Fuel cell system containing anode tail gas oxidizer and hybrid heat exchanger/reformer

• US 9,105,894 B2
• Filed: 09/05/2013
• Issued: 08/11/2015
• Est. Priority Date: 02/19/2008
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Perry, Martin, Venkataraman, Swaminathan
• Primary Examiner(s): ZARROLI, MICHAEL C
• Application Number:
  US14/018,963
• Publication Number:
  US 20140057188A1
• Time in Patent Office: 705 Days
• Field of Search: 429/423, 429/425
• US Class Current: 1/1
• CPC Class Codes: C01B 2203/066 with fuel cells
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0618 Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: H01M 8/0631 Reactor construction specially adapted for combination reactor/fuel cell hydrogen C01B3/00; reactors for physicochemical processes B01J19/00
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell system includes at least one fuel cell stack, a fuel inlet conduit, and a fuel heat exchanger containing a fuel reformation catalyst. The fuel heat exchanger is connected to the fuel inlet conduit and to at least one fuel cell system exhaust conduit which in operation provides a high temperature exhaust stream to the fuel heat exchanger. The fuel heat exchanger is thermally integrated with an anode tail gas oxidizer (ATO) exhaust conduit such that in operation an ATO exhaust stream in the ATO exhaust conduit heats a fuel inlet stream passing through the heat exchanger.

Claims

1. A method of operating fuel cell system, comprising:

providing a hydrocarbon fuel inlet stream into a fuel heat exchanger containing a fuel reformation catalyst;

reforming the hydrocarbon fuel in the fuel heat exchanger;

providing a reformed fuel from the fuel heat exchanger into at least one fuel cell stack;

providing at least one exhaust stream from the at least one fuel cell stack into the fuel heat exchanger to exchange heat with the hydrocarbon fuel inlet stream;

providing an exhaust stream from the anode tail gas oxidizer through an air heat exchanger; and

providing the exhaust stream from the anode tail gas oxidizer exiting the air heat exchanger to steam generator.

2. The method of claim 1, wherein the at least one exhaust stream comprises a fuel exhaust stream, and the at least one fuel cell stack comprises at least one solid oxide fuel cell stack.

3. The method of claim 1, wherein the fuel heat exchanger comprises a multi-stream heat exchanger which contains passages for at least three flow streams.

4. The method of claim 3, further comprising:

providing the hydrocarbon fuel inlet stream and an air inlet stream through the multi-stream heat exchanger to the at least one fuel cell stack;

providing a fuel inlet stream to the anode tail gas oxidizer;

providing a cathode exhaust stream from the at least one fuel cell stack to the anode tail gas oxidizer; and

providing an exhaust stream from the anode tail gas oxidizer and a fuel exhaust stream from the at least one fuel cell stack into the multi-stream heat exchanger to heat the hydrocarbon fuel inlet stream and the air inlet stream.

5. The method of claim 4, wherein the at least one fuel cell stack, the anode tail gas oxidizer, and the multi-stream heat exchanger are located inside a hotbox.

6. The method of claim 1, wherein the fuel heat exchanger comprises fins coated with the fuel reformation catalyst.

7. The method of claim 6, wherein the fuel reformation catalyst comprises at least one of nickel or rhodium.

8. The method of claim 7, wherein rhodium is located in a leading segment and nickel is located in a trailing segment of the fuel heat exchanger.

9. The method of claim 8, further comprising switching the hydrocarbon fuel inlet stream between a higher and a lower hydrocarbon fuel inlet stream.

13. The method of claim 1, further comprising:

providing a mixture of the first exhaust stream and steam to the hydrocarbon fuel inlet stream.

14. The method of claim 1, wherein:

the exhaust stream is provided from the anode tail gas oxidizer through the air heat exchanger to exchange heat with an air;

the exhaust stream is provided from the anode tail gas oxidizer exiting the air heat exchanger to heat steam; and

further comprising providing the heated steam into the hydrocarbon fuel inlet stream.

15. The method of claim 1, further comprising:

providing the at least one exhaust stream to an air pre-heater to exchange heat with air.

16. The method of claim 1, further comprising:

providing the at least one exhaust stream to an air pre-heater to exchange heat with air.

17. The method of claim 1, further comprising:

splitting the at least one exhaust stream exiting from the fuel heat exchanger into at least two streams, a first exhaust stream being provided to the hydrocarbon fuel inlet stream, and a second exhaust stream being provided to an anode tail gas oxidizer.

10. A method of operating a fuel cell system, comprising:

providing a first fuel inlet stream and an air exhaust stream into an anode tail gas oxidizer, the air exhaust stream being generated by a fuel cell stack;

oxidizing the first fuel inlet stream in the anode tail gas oxidizer;

providing a second fuel inlet stream into a fuel heat exchanger;

providing a fuel exhaust stream from the fuel cell stack into the fuel heat exchanger;

heating the second fuel inlet stream in the fuel heat exchanger using both the fuel exhaust stream and the an exhaust stream from the anode tail gas oxidizer; and

providing the second fuel inlet stream into the fuel cell stack after heating the second fuel inlet stream.

11. The method of claim 10, wherein heating the second fuel inlet stream comprises passing the exhaust stream from the anode tail gas oxidizer adjacent to a wall of the fuel heat exchanger.

12. The method of claim 10, further comprising providing the exhaust stream from the anode tail gas oxidizer into an air heat exchanger and heating an air inlet stream in the air heat exchanger using the exhaust stream from the anode tail gas oxidizer.

18. The method of claim 10, further comprising reforming the second fuel inlet stream in the fuel heat exchanger.

19. A method of operating fuel cell system, comprising:

providing a hydrocarbon fuel inlet stream into a fuel heat exchanger containing a fuel reformation catalyst;

reforming the hydrocarbon fuel in the fuel heat exchanger;

providing a reformed fuel from the fuel heat exchanger into at least one fuel cell stack;

providing at least one exhaust stream from the at least one fuel cell stack into the fuel heat exchanger to exchange heat with the hydrocarbon fuel inlet stream; and

splitting the at least one exhaust stream exiting from the fuel heat exchanger into at least two streams, a first exhaust stream being provided to the hydrocarbon fuel inlet stream, and a second exhaust stream being provided to an anode tail gas oxidizer.