Electrochromic device with anti-iridescent coating

• US 9,091,896 B2
• Filed: 06/21/2011
• Issued: 07/28/2015
• Est. Priority Date: 06/21/2010
• Status: Active Grant

• Current Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Original Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Inventors: Ripberger, Ingolf, Letocart, Philippe, Orillard, Julien, Selles, Oliver
• Primary Examiner(s): TRA, TUYEN Q
• Application Number:
  US13/820,313
• Publication Number:
  US 20140085701A1
• Time in Patent Office: 1,498 Days
• Field of Search: 359265-275, 345/105
• US Class Current: 1/1
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10211 Doped dielectric layer, electrically conductive, e.g. SnO2:F
• CPC Class Codes: B32B 17/10513 Electrochromic layer
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: C03C 17/225 Nitrides
• CPC Class Codes: C03C 17/23 Oxides C03C17/02 takes precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2201/38 Anti-reflection arrangements

Abstract

The invention relates to a device (1) of the electrochromic type comprising successively a substrate (2), a reflection control coating (8), a laminating interlayer (10), a functional system (4) of the electrochromic type and a substrate (2). This particular arrangement of the laminating interlayer between the reflection control coating and the functional system and the choice of the refractive index and thickness of the reflection control coating are such that the saturation values of C* in the colorimetric system (L*, a*, b*) of the device in reflection are less than or equal to 10 for angles of incidence of 60° and 8° relative to the normal (N) to the outer face (6B) of the counter-substrate and that the absolute value of the difference between the value of C* at an angle of incidence of 8° and the value of C* at an angle of incidence of 60° is less than or equal to 6.

Claims

1. A device comprising:

a substrate;

an electrochemical functional system with electrocontrollable optical and/or energy properties, the functional system comprising;

a first electrode coating formed on the substrate;

a second electrode coating; and

at least one electrochemically active layer situated between the first electrode coating and the second electrode coating, at least one active electrochemical layer being capable of passing reversibly between a first state and a second state with optical and/or energy transmission properties different from the first state;

a counter-substrate designed to be disposed on the outside relative to the substrate, on the side of the incident sunlight;

a reflection control coating for attenuating/modifying the color of the device in reflection toward the outside, the reflection control coating being formed on the inner face of the counter-substrate, the reflection control system acting to reduce the saturation values of C* in the colorimetric system (L*, a*, b*) of the device in reflection;

a laminating interlayer made of polymeric material interposed between the reflection control coating and the functional system, the counter-substrate and the laminating interlayer having a refractive index between 1.4 and 1.7 and a thickness greater than 20 μ

m for the laminating interlayer,

the reflection control coating having a refractive index and thickness chosen so that C* is less than or equal to 10 for angles of incidence of 60° and

8°

relative to the normal (N) to the outer face of the counter-substrate and that the absolute value of the difference between the value of C* at an angle of incidence of 8° and

the value of C* at an angle of incidence of 60°

is less than or equal to 6.

2. The device of claim 1, wherein the reflection control coating has a refractive index and thickness chosen so that C* is less than or equal to 10 for an angle of incidence between 8°

and 60°

relative to the normal (N) to the outer face of the counter-substrate.

3. The device of claim 1, wherein reflection control coating comprises a single layer of material.

4. The device of claim 1, wherein the reflection control coating is in contact with the inner face of the counter-substrate.

5. The device of claim 1, wherein the reflection control coating is in contact with the outer face of the laminating interlayer.

6. The device of claim 1, wherein the reflection control coating comprises a layer having a refractive index of between 1.6 and 2.4.

7. The device of claim 6, wherein the refractive index of the reflection control coating is between 1.75 and 2.15.

8. The device of claim 6, wherein the refractive index of the reflection control coating is between 1.90 and 2.05.

9. The device of claim 6, wherein the thickness of the reflection control coating is between 60 nm and 110 nm.

10. The device of claim 6, wherein the thickness of the reflection control coating is between 60 nm and 90 nm.

11. The device of claim 1, wherein the reflection control coating has a coefficient of reflection greater than or equal to 10%.

12. The device of claim 11, wherein the reflection control coating consists of one or more materials chosen from the group consisting of silicon nitride, tin oxide, silicon oxynitride, zinc oxide, aluminum nitride, tin-doped indium oxide (ITO), tin/zinc mixed oxide, titanium oxide, zinc-doped titanium oxide, silicon-doped titanium oxide and combination thereof.

13. The device of claim 1, wherein the counter-substrate and the laminating interlayer having a refractive index of between 1.45 and 1.60.

14. The device of claim 1, wherein the laminating interlayer is a film comprising a thermoplastic material.

15. The device of claim 14, wherein the thermoplastic material is polyvinyl butyral (PVB).

16. The device of claim 14, wherein the thermoplastic material is acoustic polyvinyl butyral.

17. The device of claim 14, wherein the thermoplastic material is ethylene vinyl acetate (EVA).

18. The device of claim 14, wherein the thermoplastic material is a polymer which comprises an ionoplast interlayer.

19. The device of claim 1, wherein the functional system is an electrochromic system, and wherein at least one electrochemically active layer being electrochromic.

20. The device of claim 19, wherein the electrochromic functional system is of a solid state type.

21. A glazing pane comprising at least one sheet with a glazing function, wherein the glazing comprises the device of claim 1.

22. The device of claim 1, wherein the thickness of the laminating interlayer is greater than 100 μ

m.

23. The device of claim 1, wherein the thickness of the laminating interlayer is greater than 300 μ

m.

24. The device of claim 1, wherein the thickness of the counter-substrate is greater than 100 μ

m.

25. A method for producing a device, comprising the steps of:

forming a first electrode coating on a substrate;

forming a second electrode coating;

forming at least one electrochemically active layer designed to be situated between the first electrode coating and the second electrode coating, at least one electrochemically active layer being capable of passing reversibly between a first state and a second state with optical transmission and/or energy properties different from the first state,

forming a reflection control coating for modifying/attenuating the color of the device in reflection toward the outside, the reflection control coating being formed on the inner face of a counter-substrate, the counter-substrate being designed to be disposed on the outside relative to substrate, on the side of the incident sunlight, the reflection control coating acting to reduce the saturation values of C* in the colorimetric system (L*, a*, b*) of the device in reflection;

using a laminating interlayer made of polymeric material for laminating the counter-substrate, the laminating interlayer being between the reflection control coating and the functional system, the counter-substrate and the laminating interlayer having a refractive index of between 1.4 and 1.7 and a thickness greater than 20 μ

m,

the reflection control coating having a refractive index and thickness chosen so that C* is less than or equal to 10 for angles of incidence of 60° and

8°

relative to the normal (N) to the outer face of the counter-substrate and that the absolute value of the difference between the value of C* at an angle of incidence of 8° and

the value of C* at an angle of incidence of 60°

is less than or equal to 6.

26. The method of claim 25, wherein the thickness of the laminating interlayer is greater than 100 μ

m.

27. The method of claim 25, wherein the thickness of the laminating interlayer is greater than 300 μ

m.

28. A device comprising:

a substrate;

an electrochemical functional system with electrocontrollable optical and/or energy properties, the functional system comprising;

a first electrode coating formed on the substrate;

a second electrode coating; and

at least one electrochemically active layer situated between the first electrode coating and the second electrode coating, at least one active electrochemical layer being capable of passing reversibly between a first state and a second state with optical and/or energy transmission properties different from the first state;

a counter-substrate designed to be disposed on the outside relative to the substrate, on the side of the incident sunlight;

a reflection control coating for attenuating/modifying the color of the device in reflection toward the outside, the reflection control coating being formed on the inner face of the counter-substrate the reflection control system acting to reduce the saturation values of C* in the colorimetric system (L*, a*, b*) of the device in reflection;

a laminating interlayer made of polymeric material interposed between the reflection control coating and the functional system, the counter-substrate and the laminating interlayer having a refractive index between 1.4 and 1.7 and a thickness greater than 20 μ

m for the laminating interlayer,

wherein the reflection control coating has a refractive index and thickness chosen so that C* is less than or equal to 10 for angles of incidence of 60° and

8°

relative to the normal (N) to the outer face of the counter-substrate and that the absolute value of the difference between the value of C* at an angle of incidence of 8° and

the value of C* at an angle of incidence of 60°

is less than or equal to 6; and

wherein the coefficient of reflection is between 12% and 25%.