Multilayer electronic device having one or more barrier stacks

• US 9,059,425 B2
• Filed: 04/06/2012
• Issued: 06/16/2015
• Est. Priority Date: 04/08/2011
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Thoumazet, Claire, Python, Martin, Leyder, Charles
• Primary Examiner(s): Soward, Ida M
• Application Number:
  US14/110,233
• Publication Number:
  US 20140054578A1
• Time in Patent Office: 1,166 Days
• Field of Search: 257/40, 257/759, 257/E51.002, 257/E51.003, 257/E51.012, 257/E51.027, 438/82, 438/99
• US Class Current: 1/1
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: H01L 31/02168 the coatings being antireflective or having enhancing optical properties for the solar cells
• CPC Class Codes: H01L 31/022466 made of transparent conductive layers, e.g. TCO, ITO layers
• CPC Class Codes: H01L 31/022483 composed of zinc oxide [ZnO]
• CPC Class Codes: H01L 31/048 Encapsulation of modules
• CPC Class Codes: H10K 2102/311 Flexible OLED
• CPC Class Codes: H10K 30/82 Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
• CPC Class Codes: H10K 50/816 Multilayers, e.g. transparent multilayers
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 50/86 Arrangements for improving contrast, e.g. preventing reflection of ambient light
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

A device includes an organic polymer layer and an electrode positioned against the polymer layer, the electrode being constituted by a transparent stack of thin layers including an alternation of n thin metallic layers and of (n+1) antireflection coatings, with n≧1, where each thin metallic layer is placed between two antireflection coatings. At least one of the two antireflection coatings located at the ends of the constituent stack of the electrode includes a stack that is a barrier to moisture and gases, the layers of the or each barrier stack having alternately lower and higher densities.

Claims

1. A multilayer electronic device, comprising:

an organic polymer layer;

an electrode positioned against the organic polymer layer, the electrode being constituted by a transparent stack of thin layers comprising an alternation of n thin metallic layers and of (n+1) antireflection coatings, with n≧

1, where each thin metallic layer is placed between two antireflection coatings, wherein the electrode comprises;

a first barrier stack, which is a barrier to moisture and to gases, in the end antireflection coating which is placed under the n thin metallic layers in the direction of deposition of the constituent stack of the electrode, the first barrier stack comprising at least four layers having alternately lower and higher densities,

and/or

a second barrier stack, which is a barrier to moisture and to gases, in the end antireflection coating which is placed on top of the n thin metallic layers in the direction of deposition of the constituent stack of the electrode, the second barrier stack comprising at least three layers having alternately lower and higher densities.

2. The device as claimed in claim 1, wherein each antireflection coating which is placed under, in the direction of deposition of the constituent stack of the electrode, a thin metallic layer comprises, as layer subjacent to the thin metallic layer, a wetting layer based on crystalline oxide.

3. The device as claimed in claim 2, wherein the wetting layer is based on zinc oxide.

4. The device as claimed in claim 1, wherein each antireflection coating that is placed on top, in the direction of deposition of the constituent stack of the electrode, of a thin metallic layer comprises, as layer superjacent to the thin metallic layer, an oxidized or unoxidized thin metallic overblocker layer.

5. The device as claimed in claim 1, wherein at least one barrier stack of the electrode comprises at least three successive layers having alternately lower and higher degrees of crystallinity, the ratio of the degree of crystallinity of a layer of higher degree of crystallinity to the degree of crystallinity of a layer of lower degree of crystallinity being greater than or equal to 1.1.

6. The device as claimed in claim 5, wherein said at least three successive layers are alternately in an amorphous state and in an at least partially crystalline state.

7. The device as claimed in claim 1, wherein the constituent layers of the or each barrier stack of the electrode have alternately lower and higher refractive indices.

8. The device as claimed in claim 1, wherein for the or each barrier stack of the electrode, each thin layer of the barrier stack has a geometric thickness of less than 200 nm.

9. The device as claimed in claim 8, wherein for the or each barrier stack of the electrode, each thin layer of the barrier stack has a geometric thickness of less than 100 nm.

10. The device as claimed in claim 1, wherein, for the or each barrier stack of the electrode, each thin layer of the barrier stack is a doped or undoped oxide, nitride or oxynitride layer.

11. The device as claimed in claim 1, wherein the organic polymer layer comprises an organic or hybrid organic-inorganic interfacial layer which is positioned against the electrode.

12. The device as claimed in claim 1, wherein the organic polymer layer is a substrate of the device.

13. The device as claimed in claim 1, wherein the organic polymer layer is a lamination interlayer for bonding with a substrate of the device.

14. The device as claimed in claim 1, wherein the device is an organic light-emitting diode device, where the electrode is an electrode of the organic light-emitting diode and the organic polymer layer is all or part of a structure for encapsulating the organic light-emitting diode.

15. The device as claimed claim 1, wherein the device is a photovoltaic device, where the electrode is an electrode of the photovoltaic cell and the organic polymer layer is all or part of a structure for encapsulating the photovoltaic cell.

16. The device as claimed in claim 1, wherein the device is an electrochromic device, where the electrode is an electrode of the electrochromic system and the organic polymer layer is all or part of a structure for encapsulating the electrochromic system.

17. A process for manufacturing a device as claimed in claim 1, wherein at least some of the thin layers of the or each barrier stack are deposited by sputtering.

18. The manufacturing process as claimed in claim 17, wherein all of the thin layers of the constituent stack of the electrode, including the layers of the or each barrier stack, are deposited by sputtering.

19. The manufacturing process as claimed in claim 18,

wherein all of the thin layers of the constituent stack of the electrode, including the layers of the or each barrier stack, are deposited by magnetron sputtering.

20. The manufacturing process as claimed in claim 17, wherein the at least some of the thin layers of the or each barrier stack are deposited by magnetron sputtering.

21. The device as claimed in claim 1, wherein the n thin metallic layers of the electrode are based on silver or on a metal alloy containing silver.

22. A method comprising arranging in a multilayer electronic device a multilayer component comprising

an organic polymer layer;

an electrode positioned against the organic polymer layer, the electrode being constituted by a transparent stack of thin layers comprising an alternation of n thin metallic layers and of (n+1) antireflection coatings, with where each thin metallic layer is placed between two antireflection coatings and where the electrode comprises;

a first barrier stack, which is a barrier to moisture and to gases, in the end antireflection coating which is placed under the n thin metallic layers in the direction of deposition of the constituent stack of the electrode, the first barrier stack comprising at least four layers having alternately lower and higher densities,

and/or

a second barrier stack, which is a barrier to moisture and to gases, in the end antireflection coating which is placed on top of the n thin metallic layers in the direction of deposition of the constituent stack of the electrode, the second barrier stack comprising at least three layers having alternately lower and higher densities.

23. The method as claimed in claim 22, wherein the n thin metallic layers of the electrode are based on silver or on a metal alloy containing silver.