Natural gas liquefaction processes with feed gas refrigerant cooling loops

• US 9,140,490 B2
• Filed: 06/26/2008
• Issued: 09/22/2015
• Est. Priority Date: 08/24/2007
• Status: Active Grant

• Current Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Original Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Inventors: Minta, Moses, Stone, John B., Feist, Raymond Scott
• Primary Examiner(s): Jules, Frantz
• Assistant Examiner(s): RAYMOND, KEITH MICHAEL
• Application Number:
  US12/668,811
• Publication Number:
  US 20100186445A1
• Time in Patent Office: 2,644 Days
• Field of Search: 626/12, 626/11, 626/13, 626/14
• US Class Current: 1/1
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0082 Methane
• CPC Class Codes: F25J 1/0092 Mixtures of hydrocarbons comprising possibly also minor amounts of nitrogen
• CPC Class Codes: F25J 1/0214 as a dual level refrigeration cascade with at least one MCR cycle
• CPC Class Codes: F25J 1/0215 with one SCR cycle
• CPC Class Codes: F25J 1/0219 in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
• CPC Class Codes: F25J 1/025 Details related to the refrigerant production or treatment, e.g. make-up supply from feed gas itself
• CPC Class Codes: F25J 1/0254 controlling particular process parameter, e.g. pressure, temperature
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2230/30 Compression of the feed stream
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/04 : Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/08 : Internal refrigeration by flash gas recovery loop

Abstract

The described invention relates to processes and systems for treating a gas stream, particularly one rich in methane for forming liquefied natural gas (LNG), the process including: (a) providing a gas stream; (b) providing a refrigerant; (c) compressing the refrigerant to provide a compressed refrigerant; (d) cooling the compressed refrigerant by indirect heat exchange with a cooling fluid; (e) expanding the refrigerant of (d) to cool the refrigerant, thereby producing an expanded, cooled refrigerant; (f) passing the expanded, cooled refrigerant to a first heat exchange area; (g) compressing the gas stream of (a) to a pressure of from greater than or equal to 1,000 psia to less than or equal to 4,500 psia; (h) cooling the compressed gas stream by indirect heat exchange with an external cooling fluid; and heat exchanging the compressed gas stream with the expanded, cooled refrigerant stream.

Claims

1. A process for liquefying a gas stream, said process comprising:

(a) providing said gas stream at a pressure of from 600 to 1,000 psia (4,137-6,895 kPa) as a feed gas stream;

(b) providing a refrigerant at a pressure of less than 1,000 psia (6,895 kPa) by withdrawing a portion of said gas stream for use as said refrigerant;

(c) compressing said refrigerant in a closed loop to a pressure greater than or equal to 1,600 to less than or equal to 5,000 psia (11,032 to 34,474 kPa) to produce a compressed refrigerant;

(d) cooling said compressed refrigerant by indirect heat exchange with a cooling fluid;

(e) expanding the compressed refrigerant of (d) to cool said compressed refrigerant, to produce an expanded, cooled refrigerant at a pressure of from greater than or equal to 100 psia (689 kPa) to less than or equal to 1,000 psia (6895 kPa);

(f) passing said expanded, cooled refrigerant to a first heat exchange area;

(g) compressing the feed gas stream of (a) to a pressure of from greater than or equal to 2,500 psia (17,237 kPa) to less than or equal to 3,500 psia (24,132 kPa) to produce a compressed feed gas stream;

(h) cooling said compressed feed gas stream by indirect heat exchange with an air or water refrigerant cooler;

(i) passing said compressed feed gas stream through the first heat exchange area to cool at least a part thereof by indirect heat exchange, to produce a compressed, further cooled feed gas stream, wherein the feed gas is used as the only refrigerant such that no external refrigerants are used, except for water or air;

(j) passing the compressed, further cooled feed gas stream of (i) through a second heat exchange area for extra cooling; and

(k) expanding said compressed, further cooled feed gas stream of (j) to reduce the pressure of said compressed, further cooled feed gas stream to a pressure of from greater than or equal to 50 psia (345 kPa) to less than or equal to 450 psia (3103 kPa) to produce an expanded, cooled gas stream; and

(l) withdrawing a portion not to exceed 50% of said expanded, cooled gas stream of (k) and reducing its pressure in a reduction valve to a range of about 30-200 psia (207-1379 kPa) to produce a reduced pressure gas stream and passing the reduced pressure gas stream through the second heat exchange area of (j) as a cooling gas stream.

2. The process of claim 1, further comprising passing the cooling gas stream through the first heat exchange area to assist cooling of said compressed feed gas stream.

3. The process of claim 2, further comprising subsequently compressing and cooling the cooling gas stream by indirect heat exchange with an external cooling unit, one or more times, and adding the cooling gas stream to the feed gas stream of 1(a) prior to the compressing of said feed gas stream in 1 (g).

4. The process of claim 1, further comprising expanding at least a second portion of said expanded, cooled gas stream;

and

passing the expanded second portion to a separation tank from which liquid natural gas is withdrawn and remaining gaseous vapors are withdrawn as flash gas.

5. The process of claim 4 wherein said first heat exchange area and said second heat exchange area are provided with a sub-cooling expander loop cooling stream comprising said flash gas from the final separation of the liquefied feed gas stream.

6. The process of claim 5 wherein said sub-cooling expander loop cooling stream flows in a closed loop comprising compressing said sub-cooling expander loop cooling stream after passing through said first heat exchange area and said second heat exchange area, cooling with at least one external refrigerant cooling unit, and expanding said sub-cooling expander loop cooling stream prior to providing to the first and second heat exchange areas.

7. The process of claim 6 wherein said sub-cooling expander loop cooling stream comprises nitrogen or nitrogen-containing gas.

8. The process of claim 6 wherein said sub-cooling expander loop cooling stream comprises a portion of said flash gas and the remaining portion of the flash gas is passed through one or both of the first and second heat exchange areas as a cooling fluid stream before being routed for use as a fuel source.