Method for determining the pH value of a liquid and sensor arrangement

• US 9,052,285 B2
• Filed: 01/22/2013
• Issued: 06/09/2015
• Est. Priority Date: 01/23/2012
• Status: Active Grant

• Current Assignee: EADS Deutschland GmbH (Airbus SE)
• Original Assignee: EADS Deutschland GmbH (Airbus SE)
• Inventors: Muller, Gerhard, Helwig, Andreas, Friedberger, Alois, Hackner, Angelika
• Primary Examiner(s): PHAM, HOA Q
• Application Number:
  US13/747,108
• Publication Number:
  US 20130188171A1
• Time in Patent Office: 868 Days
• Field of Search: 356432-440, 356/244, 356/246, 436/163, 436/168, 436/131, 436/133, 422/82.05, 422/82.09, 422/400, 422/552
• US Class Current: 1/1
• CPC Class Codes: G01N 21/33 using ultraviolet light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/63 optically excited
• CPC Class Codes: G01N 21/80 Indicating pH value
• CPC Class Codes: G01N 2201/0625 Modulated LED

Abstract

A system and method for determining the pH value of a liquid. The system and method excite the liquid molecules in the liquid by light with a predetermined wavelength and an intensity component, transmitted through the liquid in a predetermined wavelength range, of the light used for excitation is captured. This intensity component is used to produce a wavelength/intensity absorption characteristic and this absorption characteristic is related to a reference absorption characteristic associated with a specific pH value of the liquid. The system and method thus can be used to obtain drinking water from a fuel for aircraft.

Claims

1. A method for determining the pH value of a liquid comprising:

exciting liquid molecules in the liquid using light with a predetermined wavelength;

capturing by a detector apparatus an intensity component, transmitted by the liquid in a predetermined wavelength range, of the light used for excitation;

producing by the detector apparatus at least one of a wavelength absorption characteristic and an intensity absorption characteristic from the captured intensity component; and

relating the produced absorption characteristic produced by the detector apparatus to a reference absorption characteristic associated with a specific pH value of the liquid to determine the specific pH value of the liquid.

2. The method as claimed in claim 1, wherein

at least one of an absorption spectrum and a diffraction pattern is produced as absorption characteristic.

3. The method as claimed in claim 2, wherein

at least one of electronic transitions and vibrations are excited in the liquid molecules.

4. The method as claimed in claim 2, wherein

the liquid molecules are excited by at least one of the following:

ultraviolet light in a wavelength range from 100 nm to 330 nm;

light in a wavelength range of visible light, light in a wavelength range of mid infrared light, and light in a wavelength range of near infrared light in the wavelength range from 800 nm to 1200 nm.

5. The method as claimed in claim 1, wherein

at least one of electronic transitions and vibrations are excited in the liquid molecules.

6. The method as claimed in claim 1, wherein

the liquid molecules are excited by at least one of the following:

ultraviolet light in a wavelength range from 100 nm to 330 nm;

light in a wavelength range of visible light, light in a wavelength range of mid infrared light, and light in a wavelength range of near infrared light in the wavelength range from 800 nm to 1200 nm.

7. The method as claimed in claim 1, wherein

a plurality of intensity components of the light used for excitation are captured separately from one another in different predetermined wavelength ranges with an intensity pattern being produced as at least one of the wavelength absorption characteristic and the intensity absorption characteristic from the plurality of separately captured intensity components.

8. The method as claimed in claim 1, wherein

the liquid molecules are excited by pulsed A/C modulated light with at least one of a frequency of the intensity component of the pulsed light transmitted through the liquid being captured separately from one another in a plurality of different predetermined wavelength ranges and the intensity component of the light used for excitation, which is emitted by the light source, is captured prior to entry into the liquid.

9. A method for monitoring a pH value of a liquid, comprising:

repeatedly creating, at predetermined time intervals or continuously, an absorption characteristic of the liquid by performing the method as claimed in claim 1 with samples being taken from the liquid or the liquid being continuously conveyed past at least one of a light source and a detector apparatus; and

capturing the spectral shift of the absorption characteristic.

10. A method for obtaining drinking water from a fuel for aircraft, comprising:

electrolyzing the fuel in a fuel cell to form water and further reaction products;

adding mineral substances to the water; and

performing the method for monitoring the pH value as claimed in claim 9.

11. A sensor arrangement for determining a pH value of a liquid comprising:

a light source configured to irradiate the liquid with light that excites liquid molecules of the liquid;

a carrier apparatus configured to position the liquid in a beam path of the light used for excitation;

a detector apparatus configured to capture an intensity component transmitted through the liquid of the light used for excitation; and

a conversion apparatus configured to produce at least one of a wavelength absorption characteristic and an intensity absorption characteristic from the captured intensity component, and to relate the produced absorption characteristic to a reference absorption characteristic associated with a specific pH value of the liquid to determine the specific pH value of the liquid.

12. The sensor arrangement as claimed in claim 11, wherein

the light source includes an LED, and at least one of the following:

the emitted light has an emission peak in a wavelength range from 255 nm to 270 nm and a spectral width of 40 nm to 60 nm; and

the light source is configured to emit A/C modulated pulsed light.

13. The sensor arrangement as claimed in claim 11, wherein the carrier apparatus includes at least one of the following

a conveying apparatus configured to convey the liquid past at least one of the light source and the detector apparatus;

and

a region which is optically transparent to the light used for excitation, with the region being formed by sapphire or quartz windows.

14. The sensor arrangement as claimed in claim 13, further comprising at least one of the following

a temperature control apparatus configured to control the temperature of the liquid;

and

a temperature measuring apparatus configured to measure the temperature of the liquid prior to irradiating the liquid by the light source.

15. The sensor arrangement as claimed in claim 11, wherein the detector apparatus includes at least one detector formed by a photodiode including Si, SiC, GaN or ZnO.

16. The sensor arrangement as claimed in claim 11, wherein

the detector apparatus includes a detector array which comprises a plurality of detectors configured for separate capture of the intensity component of the light used for excitation in a plurality of different wavelength ranges, the detectors being configured by photodiodes with band-pass filters set to different wavelengths.

17. The sensor arrangement as claimed in claim 11, further comprising

a self-testing apparatus configured to test the sensor arrangement, the self-testing apparatus comprising at least one of an overall monitoring apparatus configured to monitor all electronic and optical parts of the sensor arrangement and a light-source monitoring apparatus configured to monitor the light intensity emitted by the light source.

18. The sensor arrangement as claimed in claim 17, wherein

the overall monitoring apparatus includes a pulsed light source configured to emit light which excites the liquid molecules, and a plurality of detectors configured to capture separately from one another the pulse frequency of the light used for excitation in a plurality of different wavelength ranges.

19. The sensor arrangement as claimed in claim 18, wherein

the light-source monitoring apparatus includes a beam splitter, arranged prior to the entry into the liquid in the beam path of the light used for excitation, to divert a component of the light used for excitation, and a broad-band reference detector configured to capture the intensity of the diverted light.

20. The sensor arrangement as claimed in claim 17, wherein

the light-source monitoring apparatus includes a beam splitter, arranged prior to the entry into the liquid in the beam path of the light used for excitation, to divert a component of the light used for excitation, and a broad-band reference detector configured to capture the intensity of the diverted light.