Photonic crystal electrical property indicator

• US 9,130,227 B2
• Filed: 03/04/2009
• Issued: 09/08/2015
• Est. Priority Date: 03/05/2008
• Status: Expired due to Fees

• Current Assignee: Opalux Incorporated
• Original Assignee: Opalux Incorporated
• Inventors: Arsenault, Andre, Ozin, Geoffrey Alan
• Primary Examiner(s): Ryan, Patrick
• Assistant Examiner(s): GRESO, AARON J
• Application Number:
  US12/921,065
• Publication Number:
  US 20110104535A1
• Time in Patent Office: 2,379 Days
• Field of Search: 252/500, 252/582, 252/586
• US Class Current: 1/1
• CPC Class Codes: H01M 10/425 Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing printed circuits H05K1/00
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/488 Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density
• CPC Class Codes: H01M 6/5044 Cells or batteries structurally combined with cell condition indicating means
• CPC Class Codes: H01M 6/505 Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49002 Electrical device making

Abstract

A photonic crystal electrical property indicator for a battery comprising: an electrically conductive working electrode and an electrically conductive counter electrode; an electrically-responsive photonic crystal material in contact with at least one of said first and second electrically conductive electrodes; an ionically conductive electrolyte provided between the working and counter electrodes; and electrical conductors for connecting the indicator to terminals of the battery; wherein the photonic crystal material has a reflectance spectrum that is responsive to a change in at least one electrical property of the battery, thereby providing an optically detectable indication of the at least one electrical property of the battery.

Claims

1. A photonic crystal electrical property indicator for a battery comprising:

an electrically conductive working electrode and an electrically conductive counter electrode, the working and counter electrodes being spaced apart;

an electrically-responsive photonic crystal material in contact with at least one of the working and counter electrodes;

an ionically conductive electrolyte provided between the working and counter electrodes, the electrolyte being in electrical communication with both the working and counter electrodes and the photonic crystal material; and

electrical conductors in electrical communication with the working and counter electrodes for connecting the indicator to terminals of the battery;

wherein a charge-storage material is provided on at least one of the working and counter electrodes, or within the ionically conductive electrolyte, wherein the charge storage material has different thicknesses in at least two portions of the indicator,

wherein the at least two portions have reflectance spectra that are responsive to a change in at least one electrical property of the battery, the reflectance spectra of the at least two portions differing, thereby providing at least two different optically detectable indications of the at least one electrical property of the battery.

2. The indicator of claim 1 wherein the optically detectable indications are each visibly detectable and distinguishable from each other.

3. The indicator of claim 1 wherein the at least one electrical property of the battery is a charge remaining in the battery.

4. The indicator of claim 1 whereby the photonic crystal material comprises an ordered array of first constituents having a first refractive index embedded within a polymer matrix having a second refractive index different than the first refractive index, the ordered array of first constituents having a lattice spacing giving rise to the reflectance spectrum;

wherein the polymer matrix is expandable and contractible in response to uptake and expulsion of at least one component of the ionically conductive electrolyte, expansion and contraction of the polymer matrix giving rise to changes in the lattice spacing;

wherein the uptake and expulsion of the at least one component of the ionically conductive electrolyte being responsive to a change in the at least one electrical property of the battery; and

wherein the reflectance spectrum is dependent on the lattice spacing.

5. The indicator of claim 4 wherein the reflectance spectrum is in the range of:

visible spectrum, ultraviolet spectrum, infrared spectrum, or combinations thereof.

6. The indicator of claim 1 wherein the indicator is flexible.

7. The indicator of claim 1 wherein the indicator comprises a visual effect that is optically detectable in combination with the reflectance spectrum of the photonic crystal material.

8. The indicator of claim 7 wherein the visual effect is selected from a group consisting of:

a design, a tint, a hue, shading, homogenous colors, patterns, alpha-numeric characters, graphical representations, pictures, images, data, and combinations thereof.

9. The indicator of claim 7 wherein a change in the reflectance spectrum of the photonic crystal material causes the visual effect to become more or less visible.

10. The indicator of claim 7 wherein the visual effect is static.

11. The indicator of claim 7 wherein the visual effect is dynamic in response to at least one of a change in the reflectance spectrum of the photonic crystal material and an external stimulus.

12. The indicator of claim 1 wherein at least one of the working and counter electrodes is made from a conductive material selected from the group consisting of:

conductive oxides, conductive ceramics, metals, carbons, conducting polymers, redox-active polymers, nanoparticles, and combinations thereof.

13. The indicator of claim 1 wherein at least one of the working and counter electrodes is provided on a substrate.

14. The indicator of claim 13 wherein the substrate is selected from a group consisting of fabrics, papers, metals, polymers, glasses, ceramics, semiconductors, inorganic materials, and combinations thereof.

15. The indicator of claim 1 wherein the charge-storage material is made from a material selected from the group consisting of:

conductive oxides, conductive ceramics, metals, carbons, conducting polymers, redox-active polymers, nanoparticles, redox-active small molecules, and combinations thereof.

16. The indicator of claim 1 wherein the charge-storage material is porous.

17. The indicator of claim 4 wherein the polymer is chosen from the group consisting of:

polyferrocenylsilanes, polythiophenes, polypyrroles, polyanilines, polyphenylene vinylenes, polyacetylenes, polyfluorenes, conducting polymers, conjugated polymers, metallopolymers, copolymers incorporating such polymer types, and combinations thereof.

18. The indicator of claim 4 wherein the polymer matrix comprises linear polymer chains.

19. The indicator of claim 4 wherein the polymer matrix comprises a cross-linked polymer network.

20. The indicator of claim 19 wherein the cross-linked polymer network has cross-linking groups selected from the group consisting of:

covalent bonds, ionic bonds, polar covalent bonds, hydrogen bonds, hydrophobic interactions, coordination bonds, and combinations thereof.

21. The indicator of claim 4 wherein the polymer matrix is incorporated using a method selected from the group consisting of:

melt infiltration, polymerization of a monomer or combination of monomers, polymerization of a crosslinker, solution infiltration, gas-phase infiltration, electrophoresis, sublimation, or combinations thereof.

22. The indicator of claim 4 wherein the ordered array of first constituents comprises an ordered array of spherical constituents.

23. The indicator of claim 22 wherein the spherical constituents comprise spherical voids.

24. The indicator of claim 23 wherein the substantially spherical voids are filled with at least one component of the ionically conductive electrolyte.

25. In combination, the indicator of claim 1 together with a reference chart for evaluating the at least one electrical property of the battery.

26. A method of manufacturing a photonic crystal electrical property indicator of claim 1 comprising:

providing an electrically conductive working electrode;

providing an electrically-responsive photonic crystal material in electrical communication with the working electrode;

providing an electrically conductive counter electrode spaced apart from the working electrode;

providing an ionically conductive electrolyte between the working and counter electrodes, the electrolyte being in electrical communication with the working and counter electrodes and the photonic crystal material;

sealing the electrolyte between the working and counter electrodes; and

providing electrical conductors in electrical communication with the working and counter electrodes for connecting the indicator to terminals of a battery;

wherein a charge-storage material is provided on at least one of the working and counter electrodes, or within the ionically conductive electrolyte, wherein the charge storage material has different thicknesses in at least two portions of the indicator, and

wherein the at least two portions have reflectance spectra that are responsive to a change in at least one electrical property of the battery, the reflectance spectra of the at least two portions differing, thereby providing at least two different optically detectable indications of the at least one electrical property of the battery.

27. A battery label comprising the indicator of claim 1.

28. A battery tester comprising the indicator of claim 1.