Flux addition as a filter conditioner

• US 9,089,798 B2
• Filed: 10/25/2013
• Issued: 07/28/2015
• Est. Priority Date: 12/18/2009
• Status: Active Grant

• Current Assignee: Lummus Technology Inc.
• Original Assignee: Lummus Technology Inc.
• Inventors: Troxclair, Emile J.
• Primary Examiner(s): MERKLING, MATTHEW J
• Application Number:
  US14/062,946
• Publication Number:
  US 20140050632A1
• Time in Patent Office: 641 Days
• Field of Search: 48/61
• US Class Current: 1/1
• CPC Class Codes: B01D 29/66 by flushing, e.g. counter-current air-bumps
• CPC Class Codes: C10J 2300/0993 Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
• CPC Class Codes: C10J 2300/0996 Calcium-containing inorganic materials, e.g. lime
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 3/485 Entrained flow gasifiers
• CPC Class Codes: C10J 3/721 Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10J 3/84 with means for removing dust or tar from the gas
• CPC Class Codes: C10J 3/86 combined with waste-heat boilers
• CPC Class Codes: C10K 1/024 by filtration
• CPC Class Codes: C10K 1/026 by centrifugal forces cyclones B04C

Abstract

Improvements in a gasification system and process for gasifying carbonaceous feedstock with improved energy efficiency. Improved methods and systems for more efficient removal of particulates from a raw synthesis gas while simultaneously providing a novel mechanism for fluxing agent addition to the gasification reactor. A conditioning agent, in the form of coarse fluxing agent particles, is added to the raw synthesis gas upstream from the particle filtration unit. The conditioning agent allows more rapid turnaround of the filtration unit following filter element replacement, extend filter life, facilitates the removal of filter cake from the particle filters, and combines with removed filter cake for recycling to the gasifier. Addition of fluxing agent via this route eliminates the need to premix fluxing agent with the carbonaceous feedstock, thereby maximizing the rate of feedstock addition to the gasification reactor.

Claims

1. A system for the gasification of a carbonaceous material, comprising:

a. a reactor for the gasification of a solid stream comprising particulate carbonaceous feedstock to produce heat and a mixture product comprising synthesis gas and char;

b. an initial separating device for separating said mixture product of part a) to create a gaseous product stream and a first solid product stream comprising char;

c. a coarse particulate fluxing agent having an average size in the range from 5 microns and 30 microns;

d. an entry point for the addition of a coarse particulate fluxing agent downstream from the initial separating device of part (b);

e. a particle filtration unit comprising a plurality of filter elements for filtering the gaseous product stream of part (b) and the coarse particulate fluxing agent of part (c) to retain residual particles of char, thereby creating a second solid product stream while allowing passage of said gaseous product stream of part (b), wherein the coarse particle fluxing agent decreases the permeability of the filter elements to entrained char from part (b), while maintaining permeability of synthesis gas, wherein the pluralit of filter elements are configured to allow passage of char particles and retain the coarse particulate fluxing agent;

f. piping for conducting the first and second solid streams, having;

a first terminus at the initial separating device of part (b) for conducting the first solid product stream of part b),

a second terminus at the particle filtration unit of part (c) for conducting the second solid product stream,

a connector for combining the first and second solid products streams,

a third terminus at the gasification reactor for allowing entry into the reactor of a mixture product comprising the first and second solid product streams, and the coarse particulate fluxing agent of part (c).

2. The system of claim 1, further comprising a heat recovery device placed upstream from the initial separating device of part (b), wherein said heat recovery device is selected from the group consisting of radiant heat type boiler, water tube boiler, fire tube boiler and combinations thereof.

6. The system of claim 1, further comprising a system configured to inject the coarse particulate fluxing agent through the entry point following a filter back-pulsing event.

8. The system of claim 1, wherein the entry point is immediately upstream of the particle filtration unit.

3. A system for the gasification of a carbonaceous material, comprising:

a. a reactor lower section for partially combusting a solid stream comprising particulate carbonaceous feedstock with a gas stream comprising an oxygen-containing gas to produce heat and a first mixture product comprising synthesis gas, char, and molten slag;

b. a reactor upper section for pyrolyzing said mixture product of part (a) with a first slurry stream comprising particulate carbonaceous material in a liquid carrier to produce a second mixture product comprising synthesis gas and char;

c. an initial separating device for separating said second mixture product of part (b) to create a gaseous product stream and a first solid product stream comprising char;

d. a coarse particulate fluxing agent having an average size in the range from 5 microns and 30 microns;

e. an entry point for the addition of the coarse particulate fluxing agent of part (d) downstream from the initial separating device of part (c);

f. a particle filtration unit comprising a plurality of filter elements for filtering the gaseous product stream of part (c) and the coarse particulate fluxing agent of part (d) to retain residual particles of char, thereby creating a second solid product stream while allowing passage of said gaseous product stream of part (b), wherein the coarse particle fluxing agent decreases the permeability of the filter elements to entrained char from part (b), while maintaining permeability of synthesis gas, wherein the plurality of filter elements are configured to allow passage of char particles and retain the coarse particulate fluxing agent;

g. piping for conducting the first and second solid streams, having;

a first terminus at the initial separating device of part (c) for conducting the first solid product stream of part b),

a second terminus at the particle filtration unit of part (f) for conducting the second solid product stream,

a connector for combining the first and second solid products streams,

a third terminus at the reactor lower section of part (a) for allowing entry into the reactor of a mixture product comprising the first and second solid product streams, and the coarse particulate fluxing agent of part (d).

4. The system of claim 3, further comprising a heat recovery device placed upstream from the initial separating device of part (c), wherein the heat recovery device is selected from a group consisting of radiant heat type boiler, water tube boiler, fire tube boiler and combinations thereof.

5. The system of claim 3, wherein the initial separating device comprises a cyclone, and the particle filtration unit comprises a candle filter.

7. The system of claim 3, further comprising a system configured to inject the coarse particulate fluxing agent through the entry point following a filter back-pulsing event.

9. The system of claim 3, wherein the entry point is immediately upstream of the particle filtration unit.