-aqueous cleaning composition, where a distillation apparatus removes the contaminants from the non-aqueous cleaning composition; and

recycling, by a process stream in the closed loop cleaning process, the non-aqueous cleaning composition recovered via distillation back to the closed cleaning chamber.

2. The closed loop cleaning process of claim 1, including flowing the recycled non-aqueous cleaning composition to a storage tank connected to the cleaning chamber.

3. The closed loop cleaning process of claim 1, where the organic solvents in the non-aqueous cleaning composition include propylene glycol in a range of about 5 percent by weight to about 99 percent by weight, based on total weight of the organic solvents.

4. The closed loop cleaning process of claim 1, where the organic solvents in the non-aqueous cleaning composition include propylene glycol in a range of about 15 percent by weight to about 35 percent by weight, based on total weight of the organic solvents.

5. A method of cleaning an article in a closed loop cleaning machine, comprising:

loading the article including soils on an article surface, where the soils are to be removed, into a cleaning chamber;

closing the cleaning chamber;

vaporizing a non-aqueous cleaning composition into a non-aqueous cleaning composition vapor, where the non-aqueous cleaning composition includes at least about 85 percent by weight organic solvents, based on total weight of the non-aqueous cleaning composition, and where at least about 5 percent by weight of the organic solvents is propylene glycol, based on total weight of the organic solvents;

directing the non-aqueous cleaning composition vapor into the cleaning chamber;

condensing the non-aqueous cleaning composition vapor into a liquid on the article surface to remove the soils;

collecting the non-aqueous cleaning composition including the soils from the article;

distilling the non-aqueous cleaning composition, including the soils, to separate the non-aqueous cleaning composition from the soils; and

recycling, by a process stream in the closed loop cleaning process, the non-aqueous cleaning composition recovered via distillation back to the closed cleaning chamber.

6. The method of claim 5, where the soils on the article surface have a polarity and the non-aqueous cleaning composition has a polarity, and where the method includes dissolving the soils on the article surface by adjusting the amount of propylene glycol included in the organic solvents of the non-aqueous cleaning composition up to 99 percent by weight based on the total weight of the organic solvents.