Smear resistant inkjet inks

• US 9,090,734 B2
• Filed: 11/10/2010
• Issued: 07/28/2015
• Est. Priority Date: 11/10/2009
• Status: Active Grant

• Current Assignee: DuPont Electronics, Inc. (DuPont de Nemours, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Kraiter, Daniel C., Valentini, Jose Esteban, Li, Xiaoqing
• Primary Examiner(s): Shah, Manish S
• Application Number:
  US13/508,554
• Publication Number:
  US 20120223999A1
• Time in Patent Office: 1,721 Days
• Field of Search: 347/100, 347/95, 347/96, 347/88, 347/99, 347/21, 347/20, 347/102, 347/103, 106/31.6, 106/31.13, 106/31.27, 523/160, 523/161
• US Class Current: 1/1
• CPC Class Codes: B41J 2/2107 characterised by the ink properties supplying ink in a solid state B41J2/17593
• CPC Class Codes: C08G 18/0823 containing carboxylate salt groups or groups forming them
• CPC Class Codes: C08G 18/0828 containing sulfonate groups or groups forming them
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/3228 acyclic
• CPC Class Codes: C08G 18/4018 Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
• CPC Class Codes: C08G 18/4202 Two or more polyesters of different physical or chemical nature C08G18/44 takes precedence
• CPC Class Codes: C08G 18/4211 derived from aromatic dicarboxylic acids and dialcohols
• CPC Class Codes: C08G 18/4277 Caprolactone and/or substituted caprolactone
• CPC Class Codes: C08G 18/44 Polycarbonates
• CPC Class Codes: C08G 18/4854 Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
• CPC Class Codes: C08G 18/6659 with compounds of group C08G18/34
• CPC Class Codes: C08G 18/6692 with compounds of group C08G18/34
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C09D 11/324 containing carbon black
• CPC Class Codes: C09D 11/326 characterised by the pigment dispersant

Abstract

Inkjet inks are provided, relating in particular to smear resistant inkjet inks, and even more particularly to smear resistant pigmented aqueous inkjet inks comprising polyurethane dispersions and self-dispersing pigments. The polyurethane dispersions have a glass transition temperature Tg greater than −30 ° C. to less than about 35 ° C. and have at least one of the following thermal properties: loss modulus E″ of 1.7 to 5×10⁸ pascals, and/or a peak tan delta is 0.23 to 0.65, where the glass transition temperature, peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

Claims

1. An aqueous ink jet ink composition, comprising from about 1% to about 20% by weight self dispersed pigment, and from about 1% to about 10% by weight of a polyurethane dispersion wherein the polyurethane dispersion has a glass transition temperature Tg greater than −

30°

C. to less than 35°

C. and has at least one of the following thermal properties

a. loss modulus E″

of 1.7 to 5 ×

10⁸ pascals,

b. peak tan delta is 0.23 to 0.65,

wherein the glass transition temperature Tg, peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

2. The aqueous ink jet ink composition of claim 1, where the polyurethane dispersion has loss modulus E″

of from 1.7 to 5 ×

10⁸pascals and the peak tan delta is from 0.23 to 0.65, wherein peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

3. An aqueous ink jet ink composition of claim 1, wherein the polyurethane dispersion has a loss modulus E″

of from 2.4 to 4.5 ×

10⁸ Pascal'"'"'s wherein the loss modulus is measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

4. An aqueous ink jet ink composition of claim 1, wherein the polyurethane dispersion has a peak tan delta from 0.24 to 0.45 wherein the peak tan delta is measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

5. An aqueous ink jet ink composition of claim 1, wherein the self-dispersed pigment is self-dispersed carbon black pigment comprising anionic hydrophilic chemical groups.

6. The ink of claim 5, wherein the anionic hydrophilic chemical groups on the self-dispersed carbon black pigment comprise carboxyl groups.

7. An aqueous ink jet ink composition of claim 1, wherein the self-dispersed pigment comprises a pigment that has been oxidatively treated on its surface with hypochlorous acid, sulfonic acid, or ozone so as to bond at least one functional group selected from the group consisting of carbonyl, carboxyl, hydroxyl and sulfone, onto the surface of the pigment.

8. The aqueous inkjet ink of claim 1, wherein the self-dispersed pigment comprises a pigment that has been oxidatively treated on its surface with ozone.

9. The aqueous inkjet ink of claim 1, wherein the polyurethane dispersion is an anionically stabilized polyurethane dispersion.

10. The aqueous inkjet ink of claim 1, wherein the polyurethane of the polyurethane dispersion has an acid number of 10 to 100 mg KOH/gram measured for polyurethane in the polyurethane dispersion.

11. The aqueous inkjet ink of claim 1, wherein the polyurethane of the polyurethane dispersion has weight average molecular weight of more than about 14,000.

12. An aqueous ink jet ink composition of claim 1 wherein the polyurethane of the polyurethane dispersion is substituted with a sulfonate ionic group.

13. The aqueous inkjet ink of claim 1, wherein a combination of two or more polyurethane dispersions is used.

14. The aqueous inkjet ink of claim 1, wherein the ink has a surface tension in the range of about 20 mN/m to about 70 mN/m at 25°

C., and a viscosity in the range of about 1 mPa·

s to about 30 mPa·

s at 25°

C.

20. The aqueous inkjet ink composition of claim 1, wherein T_g of the polyurethane is between 11°

C. and 34.5°

C. inclusive.

15. A process for inkjet printing comprising the step of jetting an ink onto a substrate, wherein the ink is an aqueous inkjet ink comprising from about 1% to about 20% by weight self dispersed pigment, and from about 1% to about 10% by weight of a polyurethane dispersion wherein the polyurethane dispersion has a glass transition temperature Tg greater than −

30°

C. to less than 35°

C. and has at least one of the following thermal properties

a. loss modulus E″

of 1.7 to 5×

10⁸ pascals,

b. peak tan delta is 0.23 to 0.65,

wherein the glass transition temperature Tg, peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

16. The process of claim 15, wherein the substrate is plain paper.

17. The process of claim 15, wherein the self-dispersed pigment is a self-dispersed carbon black.

18. The process of claim 15, wherein the polyurethane dispersion is an anionically stabilized polyurethane dispersion.

19. The process of claim 15, wherein the ink comprises from about 0.01 to about 10% by weight of pigment, and from 0.1 to about 10% by weight of polyurethane dispersion, based on the weight of the ink.