Method and apparatus for pretreating biomass using internal heat

• US 9,139,852 B2
• Filed: 12/14/2010
• Issued: 09/22/2015
• Est. Priority Date: 12/15/2009
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Kim, Jin Woo, Park, Jae Chan, Park, Sung Min, Park, Young Kyoung
• Primary Examiner(s): Leung, Jennifer A
• Application Number:
  US12/967,578
• Publication Number:
  US 20110143412A1
• Time in Patent Office: 1,743 Days
• US Class Current: 1/1
• CPC Class Codes: B01J 8/10 moved by stirrers or by rotary drums or rotary receptacles or endless belts
• CPC Class Codes: C12M 41/12 of temperature controlling the temperature of chemical or physical processes B01J19/0013, heating or cooling apparatus for laboratory use B01L7/00
• CPC Class Codes: C12M 45/02 by mechanical forces; Stirring; Trituration; Comminuting crushing, pulverizing, disintegrating in general B02C
• CPC Class Codes: C12M 45/04 Phase separators; Separation of non fermentable material; Fractionation
• CPC Class Codes: C12M 45/06 by chemical means or hydrolysis
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 7/08 produced as by-product or from waste or cellulosic material substrate
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: D21C 1/00 Pretreatment of the finely-divided materials before digesting of waste paper D21C5/02
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 1/04 with acid reacting compounds
• CPC Class Codes: D21C 1/06 with alkaline reacting compounds
• CPC Class Codes: D21C 1/10 Physical methods for facilitating impregnation
• CPC Class Codes: D21C 3/20 with organic solvents or in solvent environment
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

A method for pretreating a biomass, in which a water-reactive anhydride contacts a biomass, is disclosed. The biomass is pretreated using internal heating by an exothermic reaction. Further, an apparatus for pretreating a biomass having a reaction part including an inlet part and an outlet part for the water-reactive anhydride is disclosed.

Claims

1. An apparatus for pretreating a biomass, comprising:

a reaction part for pretreating a biomass, the reaction part including

an inlet part which is formed at a first end of the reaction part and through which a gaseous water-reactive anhydride can be input, wherein the inlet part is connected to a first supply tank containing fresh gaseous water-reactive anhydride, and

an outlet part which is formed at a second end of the reaction part opposite the first end and through which the gaseous water-reactive anhydride can be output;

a biomass supply part for supplying a biomass to the second end of the reaction part;

a water supply part formed between the biomass supply part and the reaction part, and connected to the second end of the reaction part to supply water to the biomass;

a washing part connected to the first end of the reaction part to wash the biomass, and

a separation part connected to the washing part for separating components extracted from the biomass,

wherein the inlet, outlet, and biomass supply parts are configured such that the direction of flow of the gaseous water-reactive anhydride through the reaction part is the reverse of the direction of transfer of the biomass through the reaction part.

2. The apparatus according to claim 1, wherein the biomass supply part, the reaction part and the separation part are continuously formed, and a screw transfer apparatus is formed inside to transfer the biomass continuously.

3. The apparatus according to claim 1, wherein an outer surface of the reaction part is insulated.

4. The apparatus according to claim 1, further comprising a fragmentation part formed between the biomass supply part and the reaction part to fragment the biomass.

5. The apparatus according to claim 1, further comprising a bridge part formed between the outlet part and the inlet part, to transfer fluid from the outlet part to the inlet part.

6. The apparatus according to claim 5, wherein the bridge part includes a dehydration column and/or a compressor.

7. The apparatus according to claim 1, further comprising a second supply tank in fluid connection with a dehydration column and/or a compressor.

8. The apparatus according to claim 7, further comprising

a mixing part in fluid connection with the first supply tank, the second supply tank, and the inlet part.

9. The apparatus according to claim 5, wherein the outlet part includes an exhaustion part, which is separated from the bridge part, to exhaust a vapor generated by internal heating.

10. The apparatus of claim 3, wherein the apparatus does not comprise a heat source outside the reaction part.

11. An apparatus for pretreating a biomass, comprising:

a reaction part for pretreating a biomass, the reaction part including

an inlet part which is formed at a first end of the reaction part and through which a gaseous water-reactive anhydride can be input, wherein the inlet part is connected to a first supply tank containing fresh gaseous water-reactive anhydride, and

an outlet part which is formed at a second end of the reaction part opposite the first end and through which the gaseous water-reactive anhydride can be output;

a biomass supply part for supplying a biomass to the second end of the reaction part;

a washing part connected to the first end of the reaction part to wash the biomass, and

a separation part connected to the washing part for separating components extracted from the biomass;

wherein the reaction part is insulated, and the apparatus does not comprise a heat source outside the reaction part, and wherein the inlet, outlet, and biomass supply parts are configured such that the direction of flow of the gaseous water-reactive anhydride through the reaction part is the reverse of the direction of transfer of the biomass through the reaction part.

12. An apparatus for pretreating a biomass, comprising:

a reaction part for pretreating a biomass, the reaction part including

an inlet part which is formed at a first end of the reaction part and through which a gaseous water-reactive anhydride can be input, wherein the inlet part is directly connected or coupled to a first supply tank, and

an outlet part which is formed at a second end of the reaction part opposite the first end and through which the gaseous water-reactive anhydride can be output;

a biomass supply part for supplying a biomass to the second end of the reaction part;

a water supply part formed between the biomass supply part and the reaction part, and connected to the second end of the reaction part to supply water to the biomass;

a washing part connected to the first end of the reaction part to wash the biomass, and

a separation part connected to the washing part for separating components extracted from the biomass,

wherein the inlet, outlet, and biomass supply parts are configured such that the direction of flow of the gaseous water-reactive anhydride through the reaction part is the reverse of the direction of transfer of the biomass through the reaction part.