Self-sealing fastener

• US 9,068,583 B2
• Filed: 11/02/2011
• Issued: 06/30/2015
• Est. Priority Date: 02/20/2007
• Status: Expired due to Fees

• Current Assignee: Systems and Materials Research Corporation
• Original Assignee: Systems and Materials Research Corporation
• Inventors: Bray, Alan V., Schmidt, Gary, Deppe, Denise, Irvin, David J.
• Primary Examiner(s): ESTREMSKY, GARY WAYNE
• Application Number:
  US13/287,791
• Publication Number:
  US 20120168055A1
• Time in Patent Office: 1,336 Days
• Field of Search: 411/82, 411/258, 411/82.3, 411/930
• US Class Current: 1/1
• CPC Class Codes: B05D 3/06 by exposure to radiation B05D3/02 takes precedence ; plasma treatment B05D3/141
• CPC Class Codes: F16B 19/008 with sealing means
• CPC Class Codes: F16B 2200/95 with markings, colours, indicators or the like
• CPC Class Codes: Y10T 29/49764 with testing or indicating
• CPC Class Codes: Y10T 29/49885 with coating before or during assembling
• CPC Class Codes: Y10T 29/49947 by applying separate fastener
• CPC Class Codes: Y10T 29/49966 with supplemental joining

Abstract

An apparatus for making and using a fastener suitable for use in airplane manufacture or repair that is coated with a pre-mixed moisture cure sealant. The sealant layer is coated with a frangible moisture barrier that will break apart when the fastener is installed, thus exposing the sealant to a moisture source. Once exposed to moisture, the sealant will begin to cure. Preferred embodiments also provide a premature cure indicator that provides a visual indication that the outer moisture resistant layer has been damaged.

Claims

1. A fastener covered with a self-sealing coating, said self-sealing coating comprising:

one or more layers of a one-part moisture-curable sealant; and

a first layer of a frangible moisture barrier coating covering said one or more layers of one-part curable sealant, such that when the fastener is installed into a pre-drilled hole in a workpiece the frangible moisture barrier will break apart, thereby allowing moisture from a moisture source to reach the sealant so that the sealant will cure and form a seal between the faster and the workpiece, and at least a portion of said moisture barrier coating will be extruded rather than mixing with the portion of the sealant forming the seal between the fastener and the workpiece.

2. The fastener of claim 1 in which the moisture-curable sealant is cure blocked with a moisture removable blocking group.

3. The fastener of claim 1 in which the portion of moisture barrier extruded is greater than 50%.

4. The fastener of claim 1 in which the portion of moisture barrier extruded is greater than 75%.

5. The fastener of claim 1 in which the one-part moisture-curable sealant comprises a thiol-terminated polymer, pre-polymer, or oligomer capped with a protecting group where the protecting group is cleaved by moisture, and is an organic and/or an organosilane blocking group.

6. The fastener of claim 1 in which the one-part moisture-curable sealant comprises a thiol-terminated polymer, pre-polymer, or oligomer capped with a protecting group where the protecting group is cleaved by moisture, and is an inorganic blocking group.

7. The fastener of claim 1 in which the one-part moisture-curable sealant comprises a thiol-terminated polymer, pre-polymer, or oligomer capped with a protecting group where the protecting group is cleaved by moisture, and is an inorganic salt blocking group.

8. The fastener of claim 1 further comprising a coating of a premature cure indicator over said one or more layers of the one-part curable sealant and underneath said layer of a frangible moisture barrier coating, said premature cure indicator changing color when exposed to thiol reactive groups.

9. The fastener of claim 1 in which the moisture source is atmospheric moisture.

10. A fastener covered with a self-sealing coating, said self-sealing coating comprising:

one or more layers of a one-part moisture-curable sealant;

one or more layers of a frangible moisture barrier coating on top of said one or more layers of the one-part curable sealant, such that when the fastener is installed the frangible moisture barrier layers will break apart allowing moisture to reach the sealant so that the sealant will cure; and

in which the frangible moisture barrier coating layers comprise a non-solvent based size coat curable by actinic radiation.

11. The fastener of claim 10 in which the moisture barrier coating is an actinic radiation curable polymer composition comprising:

(i) an acid ester;

(ii) an acrylic oligomer;

(iii) a multi-functional (meth)acrylate monomer; and

/or (iv) a layered inorganic silicate, wherein the composition is curable under ambient temperatures and pressures using actinic radiation.

12. The fastener of claim 11 in which the acid ester is either a monofunctional acid ester or a trifunctional acid ester, or a mixture thereof.

13. The fastener of claim 11 in which the acrylic oligomer is selected from the group consisting of:

epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, amine modified polyether acrylate, acrylic acrylate, or combination thereof.

14. The fastener of claim 11 in which the multi-functional (meth)acrylate monomer is selected from the group consisting of:

1,12 dodecanediol dimethacrylate;

1,4-butanediol diacrylate;

1,4-butanediol dimethacrylate;

1,6-hexanediol diacrylate;

1,6 hexanediol dimethacrylate;

diethylene glycol diacrylate;

diethylene glycol dimethacrylate;

dipropylene glycol diacrylate;

dipropylene glycol dimethacrylate;

ethylene glycol diacrylate;

ethylene glycol dimethacrylate;

polyethylene glycol diacrylate;

polyethylene glycol dimethacrylate;

1,3-butylene glycol diacrylate;

1,3-butylene glycol dimethacrylate;

neopentyl glycol diacrylate;

neopentyl glycol dimethacrylate;

cyclohexane dimethanol diacrylate;

cyclohexane dimethanol dimethacrylate;

ethoxylated bisphenol A diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, and mixtures thereof.

15. The fastener of claim 11 in which the layered silicate is a phyllosilicate selected from the group consisting of:

bentonite;

vermiculite;

montmorillonite;

nontronite;

beidellite;

volkonskoite;

hectorite;

saponite;

sauconite;

magadiite;

kanyaite;

ledikite and mixtures thereof.

16. A method of producing a fastener covered with a self-sealing coating, the method comprising:

applying one or more layers of a one-part moisture-curable sealant to a fastener; and

applying a layer of a frangible moisture barrier coating covering said one or more layers of the one-part curable sealant, such that when the fastener is installed into a pre-drilled hole in a workpiece the frangible moisture barrier will break apart, thereby allowing moisture from a moisture source to reach the sealant so that the sealant will cure and form a seal between the fastener and the workpiece, and at least a portion of the frangible moisture barrier will be extruded rather than mixing with the portion of the sealant forming the seal between the fastener and the workpiece.

17. The method of claim 16 in which applying a layer of a frangible moisture barrier coating over said one or more layers of the one-part curable sealant comprises applying a layer of a frangible moisture barrier coating over said one or more layers of the one-part curable sealant and curing the frangible moisture barrier coating using actinic radiation.

18. The method of claim 17 in which curing the frangible moisture barrier coating using actinic radiation includes frangible moisture barrier coating without curing the sealant.

19. The method of claim 16 further comprising, after applying the one or more layers of a one-part moisture-curable sealant to a fastener, applying a coating of a premature cure indicator that changes color when exposed to thiol reactive groups.

20. The method of claim 16 in which the moisture-curable sealant comprises a polysulfide sealant.

21. The method of claim 16 in which the moisture-curable sealant comprises a polythioether sealant.

22. The method of claim 16 in which applying one or more layers of a one-part moisture-curable sealant to the fastener comprises applying the one-part moisture-curable sealant to a fastener having a head and a shank by applying a sufficient volume of said sealant uniformly around the shank of the fastener so that when the fastener is installed into a workpiece a small amount of sealant visibly extrudes completely around the fastener head.