Organic electroluminescent element and method for producing the same

• US 9,136,491 B2
• Filed: 08/14/2009
• Issued: 09/15/2015
• Est. Priority Date: 08/27/2008
• Status: Active Grant

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Iwasaki, Masataka
• Primary Examiner(s): VETERE, ROBERT A
• Application Number:
  US13/060,785
• Publication Number:
  US 20110186833A1
• Time in Patent Office: 2,223 Days
• Field of Search: 427/74
• US Class Current: 1/1
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass
• CPC Class Codes: H10K 71/12 using liquid deposition, e.g. spin coating
• CPC Class Codes: H10K 71/40 Thermal treatment, e.g. annealing in the presence of a solvent vapour
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: H10K 85/141 comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE

Abstract

The problem to be solved by the present invention is to prolong the luminance half life of an organic EL element. A means for solving the problem is a method for producing an organic electroluminescent element comprising a first electrode that is formed first, a second electrode that is formed later, and a light-emitting layer that is formed between the first electrode and the second electrode, the method comprising the steps of applying a solution containing a light-emitting organic material to a surface of a layer located below to form an applied film; calcining the applied film in an inert gas atmosphere or in a vacuum atmosphere to form a light-emitting layer; holding the surrounding of the formed light-emitting layer in an inert gas atmosphere or in a vacuum atmosphere; and forming a layer located on the light-emitting layer in an inert gas atmosphere or in a vacuum atmosphere.

Claims

1. A method for producing an organic electroluminescent element comprising a first electrode that is formed first, a second electrode that is formed later, and a light-emitting layer that is formed between the first electrode and the second electrode, the method comprising the steps of:

applying a solution containing a light-emitting organic material to a surface of a layer located below in an air atmosphere, using atmospheric air, to form an applied film;

calcining the applied film in a vacuum atmosphere to form a light-emitting layer;

holding the surrounding of the formed light-emitting layer in a vacuum atmosphere; and

forming a layer located on the light-emitting layer in a vacuum atmosphere.

2. The method according to claim 1, further comprising the step of forming a layer in an inert gas atmosphere or in a vacuum atmosphere after the layer located on the light-emitting layer is formed until the second electrode is formed, while the surrounding of the layers to be formed including a layer located on the light-emitting layer being held in an inert gas atmosphere or in a vacuum atmosphere.

3. The method according to claim 1, wherein the layer located on the light-emitting layer is the second electrode.

4. The method according to claim 1, wherein the light-emitting organic material comprises a light-emitting macromolecular compound.

5. The method according to claim 4, wherein the light-emitting macromolecular compound is at least one kind selected from the group consisting of polyparaphenylene vinylene derivatives, polythiophene derivatives, polyparaphenylene derivatives, polysilane derivatives, polyacetylene derivatives, polyfluorene derivatives, and polyvinylcarbazole derivatives.

6. The method according to claim 4, wherein the light-emitting macromolecular compound is at least one kind selected from the group consisting of polyvinylcarbazole derivatives, polyparaphenylene derivatives and polyfluorene derivatives as materials that emit blue light;

polyparaphenylene vinylene derivatives and polyfluorene derivatives as materials that emit green light;

polyparaphenylene vinylene derivatives, polythiophene derivatives and polyfluorene derivatives as materials that emit red light.

7. The method according to claim 1, further comprising, before the step of applying a solution containing a light-emitting organic material to form an applied film, as a method of forming a layer located below the light-emitting layer, the steps of:

applying a solution containing a functional organic material to a surface of a layer located below to form an applied film; and

calcining the applied film in an inert gas atmosphere or in a vacuum atmosphere to form a functional layer.

8. The method according to claim 7, further comprising the step of holding the surrounding of the formed functional layer in an inert gas atmosphere or in a vacuum atmosphere.

9. The method according to claim 8, wherein the first electrode is an anode, the second electrode is a cathode, and the functional organic material contains a hole transporting macromolecular compound.

10. The method according to claim 9, wherein the above-mentioned hole transporting macromolecular compound is at least one kind selected from the group consisting of polyvinylcarbazole or its derivatives, polysilane or its derivatives, polysiloxane derivatives having an aromatic amine compound group in their side chain or main chain, polyaniline or its derivatives, polythiophene or its derivatives, polyarylamine or its derivatives, poly(p-phenylenevinylene) or its derivatives, and poly(2,5-thienylenevinylene) or its derivatives.