Reactant delivery to a reactive surface in a channel

• US 9,112,192 B2
• Filed: 03/05/2010
• Issued: 08/18/2015
• Est. Priority Date: 03/06/2009
• Status: Active Grant

• Current Assignee: Brown University
• Original Assignee: Brown University
• Inventors: Palmore, Tayhas, Lim, Keng Guan
• Primary Examiner(s): RHEE, JANE J
• Application Number:
  US12/718,444
• Publication Number:
  US 20100323262A1
• Time in Patent Office: 1,992 Days
• Field of Search: 429/443
• US Class Current: 1/1
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/0265 the reactant or coolant channels having varying cross sections
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1011 Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention provides geometric arrangements for channels through which liquids or other fluids can be made to flow, for enhanced performance of fuel cells or other chemical or biochemical reactors or analyzers. Systems and methods including these improved geometries are described herein for enhanced performance of a variety of devices. Specifically, in one set of embodiments, the reactors comprise one or more microchannels comprising a tapered cross-sectional area and at least one reactive surface portion. By flowing a liquid comprising one or more reactants through the channel such that the cross-sectional area decreases in a downstream direction, relatively more reactant may be supplied to the wall at downstream positions relative to the amount that would be supplied in a system without a tapered cross-section. In some embodiments, the microchannel may be constructed and arranged such that the amount of reactant supplied to the wall conforms to a predetermined distribution.

Claims

1. A method, comprising:

providing an enclosed microchannel wherein the microchannel comprises;

a first microchannel segment with a first cross-sectional area,

a second microchannel segment with a second cross-sectional area that is smaller than the first cross-sectional area, and

a surface comprising a reactive surface portion; and

flowing a liquid through the microchannel from the first segment to the second segment, wherein the liquid comprises at least one reactant capable of chemically or biologically reacting at the reactive surface portion of the microchannel,

wherein the distance between the surface comprising the reactive surface portion and an opposing surface is larger at a first point on the surface comprising the reactive surface portion than at a second point on the surface comprising the reactive surface portion directly downstream of the first point, and

wherein the distance between the surface comprising a reactive surface portion and an opposing surface decreases at a rate of at least about 1;

500.

2. A method as in claim 1, wherein the microchannel is part of a fuel cell.

3. A method as in claim 1, wherein the reactive surface portion comprises an electrode.

4. A method as in claim 1, wherein the ratio of the distances between two opposing surfaces measured at a first point on one of the two opposing surfaces and a second point on the same surface and directly downstream of the first point is at least about 1.5:

1.

5. A method as in claim 1, wherein the cross-sectional area of the channel decreases by at least about 5% over a length substantially parallel to the average direction of fluid flow of less than about 100 mm.

6. A method as in claim 1, wherein the reactive surface portion comprises a catalyst.

7. A method as in claim 1, wherein a catalyst is immobilized on the reactive surface portion.

8. A method as in claim 1, wherein the reactive surface portion comprises a second reactant.

9. A method as in claim 1, wherein a second reactant is immobilized on the reactive surface portion.

10. A method as in claim 1, wherein a binding partner is immobilized on the reactive surface portion.

11. A method as in claim 1, wherein the at least one reactant comprises a biological molecule capable of binding to a second biological molecule.

12. A method as in claim 1, wherein the reactant comprises a protein.

13. A method as in claim 1, wherein chemically or biologically reacting comprises decomposing a reactant into one or more products.

14. A method as in claim 1, wherein chemically or biologically reacting comprises forming one or more products from a first reactant and a second reactant using a catalyst.

15. A method as in claim 1, wherein the reactant comprises a fuel.

16. A method as in claim 1, wherein the reactant comprises a hydrocarbon.

17. A method as in claim 1, wherein the reactant comprises methanol.

18. A method as in claim 1, wherein the reactant comprises an oxidant.