Double-masking technique for increasing fabrication yield in superconducting electronics
First Claim
1. An integrated circuit having Josephson junctions, comprising:
- a Josephson junction trilayer comprising an upper superconductor, an insulating layer, and a lower superconductor, the insulating layer being between the upper superconductor and the lower superconductor;
an adhesion layer formed directly on top of the upper superconductor; and
a resist layer formed directly on top of the adhesion layer,the resist being patterned and developed, exposing portions of the adhesion layer through the patterned and developed resist layer, and the exposed portions of the adhesion layer being etched through the upper superconductor layer to expose the insulating layer; and
portions of the lower superconducting layer under the exposed portions of the insulating layer being anodized to selectively form Josephson junction circuit elements having submicron feature sizes under remaining portions of the adhesion layer and the resist layer, wherein the anodized portions of the lower superconductor form a layer of anodized superconductor on all sidewalls of the upper superconductor and insulating layer, and undergo a volumetric increase with respect to the non-anodized portions under remaining portions of the resist layer, the volumetric increase causing local stresses which are insufficient to cause substantial peeling of the resist layer on the adhesion layer and are sufficient to cause peeling of at least a portion of the resist layer directly on the upper superconductor adjacent to the anodized portions of the lower superconductor layer.
2 Assignments
0 Petitions
Accused Products
Abstract
An improved microfabrication technique for Josephson junctions in superconducting integrated circuits, based on the use of a double-layer lithographic mask for partial anodization of the side-walls and base electrode of the junctions. The top layer of the mask is a resist material, and the bottom layer is a dielectric material chosen so to maximize adhesion between the resist and the underlying superconducting layer, be etch-compatible with the underlying superconducting layer, and be insoluble in the resist and anodization processing chemistries. The superconductor is preferably niobium, under a silicon dioxide layer, with a conventional photoresist or electron-beam resist as the top layer. This combination results in a substantial increase in the fabrication yield of high-density superconducting integrated circuits, increase in junction uniformity and reduction in defect density. A dry etch more compatible with microlithography may be employed.
919 Citations
20 Claims
-
1. An integrated circuit having Josephson junctions, comprising:
-
a Josephson junction trilayer comprising an upper superconductor, an insulating layer, and a lower superconductor, the insulating layer being between the upper superconductor and the lower superconductor; an adhesion layer formed directly on top of the upper superconductor; and a resist layer formed directly on top of the adhesion layer, the resist being patterned and developed, exposing portions of the adhesion layer through the patterned and developed resist layer, and the exposed portions of the adhesion layer being etched through the upper superconductor layer to expose the insulating layer; and portions of the lower superconducting layer under the exposed portions of the insulating layer being anodized to selectively form Josephson junction circuit elements having submicron feature sizes under remaining portions of the adhesion layer and the resist layer, wherein the anodized portions of the lower superconductor form a layer of anodized superconductor on all sidewalls of the upper superconductor and insulating layer, and undergo a volumetric increase with respect to the non-anodized portions under remaining portions of the resist layer, the volumetric increase causing local stresses which are insufficient to cause substantial peeling of the resist layer on the adhesion layer and are sufficient to cause peeling of at least a portion of the resist layer directly on the upper superconductor adjacent to the anodized portions of the lower superconductor layer. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 16, 17)
-
-
11. An integrated circuit having Josephson junctions, comprising:
-
a Josephson junction trilayer comprising an upper superconductor, an intervening insulating layer, and a lower superconductor; an adhesion layer formed directly on top of the upper superconductor; a resist layer formed directly on top of the adhesion layer, the resist being patterned and developed, exposing portions of the adhesion layer through the patterned and developed resist layer, and the exposed portions of the adhesion layer being etched through the upper superconductor layer to expose the insulating layer; and portions of the lower superconducting layer beneath the exposed portions of the insulating layer being anodized, to selectively form Josephson junction circuit elements having submicron features size under remaining intact portions of the adhesion layer and the resist layer and having a layer of anodized superconductor on all sidewalls of the upper superconductor layer and insulating layer, wherein the anodized portions of the lower superconductor are volumetrically increased with respect to the non-anodized portions under remaining intact portions of the resist layer, to induce stresses in the adhesion layer and the resist layer adjacent to the anodized portions, wherein the resist layer is susceptible to a failure of adhesion and peeling under the induced stresses if applied directly to the upper superconductor, and the adhesion layer formed between the resist layer and the upper superconductor being effective to substantially prevent peeling of the resist layer from the stresses, such that adjacent portions of the adhesion layer or resist layer to the anodized portions of the lower superconductor layer remain substantially without peeling, the exposed portions of the insulating layer and the anodized portions of the lower superconductor layer being removed to expose the lower superconductor layer. - View Dependent Claims (12, 13, 14)
-
-
18. An integrated circuit having Josephson junctions, comprising:
-
a Josephson junction trilayer comprising an upper superconductor, an intervening insulating layer, and a lower superconductor; an adhesion layer directly on top of the upper superconductor; a patterned and developed resist layer directly on top of the adhesion layer, exposing portions of the insulating layer through etched portions of the adhesion layer corresponding to absent portions of the patterned and developed resist layer, wherein portions of the lower superconducting layer beneath the exposed portions of the insulating layer have a volumetric increase as a result of selective anodization, forming a layer of anodized superconductor on all sidewalls of the upper superconductor and intervening insulating layer, and Josephson junction circuit elements under remaining intact portions of the adhesion layer and the resist layer, portions of the adhesion layer or resist layer adjacent to the anodized portions of the lower superconductor layer being locally stressed from the selective anodization and being substantially unpeeled, formed by a process comprising; providing a substrate, having the Josephson junction trilayer thereon, the upper superconducting layer being directly covered by an intermediate layer comprising a dielectric having a thickness of at least 5 nm, which in turn is directly covered by a resist layer; selectively patterning portions of the resist layer in dependence on an irradiation pattern, and developing the pattered portions of the resist layer to expose portions of the intermediate layer; etching the exposed portions of the intermediate layer and underlying portions of the upper superconducting layer, substantially without removing remaining portions of the resist layer, to expose the insulating layer, to thereby form a bilayer anodization mask comprising the resist layer and the intermediate layer; and anodizing the exposed insulating layer and underlying lower superconducting layer through the bilayer mask, to cause a volumetric increase in at least a portion of the lower superconducting layer sufficient to form the layer of anodized superconductor on all sidewalls of the upper superconductor and intervening insulating layer, and to selectively form Josephson junction circuit elements having a submicron feature size comprising intact portions of the Josephson junction trilayer having a submicron feature size protected by the bilayer mask, the volumetric increase causing stresses in the remaining portions of the resist layer and the intermediate layer local to the anodizing, the resist layer being subject to a failure of adhesion and peeling under the stresses if applied directly to the upper superconductor and the intermediate layer formed between the resist layer and the Josephson junction trilayer being effective to substantially prevent peeling of the resist layer, wherein the resist layer remains strongly adherent to the intermediate layer, and the intermediate layer remains strongly adherent to the upper superconducting layer, substantially without peeling. - View Dependent Claims (19, 20)
-
Specification