Degradable plastic and manufacturing method thereof

• US 9,051,466 B2
• Filed: 04/22/2011
• Issued: 06/09/2015
• Est. Priority Date: 02/28/2011
• Status: Active Grant

• Current Assignee: Jiangsu Jinhe Hi-Tech Co., Ltd.
• Original Assignee: Jiangsu Jinhe Hi-Tech Co., Ltd.
• Inventors: Yin, Zhengfu
• Primary Examiner(s): Heincer, Liam J
• Application Number:
  US13/882,883
• Publication Number:
  US 20130225731A1
• Time in Patent Office: 1,509 Days
• Field of Search: 524/9
• US Class Current: 1/1
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 67/04 Polyesters derived from hydroxycarboxylic acids, e.g. lactones C08L67/06 takes precedence
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

A degradable plastic and a manufacturing method thereof are provided. The degradable plastic is made by mixing plastic, dry crop straw scraps and additives and extruding the mixture into granules with a double-screw extruder. The weight fraction of the plastic, crop straw scraps and additives is 63-73 wt %, 23-33 wt % and 4-6 wt % based on the total weight of raw material. The obtained granules are even, stable and can be used to manufacture daily necessities such as dishware, containers, stationery and bags having smooth surface, high strength, excellent toughness and comfortable hand feeling.

Claims

1. A method of manufacturing a degradable plastic composite comprised of, based on total weight of raw materials. from 63-73 wt % of a degradable plastic;

from 23-33 wt % of crop straw; and

from 4-6 wt % of at least one additive for the degradable plastic, wherein the method comprising the steps of;

providing, as the crop straw, wheat straw and corn stalk that have been dried;

crushing from 10 to 13 wt % of the wheat straw and from 13-20% of the corn stalk, based on total weight of raw materials, to provide crushed crop straw having a 1000 to 4200 mesh;

providing, as the at least one additive, an additive mixture comprised of, based on total weight of raw materials, from 1 to 2% of aluminate/titanate complexing coupling agent, from 1.2 to 2% of the ethylene bis-stearamide, and from 1.5 to 2% of titanium dioxide;

mixing the crushed crop straw and the additive mixture with from 63 to 73% of blow film class polydiethylene glycol sebacate as the degradable plastic, based on total weight of raw materials, to provide a raw material mixture; and

extruding the raw material mixture into granules with a double-screw extruder to provide the degradable plastic composite.

2. A method of manufacturing a degradable plastic composite comprised of, based on total weight of raw materials, from 63-73 wt % of a degradable plastic;

from 23-33 wt % of crop straw; and

from 4-6 wt % of at least one additive for the degradable plastic, the method comprising the steps of;

providing, as the crop straw, based on total weight of raw materials, from 5 to 8 wt % of rice straw, from 5 to 8 wt % of wheat straw, from 5 to 7 wt % of corn cob, and from 8 to 10 wt % of wheat bran, that have been dried;

crushing the crop straw into a powder to provide crushed crop straw having a 1000 to 1200 mesh,

providing, as the at least one additive, an additive mixture comprised of, based on total weight of raw materials, from 1.5 to 2 wt % of ethylene bis-stearomide and from 2 to 4 wt % of titanium dioxide;

mixing the crushed crop straw and the additive mixture with from 63 to 73 wt % of drawing class polylactic acid as the degradable plastic, based on total weight of raw materials, to provide a raw material mixture; and

extruding the raw material mixture into granules with a double-screw extruder.