Adhesive

• US 9,062,234 B2
• Filed: 08/06/2012
• Issued: 06/23/2015
• Est. Priority Date: 06/08/2010
• Status: Active Grant

• Current Assignee: Wuhan Keda Marble Protective Materials Co., Ltd.
• Original Assignee: Wuhan Keda Marble Protective Materials Co., Ltd.
• Inventors: Du, Kunwen, Du, Kunwu
• Primary Examiner(s): Fink, Brieann R
• Application Number:
  US13/568,102
• Publication Number:
  US 20120302686A1
• Time in Patent Office: 1,051 Days
• Field of Search: 524/313
• US Class Current: 1/1
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08K 3/20 Oxides; Hydroxides graphene oxides C08K3/042
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 5/0025 Crosslinking or vulcanising agents; including accelerators
• CPC Class Codes: C08K 5/103 with polyalcohols
• CPC Class Codes: C09J 167/06 Unsaturated polyesters having carbon-to-carbon unsaturation

Abstract

An adhesive including at least 100 weight parts of an unsaturated polyester resin suitable for air-drying, between 0 and 5 weight parts of hydrogenated castor oil, between 1 and 20 weight parts of a nano powder, between 10 and 250 weight parts of a filler, and between 1 and 15 weight parts of an anti-shrinking agent.

Claims

1. An adhesive comprising:

at least 100 weight parts of an unsaturated polyester resin suitable for air-drying selected from the group consisting of allyl glycidyl ether-modified unsaturated polyester resin, and trimethylolpropane diallyl ether-modified unsaturated polyester resin,

between 0 and 5 weight parts of hydrogenated castor oil,

between 1 and 20 weight parts of a nano powder selected from the group consisting of nano calcium carbonate, nano magnesium silicate, nano calcium oxide, nano alumina, and a mixture thereof,

between 10 and 250 weight parts of a filler,

between 1 and 15 weight parts of an anti-shrinking agent, and

between 1 and 5 weight parts of an active diluent selected from the group consisting of α

-methyl styrene, diallyl phthalate, 2-chlorostyrene, p-tert-butyl styrene, and a mixture thereof.

2. The adhesive of claim 1, comprising at least 100 weight parts of the unsaturated polyester resin suitable for air-drying, between 1 and 3 weight parts of the hydrogenated castor oil, between 3 and 10 weight parts of the nano powder, between 50 and 200 weight parts of the filler, and between 5 and 10 weight parts of the anti-shrinking agent.

3. The adhesive of claim 2, comprising 100 weight parts of the unsaturated polyester resin suitable for air-drying, one weight part of the hydrogenated castor oil, 6 weight parts of the nano powder, 70 weight parts of the filler, and 8 weight parts of the anti-shrinking agent.

4. The adhesive of claim 1, wherein the nano powder and the filler are dispersed using ultrasonic wave and stirred at least 1,500 rpm.

5. The adhesive of claim 1, wherein the filler is selected from the group consisting of calcium carbonate, talcum powder, heavy calcium carbonate, quartz powder, calcium stearate, dolomite powder, calcium stearate, barium sulfate, or a mixture thereof.

6. The adhesive of claim 1, wherein the anti-shrinking agent is selected from the group consisting of polypropyl acetate, poly (adipate-co-propanetriol), poly vinyl acetate, polyacrylate, polystyrene, polyethylene, polyvinyl chloride, polymethyl methacrylate, or a mixture thereof.

7. The adhesive of claim 1, further comprising between 5 and 20 weight parts of rutile titanium dioxide.

8. The adhesive of claim 1, further comprising a colored pigment.

9. The adhesive of claim 5, wherein the filler used is between 300 and 1,250 mesh on the average.

10. The adhesive of claim 1, wherein the unsaturated polyester resin is trimethylolpropane diallyl ether-modified unsaturated polyester resin.

11. The adhesive of claim 1, wherein the nano powder is nano calcium carbonate, nano magnesium silicate, nano calcium oxide, nano alumina, or a mixture thereof.

12. An adhesive comprising:

at least 100 weight parts of an unsaturated polyester resin selected from the group consisting of allyl glycidyl ether-modified unsaturated polyester resin, and trimethylolpropane diallyl ether-modified unsaturated polyester resin;

between 0 and 5 weight parts of hydrogenated castor oil;

between 1 and 20 weight parts of a nano powder selected from the group consisting of nano magnesium silicate, nano calcium oxide, and a mixture thereof;

between 10 and 250 weight parts of a filler;

between 1 and 15 weight parts of an anti-shrinking agent selected from the group consisting of poly (adipate-co-propanetriol), poly vinyl acetate, polyvinyl chloride, and a mixture thereof; and

between 1 and 5 weight parts of an active diluent selected from the group consisting of α

-methyl styrene, diallyl phthalate, 2-chlorostyrene, p-tert-butyl styrene, and a mixture thereof.

13. The adhesive of claim 12, wherein the unsaturated polyester resin is trimethylolpropane diallyl ether-modified unsaturated polyester resin.

14. The adhesive of claim 12, wherein the nano powder and the filler are dispersed using ultrasonic wave, and are stirred in the adhesive at a speed of at least 1,500 rpm.

15. The adhesive of claim 12, wherein the filler is selected from the group consisting of calcium carbonate, talcum powder, heavy calcium carbonate, quartz powder, calcium stearate, dolomite powder, calcium stearate, barium sulfate, and a mixture thereof.

16. The adhesive of claim 12, wherein the unsaturated polyester resin is allyl glycidyl ether-modified unsaturated polyester resin, the nano powder is nano magnesium silicate, the anti-shrinking agent is poly (adipate-co-propanetriol), and the active diluent is diallyl phthalate.