Method and apparatus for remote detection of alcohol vapor in the atmosphere

• US 9,068,885 B2
• Filed: 05/23/2013
• Issued: 06/30/2015
• Est. Priority Date: 05/29/2012
• Status: Active Grant

• Current Assignee: Airoptic Sp. z o.o.
• Original Assignee: Airoptic Sp. z o.o.
• Inventors: Lundqvist, Stefan, Kluczynski, Pawel
• Primary Examiner(s): Gaworecki, Mark R
• Application Number:
  US13/901,260
• Publication Number:
  US 20130334419A1
• Time in Patent Office: 768 Days
• Field of Search: 250/339.12, 250/339.13, 250/343, 356/437, 422/84, 73/233
• US Class Current: 1/1
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 33/4972 Determining alcohol content for vehicle safety devices B60K28/06

Abstract

A light beam generated by a light source having a wavelength corresponding to the ethanol absorption spectrum, preferably in the wavelength range of 3.28-3.52 μm or in one or more wavelength ranges 6.49-7.46 μm, 7.74-8.33 μm, 8.84-10.10 μm, 10.7-12.00 μm, is sent through a measuring space containing a sample of exhaled breath, and then the intensity of the light beam passing through the measuring space is measured. Based on the spectral analysis of the dependence of the light intensity to the alcohol concentration, the concentration of ethanol vapor is determined and the information about the level of the ethanol content is provided to a suitable display or device.

Claims

1. A method for remote detection of alcohol vapor in the atmosphere, useful for determination of a concentration of ethanol vapor in air exhaled by humans, comprising

generating from a laser light source a beam of laser light with a wavelength corresponding to the absorption spectrum of alcohol in a wavelength range of 3.28-3.52 μ

m, or in one or several wavelength ranges of 6.49-7.46 μ

m, 7.74-8.33 μ

m, 8.84-10.10 μ

m, and 10.7-12.00 μ

m,

sending the laser light beam outside of a device in which the laser light source is housed and across a measurement space outside and separate from the device, the laser light beam being received by a detector,

subsequently measuring a light intensity of the laser light after the beam has passed through the measurement space and has been received by the detector, and

subsequently, based on spectral analysis of the dependence of the measured light intensity on an alcohol level, determining a concentration of alcohol vapor in the measurement space.

2. The method according to claim 1, wherein the wavelength of the laser light source is tuned over a wavelength range covering a sharp absorption feature of ethanol at a wavelength of 3.345 μ

m or 7.174 μ

m or 8.057 μ

m or 9.377 μ

m or 11.372 μ

m, and a part of and/or a whole of an absorption ‘

plateau’

, located in close proximity of the sharp absorption feature.

3. The method according to claim 2, wherein the wavelength is further tuned over a wavelength range covering a single absorption line or multiple absorption lines of a tracer gas selected from the group consisting of carbon dioxide and water vapor used to measure an amount of exhaled breath.

4. The method according to claim 1, wherein after the determining of the alcohol vapor concentration, the information is supplied to a suitable display and/or other equipment for further processing.

5. The method according to claim 1, wherein the laser light source and the detector are located on opposite sides of the measurement space.

6. The method according to claim 1, wherein the laser light source and the detector are on a same side of the measurement space and a retro-reflector that redirects the laser light beam to the detector is located on an opposite side of the measurement space.

7. The method according to claim 1, wherein the measurement space comprises a vehicle passenger cabin.

8. A method of remote detection of ethanol vapor concentration in the exhaled breath from persons inside a cabin of a vehicle, comprising generating a beam of laser light at a wavelength range around 3.345 μ

m, said wavelength range covering a whole or a part of a sharp absorption feature of ethanol at a wavelength of 3.345 μ

m, sending the laser light beam through the cabin of the vehicle, and then measuring the light intensity of the laser light after the beam is passed through the cabin of the vehicle and determining the concentration of ethanol vapor by means of spectral analysis of the dependence of the light intensity on the ethanol concentration.

9. The method according to claim 8, wherein the wavelength of the light source is tuned over a wavelength range including a part of, or a whole of, an absorption ‘

plateau’

located in proximity of the sharp absorption feature of ethanol.

10. The method according to claim 9, wherein before the sending of the laser light beam through the cabin of the vehicle, a background signal, which contains an absorption signal from atmospheric gases and characteristics of the light source including any distortion of a received optical signal, is recorded and removed from the measuring and determining.

11. The method according to claim 10, wherein the method further comprises generating a second light beam from a second light source with a wavelength corresponding to an absorption feature of a tracer gas selected from the group consisting of carbon dioxide and water vapor, sending the generated second light beam from the second light source through the cabin of the vehicle containing a sample of exhaled air, measuring the light intensity of the light from the second light source and determining the level of carbon dioxide or water vapor in the cabin of the vehicle based on the measuring of the light intensity of the light from the second source, and then determining a level of alcohol in the breath using the determined concentration of the ethanol vapor and the determined tracer gas level in the cabin.

12. The method according to claim 9, wherein the wavelength is also tuned over a wavelength range covering a single absorption line or multiple absorption lines of a tracer gas selected from the group consisting of carbon dioxide and water vapor.

13. A method for detecting the presence of ethanol vapor in air from an exhaled breath of a human, comprising

generating from a laser light source a modulated beam of laser light at a wavelength corresponding to an absorption feature of ethanol within the wavelength range of 3.28-3.52 μ

m, or within one or more of the wavelength ranges of 6.49-7.46 μ

m, 7.74-8.33 μ

m, 8.84-10.10 μ

m, 10.7-12.00 μ

m,

passing the modulated beam of laser light outside of a device in which the laser light source is housed and through a space, outside and separate from the device, containing the exhaled breath, and

measuring the light passing through the space using the Wavelength Modulation Spectroscopy (WMS) method, and determining a level of ethanol vapor in the exhaled breath based on the light detected after the beam is passed through the space.

14. The method according to claim 13, wherein the method further comprises generating a source of light of a wavelength corresponding to an absorption spectrum of a tracer gas selected from the group consisting of carbon dioxide and water vapor, present in the exhaled air, and sending the source of light through the space containing the exhaled breath, measuring an intensity of the light passing through the space and determining the level of tracer gas in the exhaled breath based on the measured intensity of the light, and then determining the level of ethanol vapor in the exhaled breath by means of the determined level of ethanol vapor and the determined level of tracer gas in said space.

15. A system for remote detection of ethanol vapor concentration in exhaled air, comprising a laser light source in a housing, and a detector for detecting the intensity of laser light from the laser light source emitting at a wavelength corresponding to the spectrum of ethanol absorption, wherein the which the laser light source is contained and across a measurement space outside and separate from the housing, wherein the system is equipped with a synchronizing-calculating module for determination of the concentration of ethanol by means of spectral analysis which is connected to the detector for detecting the light intensity, and wherein the laser light source emits a beam of laser light in the wavelength range of 3.28-3.52 μ

m, or within one or more of the wavelength ranges of 6.49-7.46 μ

m, 7.74-8.33 μ

m, 8.84-10.10 μ

m, 10.7-12.00 μ

m.

16. The system according to claim 15, wherein the light source is a tunable, single-mode semiconductor laser of GaInAsSb/AlGaInAsSb.

17. The system according to claim 15, wherein the light source is a tunable quantum cascade laser.

18. The system according to claim 17, wherein the light source is an Interband Cascade Laser (ICL).

19. The system according to claim 15, wherein the light source is a tunable vertical-cavity surface-emitting laser (VCSEL).

20. The system according to claim 15, wherein the light beam is created by difference frequency generation (DFG), which generates light by means of differential mixing of light waves from two lasers.

21. The system according to claim 15, wherein the light source is configured to emit a light beam with a wavelength of 3.345 μ

m or 7.174 μ

m or 8.057 μ

m or 9.377 μ

m or 11.372 μ

m, and optionally further wavelength tuned through a sharp absorption feature of ethanol vapor, which occur at wavelengths of 3.345 μ

m or 7.174 μ

m or 8.057 μ

m or 9.377 μ

m or 11.372 μ

m.

22. The system according to claim 15, wherein the light source is additionally tuned over a wavelength range covering a single absorption line or multiple absorption lines of a tracer gas selected from the group consisting of carbon dioxide and water vapor, in order to determine the absolute concentration of ethanol in the exhaled air.

23. The system according to claim 15, wherein the system is equipped with an additional source of laser light at a wavelength corresponding to an absorption line of tracer gas, selected from the group consisting of carbon dioxide and water vapor, contained in the exhaled breath, in order to determine the absolute concentration of ethanol in the exhaled air.

24. The system according to claim 15, wherein the system is configured to detect the presence of alcohol vapor in the passenger compartment of a vehicle, using a beam of light with a wavelength of 3.345 μ

m.

25. The system according to claim 15, wherein the laser light source and the detector are located on opposite sides of the measurement space.

26. The system according to claim 15, wherein the system is equipped with a retro-reflector to redirect the beam to the detector, where the laser light source and the detector are on a same side of the measurement space and the retro-reflector is located on an opposite side of the measurement space.