MultiLayer solid electrolyte for lithium thin film batteries

• US 9,093,707 B2
• Filed: 06/11/2007
• Issued: 07/28/2015
• Est. Priority Date: 06/11/2007
• Status: Active Grant

• Current Assignee: Alliance For Sustainable Energy LLC
• Original Assignee: Alliance For Sustainable Energy LLC
• Inventors: Lee, Se-Hee, Tracy, C. Edwin, Pitts, John Roland, Liu, Ping
• Primary Examiner(s): Crepeau, Jonathan
• Application Number:
  US11/816,730
• Publication Number:
  US 20100285372A1
• Time in Patent Office: 2,969 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: H01M 10/0436 Small-sized flat cells or batteries for portable equipment
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0562 Solid materials
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 2300/0068 inorganic
• CPC Class Codes: H01M 2300/0094 in the form of layered products, e.g. coatings
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 6/185 with oxides, hydroxides or oxysalts as solid electrolytes
• CPC Class Codes: H01M 6/187 Solid electrolyte characterised by the form
• CPC Class Codes: H01M 6/20 working at high temperature deferred-action thermal cells H01M6/36
• CPC Class Codes: H01M 6/24 Cells comprising two different electrolytes
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A lithium metal thin-film battery composite structure is provided that includes a combination of a thin, stable, solid electrolyte layer [18] such as Lipon, designed in use to be in contact with a lithium metal anode layer; and a rapid-deposit solid electrolyte layer [16] such as LiAlF₄ in contact with the thin, stable, solid electrolyte layer [18]. Batteries made up of or containing these structures are more efficient to produce than other lithium metal batteries that use only a single solid electrolyte. They are also more resistant to stress and strain than batteries made using layers of only the stable, solid electrolyte materials. Furthermore, lithium anode batteries as disclosed herein are useful as rechargeable batteries.

Claims

1. A rechargeable lithium battery device comprising:

an anode current collector comprising a metal material selected from copper, nickel, chrome ferrous alloy, a refractory metal, or stainless steel, the metal material being substantially inert toward a lithium metal material;

an anode overlaying the anode current collector, and the anode being electrically coupled to the current collector and comprising lithium metal material;

a first electrolyte layer overlaying the anode consisting of Li₂S, Li₂O, or combinations thereof, the first electrolyte layer being substantially stable toward lithium metal material, the first electrolyte layer being characterized by a first deposition rate and a thickness of 10-100 nm;

a second electrolyte layer in direct contact with the first electrolyte layer and comprising at least one of lithium nitride, lithium fluoride, or lithium aluminum fluoride, the second electrolyte layer being characterized by a second deposition rate;

a cathode overlaying the second electrolyte layer; and

a cathode current collector overlaying the cathode;

wherein the first electrolyte layer and the second electrolyte layer are characterized by a total thickness of less than 20 um.

2. The device of claim 1 wherein the anode current collector is characterized by a thickness of about 50-500 nm.

3. The device of claim 1 wherein the anode current collector further comprises a non-conductive substrate material, the metal material overlaying a surface of the non-conductive substrate material.

4. The device of claim 1 wherein the metal material comprises a transition metal material.

5. The device of claim 1 wherein the first electrolyte layer being useful for up to 1000 cycles.

6. The device of claim 1 wherein the first deposition rate is from about 5 nm/min to about 15 nm/min.

7. The device of claim 1 wherein the first electrolyte layer is formed by a vapor deposition process.

8. The device of claim 1 wherein the second electrolyte layer further comprises a polymer material.

9. The device of claim 8 wherein the cathode comprises material selected from lithium vanadate, lithium manganate, lithium nickelate, lithium cobaltate, lithium molybdenum oxide, or lithium titanium oxide.

10. The device of claim 1 wherein the cathode is characterized by a thickness of about 50 nm to about 5000 nm.

11. The device of claim 1 wherein the cathode is formed by deposition on the cathode current collector.

12. The device of claim 1 wherein the cathode current collector comprises at least one of copper, aluminum, gold, chrome ferrous alloy, or refractory metals.

13. The device of claim 1 wherein the cathode current collector is characterized by a thickness of about 50-500 nm.

14. The device of claim 1 wherein the second electrolyte layer is formed by a rapid deposition process.

15. The device of claim 1 wherein the second electrolyte layer further comprises at least one of a polyether, a polyimine, a polythioether, a polyphosphazene, or a polymer blend.

16. The device of claim 1 wherein the second electrolyte layer is substantially free from liquid.

17. The device of claim 1 wherein the second deposition rate is about 1000 nm/min.

18. The device of claim 1 wherein the second electrolyte layer being characterized by a thickness of 650-1000 nm.

19. The device of claim 1 wherein the second deposition rate is higher than the first deposition rate.