Hybrid copolymer compositions

• US 9,109,068 B2
• Filed: 07/30/2010
• Issued: 08/18/2015
• Est. Priority Date: 07/21/2005
• Status: Active Grant

• Current Assignee: Nouryon Chemicals International B.V. (Nouryon BV)
• Original Assignee: Akzo Nobel N.V. (Nouryon BV)
• Inventors: Rodrigues, Klin A., Vanderhoof, Matthew M., Carrier, Allen M., Sanders, Jannifer
• Primary Examiner(s): Heincer, Liam J
• Assistant Examiner(s): HILL, NICHOLAS E
• Application Number:
  US13/387,882
• Publication Number:
  US 20120128608A1
• Time in Patent Office: 1,845 Days
• Field of Search: 524/31, 525/54.3, 210/702, 526/200, 252/175, 510/247
• US Class Current: 1/1
• CPC Class Codes: C02F 5/10 using organic substances
• CPC Class Codes: C08F 2/38 Polymerisation using regulators, e.g. chain terminating agents , e.g. telomerisation
• CPC Class Codes: C08F 251/00 Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
• CPC Class Codes: C08F 251/02 on to cellulose or derivatives thereof
• CPC Class Codes: C08F 289/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C08L 51/02 grafted on to polysaccharides
• CPC Class Codes: C11D 3/222 Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
• CPC Class Codes: C11D 3/3788 Graft polymers
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

Hybrid copolymer compositions include a hybrid copolymer including at least one ethylenically unsaturated monomer and a naturally derived hydroxyl containing chain transfer agent as an end group; and a hybrid synthetic copolymer including one or more synthetic polymers derived from the at least one ethylenically unsaturated monomer with at least one initiator fragment as an end group. The hybrid copolymer composition may be prepared as a scale inhibiting composition. Methods of preparing a hybrid copolymer are also included.

Claims

1. An anionic hybrid copolymer composition comprising:

a hybrid copolymer derived from at least one anionic ethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, α

-chloro-acrylic acid, α

-cyano acrylic acid, β

-methyl-acrylic acid, α

-phenyl acrylic acid, β

-acryloxy propionic acid, sorbic acid, α

-chloro sorbic acid, angelic acid, cinnamic acid, p-chloro cinnamic acid, β

-styryl acrylic acid, itaconic acid, maleic acid, citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, fumaric acid, tricarboxy ethylene, muconic acid, 2-acryloxypropionic acid, 2-acrylamido-2-methyl propane sulfonic acid, vinyl sulfonic acid, sodium methallyl sulfonate, sulfonated styrene, allyloxybenzene sulfonic acid, vinyl phosphonic acid, and mixtures thereof; and

a naturally derived hydroxyl containing chain transfer agent as an end group, wherein the chain transfer agent is obtained from a renewable source; and

a hybrid synthetic copolymer derived from the at least one anionic ethylenically unsaturated monomer with at least one initiator fragment as an end group, said hybrid synthetic copolymer having the structure;

2. The anionic hybrid copolymer composition of claim 1 wherein the chain transfer agent is selected from the group consisting of cellulose, derivatives of cellulose, inulin, and derivatives of inulin.

3. The anionic hybrid copolymer composition of claim 1 wherein the hybrid copolymer is water soluble.

4. The anionic hybrid copolymer composition of claim 1 wherein the hybrid copolymer has an average molecular weight of about 100,000 or less.

5. The anionic hybrid copolymer composition of claim 1 wherein the chain transfer agent has a molecular weight of about 100,000 or less.

6. The anionic hybrid copolymer composition of claim 1 wherein I is derived from a water soluble initiator.

7. The anionic hybrid copolymer composition of claim 1 wherein I is a fragment from an azo or peroxide initiator, with the proviso that the fragment is not an hydroxyl group.

8. The anionic hybrid copolymer composition of claim 1 wherein the at least one anionic ethylenically unsaturated monomer further comprises at least one ester monomer.

9. The anionic hybrid copolymer composition of claim 8 wherein the at least one ester monomer is derived from a dicarboxylic acid or is selected from the group consisting of monomethylmaleate, dimethylmaleate, monomethylitaconate, dimethylitaconate, monoethylmaleate, diethylmaleate, monoethylitaconate, diethylitaconate, monobutylmaleate, dibutylmaleate, monobutylitaconate and dibutylitaconate.

10. The composition of claim 1 wherein the chain transfer agent is present in amounts greater than 85% by weight to about 99% by weight, based on the total weight of the hybrid copolymer.

11. The composition of claim 1 wherein the chain transfer agent is present in amounts greater than 90% by weight to about 99% by weight, based on the total weight of the hybrid copolymer.

12. A formulation comprising the anionic hybrid copolymer composition of claim 1, wherein the formulation is selected from the group consisting of a cleaning formulation, a superabsorbent formulation, a fiberglass binder formulation, a rheology modifier formulation, an oil field formulation, a personal care formulation, a water treatment formulation, a dispersant formulation, a scale inhibiting formulation, a cement formulation and a concrete formulation.

13. The formulation of claim 12 wherein the formulation is the cleaning formulation and said cleaning formulation is a detergent, fabric cleaner, automatic dishwashing detergent, glass cleaner, rinse aids, fabric care formulation, fabric softener, flocculant, coagulant and emulsion breaker, a hard surface cleaner or a laundry detergent.

14. The formulation of claim 13 wherein formulation is the automatic dishwashing detergent and said automatic dishwashing detergent is substantially free of phosphates, low foaming non-ionic surfactants, glutamic acid N,N-diacetic acid or methylglycine N,N-diacetic acid or combinations thereof.

15. The formulation of claim 14 further comprising alkali metal or alkali-metal earth carbonates, citrates or silicates.

16. A scale inhibiting composition for aqueous systems, comprising an anionic hybrid copolymer composition wherein said anionic hybrid copolymer composition comprises:

a hybrid copolymer derived from at least one anionic ethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, α

-chloro-acrylic acid, α

-cyano acrylic acid, β

-methyl-acrylic acid, α

-phenyl acrylic acid, β

-acryloxy propionic acid, sorbic acid, α

-chloro sorbic acid, angelic acid, cinnamic acid, p-chloro cinnamic acid, β

-styryl acrylic acid, itaconic acid, maleic acid, citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, fumaric acid, tricarboxy ethylene, muconic acid, 2-acryloxypropionic acid, 2-acrylamido-2-methyl propane sulfonic acid, vinyl sulfonic acid, sodium methallyl sulfonate, sulfonated styrene, allyloxybenzene sulfonic acid, vinyl phosphonic acid, and mixtures thereof; and

a naturally derived hydroxyl containing chain transfer agent as an end group, wherein the chain transfer agent is obtained from a renewable source; and

a hybrid synthetic copolymer derived from the at least one anionic ethylenically unsaturated monomer with at least one initiator fragment as an end group, said hybrid synthetic copolymer having the structure;

17. The scale inhibiting composition of claim 16 wherein the chain transfer agent is selected from the group consisting of cellulose, derivatives of cellulose, inulin, and derivatives of inulin.

18. The scale inhibiting composition of claim 16 wherein the hybrid copolymer composition is water soluble.

19. The scale inhibiting composition of claim 16 wherein the anionic hybrid copolymer composition has an average molecular weight of less than 100,000.

20. The scale inhibiting composition of claim 16 wherein the chain transfer agent has a molecular weight of less than 100,000.

21. The scale inhibiting composition of claim 16 wherein I is derived from a water soluble initiator.

22. The scale inhibiting composition of claim 16 wherein I is a fragment from an azo or peroxide initiator, with the proviso that the fragment is not an hydroxyl group.

23. The scale inhibiting composition of claim 16 wherein the hybrid copolymer has an absorption in a range of from about 300 to about 800 nanometers when activated.

24. The scale inhibiting composition of claim 16 wherein the at least one anionic ethylenically unsaturated monomer further comprises at least one ester monomer.

25. The scale inhibiting composition of claim 24 wherein the at least one ester monomer is derived from a dicarboxylic acid or is selected from the group consisting of monomethylmaleate, dimethylmaleate, monomethylitaconate, dimethylitaconate, monoethylmaleate, diethylmaleate, monoethylitaconate, diethylitaconate, monobutylmaleate, dibutylmaleate, monobutylitaconate and dibutylitaconate.

26. The scale inhibiting composition of claim 16 wherein said composition has greater than 80% carbonate inhibition at a 25 ppm dosage level of the hybrid copolymer in said aqueous system.

27. The scale inhibiting composition of claim 16 wherein the chain transfer agent is present in amounts greater than 85% by weight to about 99% by weight, based on the total weight of the hybrid copolymer.

28. The scale inhibiting composition of claim 16 wherein the chain transfer agent is present in amounts greater than 90% by weight to about 99% by weight, based on the total weight of the hybrid copolymer.

29. A method of inhibiting scale formation in an aqueous system, said method comprising adding to said aqueous system a scale inhibiting effective amount of the scale inhibiting composition of claim 16.