Carbon dioxide capture method and facility

• US 9,095,813 B2
• Filed: 08/21/2009
• Issued: 08/04/2015
• Est. Priority Date: 08/21/2008
• Status: Active Grant

• Current Assignee: Carbon Engineering ULC (Occidental Petroleum Corporation)
• Original Assignee: Carbon Engineering Limited Partnership
• Inventors: Keith, David, Mahmoudkhani, Maryam, Biglioli, Alessandro, Hart, Brandon, Heidel, Kenton, Foniok, Mike
• Primary Examiner(s): MCKENZIE, THOMAS B
• Application Number:
  US12/545,579
• Publication Number:
  US 20100064890A1
• Time in Patent Office: 2,174 Days
• Field of Search: 95149-240, 96234-233, 96243-371, 261 19- 74
• US Class Current: 1/1
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/306 of potassium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 53/77 Liquid phase processes
• CPC Class Codes: B01F 23/214 using a gas-liquid mixing column or tower
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A carbon dioxide capture facility is disclosed comprising packing formed as a slab, and at least one liquid source. The slab has opposed dominant faces, the opposed dominant faces being at least partially wind penetrable to allow wind to flow through the packing. The at least one liquid source is oriented to direct carbon dioxide absorbent liquid into the packing to flow through the slab. The slab is disposed in a wind flow that has a non-zero incident angle with one of the opposed dominant faces. A method of carbon dioxide capture is also disclosed. Carbon dioxide absorbing liquid is applied into packing in a series of pulses. A gas containing carbon dioxide is flowed through the packing to at least partially absorb the carbon dioxide from the gas into the carbon dioxide absorbing liquid.

Claims

1. A method for removing carbon dioxide from ambient air with a carbon dioxide capture facility, comprising:

providing a liquid having a capacity to absorb carbon dioxide;

providing a packing material comprising a plurality of flow passages;

positioning the packing material such that ambient air flows in a direction from a first opposed dominant face through the plurality of flow passages to a second opposed dominant face opposite the first dominant face;

positioning a fan to influence flow of the ambient air through at least a section of one of the first or second opposed dominant faces of the packing material, the packing material having a dimension between the first and second opposed dominant faces that is parallel to the flow of the ambient air between about 1 meter and about 15 meters;

circulating, with the fan, the ambient air comprising atmospheric carbon dioxide through the plurality of flow passages of the packing material;

applying, with a pump, the liquid over the packing material at a first flow rate of the liquid during a first portion of a time duration, the first portion comprising a sufficient time duration to substantially replace a previous portion of the liquid on the packing with a new portion of the liquid that has a greater carbon dioxide absorption rate than the previous portion of the liquid;

applying, with the pump, the liquid over the packing material at a second flow rate of the liquid applied during a second portion of the time duration; and

absorbing at least a portion of the atmospheric carbon dioxide with the liquid at a predetermined duty cycle based on the time duration.

2. The method of claim 1, further comprising:

positioning the packing material such that the flow of the liquid through the packing material is in a mean flow direction that is parallel to a plane defined by the first and second opposed dominant faces.

3. The method of claim 2, wherein positioning the packing material such that the flow of the liquid through the packing material is in a mean flow direction that is parallel to a plane defined by the first and second opposed dominant faces comprises:

positioning the packing material to allow the liquid to flow through the packing material by gravity.

4. The method of claim 2, further comprising:

positioning the packing material such that the first and second opposed dominant faces are vertically oriented.

5. The method of claim 1, wherein the dimension ranges from about 1 meter to about 3 meters.

6. The method of claim 1, further comprising:

selectively controlling a speed or a direction of the fan based on a direction of wind incident on the packing material.

7. The method of claim 6, wherein the fan comprises a part of a fan wall adjacent at least one of the first or second opposed dominant faces of the packing material.

8. The method of claim 1, further comprising:

connectively positioning a plurality of modular structures containing the packing material in the carbon dioxide capture facility.

9. The method of claim 8, wherein each modular structure comprises dimensions of about 5 meters by about 5 meters by about 7 meters, the method further comprising:

interconnecting the plurality of modular structures to result in a carbon dioxide capture facility in which the packing material occupies a space having dimensions of about 200 meters by about 20 meters by about 3 meters.

10. The method of claim 1, wherein the liquid comprises a hydroxide solution.

11. The method of claim 10, wherein the hydroxide solution comprises a sodium hydroxide solution.

12. The method of claim 1, wherein the second flow rate is substantially zero.

13. The method of claim 1, wherein the predetermined duty cycle is between 1-50% such that the first portion of the time duration is between about 1% of the time duration and about 50% of the time duration.

14. The method of claim 1, further comprising

positioning the fan to influence flow of the ambient air through at least a portion of the packing material during the second portion of the time duration.

15. The method of claim 1, wherein the liquid and the packing material are configured to cooperatively achieve a liquid holdup that provides an increased carbon dioxide capture rate relative to the carbon dioxide capture facility operating with the pump constantly at a flow rate substantially equal to an average flow rate of the first and second flow rates.

16. The method of claim 1, wherein the first and second portions of the time duration are distinct in value.

17. The method of claim 1, further comprising circulating, with the pump, the liquid through a liquid distributor system and to the packing material.

18. The method of claim 1, wherein the packing material comprises structured packing.