Material system of co-sintered metal and ceramic layers

• US 9,056,354 B2
• Filed: 08/30/2011
• Issued: 06/16/2015
• Est. Priority Date: 08/30/2011
• Status: Active Grant

• Current Assignee: Mikro Systems, Inc., Siemens AG
• Original Assignee: Mikro Systems, Inc., Siemens AG
• Inventors: Merrill, Gary B., Schillig, Cora, Burns, Andrew J., Paulus, John R.
• Primary Examiner(s): SNELTING, ERIN LYNN
• Application Number:
  US13/221,077
• Publication Number:
  US 20130052442A1
• Time in Patent Office: 1,386 Days
• Field of Search: 264/642
• US Class Current: 1/1
• CPC Class Codes: B22F 3/105 by using electric current other than for infrared radiant energy, laser radiation or plasma B22F3/11 takes precedence; by ultrasonic bonding B22F3/115 takes precedence
• CPC Class Codes: B22F 7/02 of composite layers B22F7/002 takes precedence
• CPC Class Codes: B32B 15/16 next to a particulate layer
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C04B 2235/5454 nanometer sized, i.e. below 100 nm
• CPC Class Codes: C04B 2235/666 Applying a current during sintering, e.g. plasma sintering [SPS], electrical resistance heating or pulse electric current sintering [PECS]
• CPC Class Codes: C04B 2235/95 Products characterised by their size, e.g. microceramics
• CPC Class Codes: C04B 2235/9607 Thermal properties, e.g. thermal expansion coefficient
• CPC Class Codes: C04B 2235/9615 Linear firing shrinkage

Abstract

A method of forming a ceramic layer on a metal substrate. A substrate (40) is formed (54) from a powder (24) of the metal, and may optionally be partially sintered (56). A layer (43) of powdered ceramic is formed (58) on or applied against the substrate (45). The ceramic powder may include a proportion of nano-sized particles effective to reduce the ceramic sintering temperature and to increase the sintering shrinkage of the ceramic layer to more closely match that of the metal substrate. The substrate and layer are then co-sintered (21, 60) at a temperature and for a duration that densifies and bonds them, producing a metal/ceramic layered material system with low interface stress that is durable to temperature variations in a gas turbine. Spark plasma sintering (32, 34, 36) may be used to sinter and/or co-sinter substrate and layer materials that normally cannot be sintered.

Claims

1. A method of fabricating a metal and ceramic layered material system, comprising:

selecting a metal material and a ceramic material with respective coefficients of thermal expansion that are within 15% of each other throughout an operating temperature range plus a co-sintering temperature range;

forming a substrate from a powder of the metal material;

disposing a layer on the substrate, wherein the layer comprises a powder of the ceramic material containing at least 2% by volume of ceramic nano-particles having an average diameter of less than 100 nm;

co-sintering the substrate and the layer within the co-sintering temperature range to a final density of the substrate of at least 97% theoretical density; and

selecting the metal material, the ceramic material, and the percentage of ceramic nano-particles such that the co-sintering produces respective shrinkage amounts of the layer and the substrate that are within 1.0% of each other throughout the co-sintering thereof.

2. The method of claim 1, further comprising partial sintering the substrate forming a pre-sintered substrate prior to the step of disposing of the layer on the substrate.

3. The method of claim 2, further comprising:

performing the co-sintering by spark plasma sintering; and

selecting the metal material, the ceramic material, the percentage of ceramic nano-particles, and the amount of the partial sintering wherein the co-sintering produces respective shrinkage amounts of the layer and the pre-sintered substrate that are within 0.6% of each other throughout the co-sintering thereof.

4. The method of claim 2, further comprising:

disposing the pre-sintered substrate in a die;

pressing the ceramic material powder onto a surface of the pre-sintered substrate; and

applying a voltage across the layer and the pre-sintered substrate that concurrently spark plasma sinters the layer and the pre-sintered substrate to respective final densities of the substrate and the layer that do not change significantly over an operating temperature range of the component.

5. The method of claim 1, further comprising:

forming the layer by mixing the ceramic material powder with a binder to form a ceramic/binder mixture;

injecting the ceramic/binder mixture onto the substrate; and

applying a voltage across the substrate and the layer that concurrently spark plasma sinters the layer and the substrate to respective final densities of the substrate and the layer that do not change significantly over an operating temperature range of the component.

6. The method of claim 1, further comprising:

forming the substrate from a mixture of the metal powder and a binder that forms a metal/binder mixture;

forming a surface of the substrate that provides engineered interlocking surface features on the substrate;

forming the layer by filling the interlocking surface features on the substrate with the ceramic powder to provide an interlock there between.

7. The method of claim 1, further comprising:

selecting the metal and ceramic materials to be a material couple from the set of material couples consisting of;

MoCu and Al₂O₃;

Ta and Al₂O₃; and

FeCrSi—

Y₂O₃ and 8 mol YSZ; and

applying a voltage across the layer and the substrate that concurrently spark plasma sinters the layer and the substrate to respective final densities of the substrate and the layer that do not change significantly over an operating temperature range of the component.

8. A method of fabricating a metal and ceramic layered material system, comprising:

selecting a metal material and a ceramic material with respective coefficients of thermal expansion that are within 15% of each other throughout a temperature range of 0-1400°

C.;

forming a substrate comprising engineered interlocking surface features from a powder of the metal material;

partially sintering the substrate to produce a pre-sintered substrate;

disposing a layer on the pre-sintered substrate, wherein the layer comprises a powder of the ceramic material containing 2% to 50% by volume of ceramic nano-particles having an average diameter of less than 100 nm;

co-sintering the pre-sintered substrate and the layer enough to achieve a final density of the substrate of at least 97% theoretical density; and

selecting the metal material, the ceramic material, the percentage of ceramic nano-particles, and a degree of the partial sintering, wherein the co-sintering produces respective shrinkage amounts of the layer and the pre-sintered substrate that are within 1.0% of each other throughout the co-sintering thereof.

9. The method of claim 8, further comprising:

performing the partial sintering to 85%-90% of a full density of the substrate;

performing the co-sintering by spark plasma sintering; and

selecting the metal material, the ceramic material, and the percentage of ceramic nano-particles, wherein the co-sintering produces respective shrinkage amounts of the layer and the pre-sintered substrate that are within 0.6% of each other throughout the co-sintering thereof.

10. A method of fabricating a metal and ceramic layered material system, comprising:

forming a substrate comprising particles of a metal material;

forming a layer comprising particles of a ceramic material comprising a particle size distribution including 5% to 40% of the particles being less than 50 nm in average diameter;

co-sintering the layer onto the substrate with a co-processing cycle wherein a sintering shrinkage of the substrate and a sintering shrinkage of the layer stay within 1.0% of each other throughout the co-sintering to form a chemical bond between the substrate and the layer comprising interspersed elements of both the metal material and the ceramic material.

11. The method of claim 10, wherein the co-sintering comprises spark plasma sintering.

12. The method of claim 10, further comprising partially sintering the substrate prior to the co-sintering step.

13. The method of claim 12, wherein at least one of the partial sintering and the co-sintering comprises spark plasma sintering.

14. The method of claim 10, further comprising selecting the metal material and the ceramic material to have respective coefficients of thermal expansion that are within 15% of each other throughout a temperature range of 0-1700°

C.

15. The method of claim 10, further comprising the selecting the metal material and the ceramic material from the set of material couples consisting of:

MoCu and Al₂O₃;

Ta and Al₂O₃; and

FeCrSi—

Y₂O₃ and 8 mol YSZ.

16. The method of claim 10, further comprising:

forming the substrate and the layer to have cooperating surface features;

aligning the surface features of the substrate and the layer together prior to the step of co-sintering such that the chemical bond formed is reinforced by mechanical cooperation between the surface features.

17. The method of claim 10, further comprising:

the step of forming a layer comprising particles of a ceramic material further comprises forming an intermediate layer comprising both metal and ceramic particles and forming a top layer consisting of ceramic particles; and

co-sintering the intermediate layer onto the substrate and the top layer onto the intermediate layer with a co-processing cycle wherein the sintering shrinkage of the substrate and that of the intermediate layer stay within 1.0% of each other throughout the co-sintering and the sintering shrinkage of the intermediate layer and that of the top layer stay within 1.0% of each other throughout the co-sintering.