Geopolymeric structural building units and methods of manufacture thereof

• US 9,126,865 B2
• Filed: 07/06/2010
• Issued: 09/08/2015
• Est. Priority Date: 07/06/2009
• Status: Active Grant

• Current Assignee: Random Technologies LLC
• Original Assignee: Random Technologies LLC
• Inventors: Blackstock, John McIlvenna, Neill, James, McIntosh, John Andrew
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US13/261,120
• Publication Number:
  US 20120260594A1
• Time in Patent Office: 1,890 Days
• Field of Search: 106/600, 106/692
• US Class Current: 1/1
• CPC Class Codes: C04B 14/104 Bentonite, e.g. montmorillonite
• CPC Class Codes: C04B 14/106 Kaolin
• CPC Class Codes: C04B 14/14 Minerals of vulcanic origin granite C04B14/048
• CPC Class Codes: C04B 18/141 Slags
• CPC Class Codes: C04B 2111/00206 Compositions defined by their elemental analysis
• CPC Class Codes: C04B 28/006 containing mineral polymers, e.g. geopolymers of the Davidovits type
• CPC Class Codes: Y02P 40/10 Production of cement, e.g. improving or optimising the production methods; Cement grinding
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete

Abstract

The present invention provides a geopolymeric cement formed from a precursor having a relatively high alumina content (Si:Al atomic ratio of less than or equal to 1.3:1) to form an alkaline multiphase alumino-silicate material.

The precursor comprises basaltic rock in which kaolinization is at an advanced stage, preferably Interbasaltic material found in Northern Ireland.

The present invention also provides structural units for constructing a building, the structural units being manufactured using the geopolymeric cement of the invention.

The invention also provides a process for producing a geopolymeric cement comprising a precursor having a relatively high alumina content (Si:Al atomic ratio of less than or equal to 1.3:1) to form an alkaline alumino-silicate geopolymer material for manufacturing geopolymeric structural building units having compressive strengths of greater than 3 N/mm² and preferably having compressive strengths in the range of 12-25 N/mm².

Claims

1. A geopolymeric cement formed from a precursor having a Si:

Al atomic ratio of less than or equal to 1.3;

1 and an alkali metal hydroxide and alkali silicate solution to form an alkaline alumino-silicate material, and wherein the precursor comprises weathered basaltic rock which is comprised of between 20% to 80% w/w of kaolinite with the remaining 80% to 20% w/w made up of smectites, iron oxides, gibbsite and olivine residual materials.

2. A geopolymer cement as claimed in claim 1 formed from a precursor having a Si:

Al atomic ratio in the range of between 0.5;

1 and 1.3;

1 and forming an alkaline aluminosilicate geopolymer material.

3. A geopolymer cement as claimed in claim 1 wherein the precursor has a Si:

Al atomic ratio in the range of between 1;

1 and 1.3;

1.

4. A geopoylmer cement as claimed in claim 1 wherein the precursor comprises Interbasaltic rock from Northern Ireland.

5. A geopolymeric cement as claimed in claim 1 wherein the precursor has a maximum particle size of less than 250 microns.

6. A geopolymeric cement as claimed in claim 1 wherein the smectites are selected from montmorillionite and vermiculite.

7. A geopolymeric cement as claimed in claim 1 wherein the geopolymeric cement is also formed using a calcium silicate material.

8. A geopolymeric cement as claimed in claim 7 wherein the calcium silicate material comprises Ground Granulated Blastfurnace Slag (GGBS) which provides a source of calcium which functions as an accelerator in the setting process.

9. A geopolymeric cement as claimed in claim 1 having a compressive strength in the range of between 95 to 120 N/mm².

17. A geopolymer cement as claimed in claim 3 wherein the Si:

Al atomic ratio of the precursor is in the range between 1;

1 and 1.2;

1.

18. A geopolymer cement as claimed in claim 3 wherein the Si:

Al atomic ratio of the precursor is in the range of 1.05;

1 and 1.2;

1.

19. A geopolymer cement as claimed in claim 4 wherein the precursor comprises Interbasaltic material known as Lithomarge found in Northern Ireland.

20. A geopolymeric cement as claimed in claim 5 wherein the precursor has a maximum particle size of less than 150 microns.

10. A process for producing a geopolymeric cement from a precursor having a Si:

Al atomic ratio of less than or equal to 1.3;

1 and an alkali metal hydroxide and alkali silicate solution to form an alkaline alumino-silicate material, and wherein the precursor comprises weathered basaltic rock which is comprised of between 20% to 80% w/w of kaolinite with the remaining 80% to 20% w/w made up of smectites, iron oxides, gibbsite and olivine residual materials.

11. A process as claimed in claim 10 wherein the precursor comprises basaltic rock having high alumina content.

12. A process as claimed in claim 11 wherein the precursor comprises basaltic rock in which kaolinization is at an advanced stage, preferably lithomarge.

13. A process as claimed in claim 12 wherein the precursor is calcined at a temperature in the range of between 650°

C. to 950°

C.

14. A process as claimed in claim 12 wherein the weathered basaltic rock is composed of between 20% to 80% w/w of kaolinite with the remaining 80% to 20% w/w made up of smectites (e.g., montmorillionite and vermiculite), iron oxides, gibbsite and olivine residual materials.

15. A process as claimed in claim 12 wherein the ratio of precursor to alkali silicate is between 1:

0.4 and 1;

2 (w/w).

16. A process as claimed in claim 12 wherein a calcium silicate glass material is included in an amount of between 0 to 50% w/w of the geopolymeric cement.