Corrosion resistant gasifier components

• US 9,120,985 B2
• Filed: 03/22/2011
• Issued: 09/01/2015
• Est. Priority Date: 05/26/2010
• Status: Active Grant

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Oldenburg, Paul D., Raterman, Michael F.
• Primary Examiner(s): HANDAL, KAITY V
• Application Number:
  US13/053,986
• Publication Number:
  US 20110289842A1
• Time in Patent Office: 1,624 Days
• Field of Search: 48/61, 481/279, 481/271, 48/76, 48/69, 48200-203, 48 71- 73
• US Class Current: 1/1
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 3/485 Entrained flow gasifiers
• CPC Class Codes: C10J 3/506 for entrained flow gasifiers
• CPC Class Codes: C10J 3/74 Construction of shells or jackets
• CPC Class Codes: C10J 3/76 Water jackets; Steam boiler-jackets

Abstract

The present invention relates to an improved gasifier reactor design. In particular, the present invention relates to improved design of gasifier reactor faceplates, gasifier reactor walls, gasifier reactor cooling tubes, and gasifier reactor walls with integrated cooling channels. The present invention utilizes aluminum nitride and/or aluminum nitride/metal composite materials which promote many benefits to the present design herein, including improved corrosion and erosion resistively as compared to high alloy metal materials.

Claims

1. An entrained-flow gasifier reactor comprising:

a gasifier faceplate having at least one fuel feed port and at least one oxidizing gas port passing therethrough, the gasifier faceplate formed of a corrosion-resistant faceplate material comprised of an aluminum nitride;

a fuel feed line providing a solid fuel feed or high boiling point liquid hydrocarbon feed to the at least one fuel feed port; and

a reactor wall extending away from the gasifier faceplate.

2. The entrained-flow gasifier reactor of claim 1, wherein the corrosion-resistant faceplate material is in the sintered or hot pressed condition.

3. The entrained-flow gasifier reactor of claim 1, wherein the gasifier faceplate further comprises integral cooling channels.

4. The entrained-flow gasifier reactor of claim 1, further comprising a cooling plate that is in thermal contact with the gasifier faceplate.

5. The entrained-flow gasifier reactor of claim 4, wherein the cooling plate is mechanically attached to the gasifier faceplate by means of a brazing agent.

6. The entrained-flow gasifier reactor of claim 4, wherein the cooling plate is comprised of copper, aluminum, or brass.

7. The entrained-flow gasifier reactor of claim 6, wherein the cooling plate is comprised of oxygen free high conductivity (“

OFHC”

) copper.

8. The entrained-flow gasifier reactor of claim 1, wherein the corrosion-resistant faceplate material is further comprised of a metal selected from the group consisting of zirconium (Zr), aluminum (Al), and titanium (Ti).

9. The entrained-flow gasifier reactor of claim 1, wherein the corrosion-resistant faceplate material consists essentially of aluminum nitride.

10. The entrained-flow gasifier reactor of claim 1, wherein at least a portion of the reactor wall is comprised of a corrosion-resistant reactor wall material selected from the group consisting of aluminum nitride and an aluminum-nitride/metal composite.

11. The entrained-flow gasifier reactor of claim 10, wherein said portion of the reactor wall is a monolith further comprising integral cooling channels.

12. The entrained-flow gasifier reactor of claim 11, wherein said portion of the reactor wall consists essentially of a corrosion-resistant reactor wall material selected from the group consisting of aluminum nitride and an aluminum-nitride/metal composite.

13. The entrained-flow gasifier reactor of claim 12, wherein the corrosion-resistant reactor wall material is an aluminum-nitride/metal composite, wherein the metal component is selected from the group consisting of zirconium (Zr), aluminum (Al), and titanium (Ti).

14. The entrained-flow gasifier reactor of claim 1, further comprising reactor wall cooling tubes that consist essentially of a corrosion-resistant cooling tube material selected from the group consisting of aluminum nitride and an aluminum-nitride/metal composite.

15. The entrained-flow gasifier reactor of claim 14, wherein the corrosion-resistant cooling tube material is an aluminum-nitride/metal composite, wherein the metal component is selected from the group consisting of zirconium (Zr), aluminum (Al), and titanium (Ti).