Fire resistant glazing

• US 9,109,164 B2
• Filed: 10/12/2010
• Issued: 08/18/2015
• Est. Priority Date: 10/13/2009
• Status: Active Grant

• Current Assignee: Pilkington Group Limited
• Original Assignee: Pilkington Group Limited
• Inventors: Cheung, Angela Yuk Fungt, Varma, Karikath Sukumar, Holden, David William, Holland, John Richard, Bond, Stephen Ian
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US13/261,262
• Publication Number:
  US 20120208921A1
• Time in Patent Office: 1,771 Days
• Field of Search: 523/179, 428/428, 428/332, 428/429, 427/389.7, 156/99
• US Class Current: 1/1
• CPC Class Codes: B32B 17/069 of intumescent material B32B17/10311 takes precedence
• CPC Class Codes: C09K 21/02 Inorganic materials

Abstract

A transparent fire resistant glazing comprising an intumescent interlayer, wherein the intumescent interlayer comprises an alkali metal silicate and a foam improvement additive, wherein the foam improvement additive comprises a polymer and/or oligomer and/or salts thereof, wherein said polymer, oligomer and/or salts thereof each contain at least one organic moiety having at least one hydrogen-bondable functional group covalently attached thereto.

Claims

1. A transparent fire resistant glazing comprising an intumescent interlayer sandwiched between two opposed glass panes, wherein the intumescent interlayer comprises an alkali metal silicate mixed with a foam improvement additive, wherein the foam improvement additive comprises a polymer and/or oligomer and/or salts thereof, wherein said polymer, oligomer and/or salts thereof each contain at least one organic moiety having at least one hydrogen-bondable functional group covalently attached thereto, and wherein the additive is polymerised in-situ.

2. The fire resistant glazing as claimed in claim 1, wherein the additive comprises a polymer network extending through a portion of the interlayer.

3. The fire resistant glazing as claimed in claim 1, wherein the additive is selected from the group consisting of dextran, poly(vinyl alcohol), poly(ethylene glycol), gum arabic, carboxymethyl cellulose, poly(acrylic acid), poly(acrylic acid) sodium salt, poly(acrylic acid) potassium salt, poly(acrylic acid) lithium salt, poly(acrylic acid-co-maleic acid), poly(acrylic acid-co-maleic acid) sodium salt, polymethacrylic acid, polymethacrylamide, polyaspartate, alkyl polyglucoside, polyasparagine and their derivatives.

4. The fire resistant glazing as claimed in claim 1, wherein the additive is a hydrophilic polymer.

5. The fire resistant glazing as claimed in claim 1, wherein the additive is substantially soluble in water.

6. The fire resistant glazing as claimed in claim 1, wherein the polymerisation of the additive is thermally initiated.

7. The fire resistant glazing as claimed in claim 1, wherein polymerisation of the additive comprises polymerisation of at least one precursor of formula

8. The fire resistant glazing as claimed in claim 7, wherein polymerisation of the additive comprises polymerisation of at least one precursor of formula

9. The fire resistant glazing as claimed in claim 7, wherein the precursor is a (meth)acrylate or a (meth)acrylamide.

10. The fire resistant glazing as claimed in claim 7, wherein the precursor is selected from sodium(meth)acrylate, potassium(meth)acrylate, ammonium(meth)acrylate, (meth)acrylic acid, itaconic acid, maleic acid, (meth)acrylic acid, maleic acid coprecursor, glycerol 1,3-diglycerolate di(meth)acrylate, diurethane di(meth)acrylate, 3-(Acryloyloxy)-2-hydroxypropyl(meth)acrylate, and N,N′

-(1,2)-dihydroxyethylene)-bis(meth)acrylamide.

11. The fire resistant glazing as claimed in claim 7, wherein the additive is polymerised from a mixture of precursors.

12. The fire resistant glazing as claimed in claim 1, wherein the alkali metal silicate comprises sodium silicate, and wherein the sodium silicate has a molar ratio SiO₂:

Na₂O of 2.0;

1 to 4.0;

1.

13. The fire resistant glazing as claimed in claim 1, wherein the alkali metal silicate comprises potassium silicate, and wherein the potassium silicate has a molar ratio SiO₂:

K₂O from 1.4;

1 to 2.0;

1.

14. The fire resistant glazing as claimed in claim 1, wherein the content of additive is less than 5% by weight.

15. The fire resistant glazing as claimed in claim 14, wherein the content of additive is less than 0.5% by weight.

17. The fire resistant glazing as claimed in claim 1, wherein the interlayer has a total water content in the range of 20 to 60% by weight.

16. A process for the production of transparent fire resistant glazing, the process comprising,

a) providing two opposed glass panes,

b) providing an aqueous solution of an alkali metal silicate and at least one foam improvement additive between and in contact with the two opposed glass panes, and

c) polymerising the foam improvement additive in-situ to form a polymer and/or oligomer and/or salts thereof, wherein said polymer, oligomer and/or salts thereof each contain at least one organic moiety having at least one hydrogen-bondable functional group covalently attached thereto.