Method of operation of process to produce syngas from carbonaceous material

• US 9,045,706 B2
• Filed: 05/13/2014
• Issued: 06/02/2015
• Est. Priority Date: 04/06/2011
• Status: Active Grant

• Current Assignee: Jupeng Bio (HK) Limited
• Original Assignee: INEOS Bio SA
• Inventors: Ko, Ching-Whan, Slape, Michael Sean, Bell, Peter Simpson, Ocfemia, Kim
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US14/276,492
• Publication Number:
  US 20140246626A1
• Time in Patent Office: 385 Days
• Field of Search: 252/373
• US Class Current: 1/1
• CPC Class Codes: C01B 2203/0877 by direct injection of fluid
• CPC Class Codes: C01B 2203/0894 Generation of steam
• CPC Class Codes: C01B 2203/142 At least two reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 2203/143 Three or more reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C10J 2200/09 Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
• CPC Class Codes: C10J 2200/15 Details of feeding means
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/1606 Combustion processes
• CPC Class Codes: C10J 2300/1846 Partial oxidation, i.e. injection of air or oxygen only
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 3/72 Other features
• CPC Class Codes: C10J 3/721 Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10J 3/723 Controlling or regulating the gasification process
• CPC Class Codes: C10J 3/726 Start-up
• CPC Class Codes: C10J 3/84 with means for removing dust or tar from the gas
• CPC Class Codes: C10J 3/86 combined with waste-heat boilers
• CPC Class Codes: C10K 1/02 Dust removal
• CPC Class Codes: C10K 1/04 by cooling to condense non-gaseous materials C10K1/001 takes precedence
• CPC Class Codes: C10K 3/003 Reducing the tar content
• CPC Class Codes: C10K 3/005 : by partial oxidation
• CPC Class Codes: C10K 3/008 : by cracking
• CPC Class Codes: F22B 1/1838 : the hot gas being under a high pressure, e.g. in chemical installations
• CPC Class Codes: Y02E 20/18 : Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
• CPC Class Codes: Y02E 50/10 : Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 : Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02E 60/32 : Hydrogen storage
• CPC Class Codes: Y02P 20/10 : Process efficiency
• CPC Class Codes: Y02P 20/129 : Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

A process is provided for producing syngas that is effective for use in downstream processes. The process for producing syngas includes operating a gasification apparatus in a start-up mode until the gasification apparatus and equipment downstream of the gasification apparatus are adequately warmed up to a first target temperature. Upon reaching a first target temperature, the process is then operated in a production mode to produce a second syngas with a higher CO/CO₂ molar ratio. Operation in a start-up mode until reaching a first target temperature, provides a process that is effective for reducing fouling in downstream equipment and for providing a second syngas can be more effectively cooled and cleaned.

Claims

1. A process for producing syngas, the process comprising:

gasifying carbonaceous material to provide a first syngas having a CO to CO₂ molar ratio of less than about 0.5 until the first syngas reaches a first target temperature, wherein at least a portion of the first syngas is passed to a syngas cooler at a linear velocity of greater than about 24 meters per second and/or at least a portion of the first syngas is passed to a thermal oxidation unit;

upon reaching the first target temperature, gasifying carbonaceous material to provide a second syngas having a CO to CO₂ ratio of greater than the first syngas; and

passing at least a portion of the second syngas to a syngas cooler at a linear velocity of greater than about 24 meters per second.

2. The process of claim 1 wherein the gasifying of carbonaceous material occurs in a gasification apparatus.

3. The process of claim 1 wherein molecular oxygen is introduced at a rate of about 0 to about 100 lb-mole per ton of carbonaceous material on a dry basis to provide the first syngas.

4. The process of claim 2 wherein the temperature of the first syngas is measured at one or more points inside and/or downstream of the gasification apparatus.

5. The process of claim 4 wherein when the temperature of the first syngas at one or more points inside and/or outside the gasification apparatus reaches the first target temperature, molecular oxygen is introduced at a rate of about 0 to about 100 lb-mole per ton of carbonaceous material on a dry basis to provide the second syngas.

6. The process of claim 1 wherein the first target temperature is about 700°

C. to about 1000°

C.

7. The process of claim 1 wherein at least a portion of the first syngas is passed through a syngas cooler to produce a cooled first syngas and wherein at least a portion of the second syngas is passed through a syngas cooler to produce a cooled second syngas.

8. The process of claim 1 wherein at least a portion of the first syngas is provided to a thermal oxidation unit until the first syngas reaches the first target temperature.

9. A process to produce syngas, said process comprising:

(a) adding carbonaceous material and molecular oxygen to a gasification apparatus to produce a first syngas with CO/CO₂ molar ratio less than 0.5;

(b) passing at least a portion of the first syngas to a syngas cooler and/or passing at least a portion of the first syngas to a thermal oxidation unit;

(c) measuring temperature of said first syngas downstream of said gasification apparatus; and

(d) upon said temperature of said first syngas prior to entry in said syngas cooler attaining a first target temperature, reducing the addition of molecular oxygen per unit mass of carbonaceous material in said gasification apparatus to produce a second syngas with CO/CO₂ molar ratio greater than that of said first syngas,

wherein a flow of syngas through the syngas cooler is maintained at a linear velocity of greater than about 24 meters per second.

10. The process of claim 9 wherein the temperature of said first syngas is measured prior to entry into a syngas cooler.

11. The process of claim 9 wherein the temperature of said first syngas is measured downstream of a syngas cooler.

12. The process of claim 9 wherein at least a portion of said first syngas is passed through said syngas cooler to produce a cooled first syngas and at least a portion of said second syngas is passed through said syngas cooler to produce a cooled second syngas.

13. The process of claim 9 wherein a source of molecular oxygen in step (a) is selected from the group consisting of air, oxygen enriched air, pure oxygen, and combinations thereof.

14. The process of claim 9 wherein a source of molecular oxygen in step (c) is selected from the group consisting of air, oxygen enriched air, pure oxygen, and combinations thereof.

15. The process of claim 9 wherein the source of molecular oxygen in step (a) comprises air.

16. The process of claim 9 wherein the source of molecular oxygen in step (c) comprises pure oxygen.

17. The process of claim 9 wherein said first target temperature is about 700°

C. to about 1000°

C.

18. The process of claim 9 wherein said first target temperature is about 750°

C. to about 850°

C.

19. The process of claim 9 wherein reduction of addition of molecular oxygen per unit mass of carbonaceous material is accomplished by increasing rate of addition of carbonaceous material.

20. The process of claim 9 wherein reduction of addition of molecular oxygen per unit mass of carbonaceous material is accomplished by decreasing rate of addition of molecular oxygen.

21. The process of claim 12 further comprising mixing at least a portion of said cooled first syngas with said portion of first syngas prior to passing through said syngas cooler to produce said cooled first syngas.

22. The process of claim 12 further comprising mixing at least a portion of said cooled second syngas with at least a portion of said second syngas prior to passing through said syngas cooler.

23. The process of claim 21 wherein linear velocity of mixture of said cooled first syngas and said first syngas flowing through said syngas cooler is greater than about 24 meter/second.

24. The process of claim 22 wherein linear velocity of mixture of said cooled second syngas and said second syngas flowing through said syngas cooler is greater than about 24 meter/second.

25. The process of claim 9 wherein the CO/CO₂ molar ratio of said second syngas is greater than about 1.0.

26. The process of claim 9 wherein the CO/CO₂ molar ratio of said second syngas is greater than about 1.5.

27. The process of claim 9 wherein said gasification apparatus is selected from the group consisting of moving bed, fixed bed, fluidized bed, entrained flow, counter-current (“

up draft”

), co-current (“

down draft”

), counter-current fixed bed, co-current fixed bed, counter-current moving bed, co-current moving bed cross draft, hybrid, cross flow, cross flow moving bed, part thereof, and combinations thereof.

28. The process of claim 9 wherein said gasification apparatus comprises one or more reaction zones.

29. The process of claim 9 wherein said gasification apparatus comprises a gasification zone for gasification of carbonaceous material to produce a raw syngas and a heat treatment zone for thermal treatment of said raw syngas to produce first syngas or second syngas.

30. The process of claim 29 further comprising:

attaining at least about 900°

C. temperature in said heat treatment zone prior to step (c).

31. The process of claim 29 further comprising:

attaining at least about 1000°

C. temperature in said heat treatment zone prior to step (c).

32. The process of claim 9 further comprising treating at least a portion of one or more of said first syngas, second syngas, cooled first syngas, and cooled second syngas in a thermal oxidation unit.

33. The process of claim 9 further comprising treating at least a portion of said first syngas in a thermal oxidation unit until said temperature of first syngas downstream of said gasification apparatus attains a first target temperature.

34. The process of claim 29 further comprising treating at least a portion of said first syngas in a thermal oxidation unit until attaining at least about 900°

C. temperature in said heat treatment zone.

35. The process of claim 9 wherein said syngas cooler is selected from the group consisting of shell-and-tube heat exchanger, plate heat exchanger, plate-and-frame heat exchanger, tubular heat exchanger, double-pipe heat exchanger, hair-pin heat exchanger, single-pass heat exchanger, multi-pass heat exchanger, plate-fin heat exchanger, spiral heat exchanger, and combinations thereof.

36. The process of claim 9 further comprising adding one or more of steam and CO₂ in step (c).

37. The process of claim 9 wherein less than about 50 lb-mole steam per ton of carbonaceous material on a dry basis or less than about 50 lb-mole CO₂ per ton of carbonaceous material on a dry basis is added in step (a).

38. A process comprising gasifying carbonaceous material in a gasification apparatus to produce a syngas, said method comprising:

(a) adding carbonaceous material and adding molecular oxygen in said gasification apparatus to produce a first syngas with CO/CO₂ molar ratio less than 0.5;

(b) passing at least a portion of said first syngas through a syngas cooler at a linear velocity of greater than about 24 meters per second to produce a cooled first syngas;

(c) passing at least a portion of said cooled first syngas through a dust collection system to produce a cleaned syngas;

(d) measuring a temperature of said cleaned syngas at an exit of the dust collection system; and

(e) upon said temperature of cleaned syngas attaining a second target temperature, reducing addition of molecular oxygen per unit mass of carbonaceous material in said gasification apparatus to produce a second syngas with CO/ CO₂ molar ratio greater than that of said first syngas.

39. The process of claim 38 wherein said second target temperature is about 100°

C. to about 200°

C.

40. The process of claim 38 wherein said second target temperature is about 100°

C. to about 150°

C.

41. The process of claim 38 wherein the syngas contains less than 10 ppm tars.