Highly-neutralized thermoplastic copolymer center for improved multi-layer core golf ball

• US 9,149,688 B2
• Filed: 12/30/2013
• Issued: 10/06/2015
• Est. Priority Date: 06/26/2001
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Sullivan, Michael J., Ladd, Derek A.
• Primary Examiner(s): BUTTNER, DAVID J
• Application Number:
  US14/143,870
• Publication Number:
  US 20140113747A1
• Time in Patent Office: 645 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0039 characterised by the material
• CPC Class Codes: A63B 37/0043 Hardness
• CPC Class Codes: A63B 37/0045 Thickness
• CPC Class Codes: A63B 37/0046 Deflection or compression
• CPC Class Codes: A63B 37/0047 Density; Specific gravity
• CPC Class Codes: A63B 37/0049 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0056 Hollow; Gas-filled
• CPC Class Codes: A63B 37/0059 Ionomer
• CPC Class Codes: A63B 37/0061 Coefficient of restitution
• CPC Class Codes: A63B 37/00621 Centre hardness
• CPC Class Codes: A63B 37/00622 Surface hardness
• CPC Class Codes: A63B 37/0064 Diameter
• CPC Class Codes: A63B 37/0065 Deflection or compression
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0087 Deflection or compression
• CPC Class Codes: A63B 37/0091 Density distribution amongst the different ball layers
• CPC Class Codes: A63B 37/0092 Hardness distribution amongst different ball layers

Abstract

Multi-layer golf balls comprising a center, intermediate layer, and cover are disclosed. The center is formed from a highly-neutralized acid copolymer composition.

Claims

1. A golf ball comprising:

a center having a diameter of from 0.80 inches to 1.40 inches, a compression of from 62 to 107, and formed from a composition comprising;

a copolymer of ethylene and an α

,β

-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;

an organic acid or salt thereof present in an amount of from 5 wt % to 50 wt %, based on the total weight of the copolymer and organic acid or salt thereof; and

a cation source present in an amount sufficient to neutralize greater than 80% of all acid groups present in the composition;

an outer core layer having a thickness of 0.090 inches or greater and formed from a composition having a Shore D hardness of from 40 to 70; and

a cover formed from a polyurethane;

wherein a sphere resulting from a combination of the center and the outer core layer has a compression of 80 or greater; and

wherein the Shore D hardness of the center composition is less than the Shore D hardness of the outer core layer composition.

2. The golf ball of claim 1, wherein the cation source is present in an amount sufficient to neutralize from 90% to 100% of the acid groups of the copolymer.

3. The golf ball of claim 1, wherein the cation source is present in an amount sufficient to neutralize 100% of the acid groups of the copolymer.

4. The golf ball of claim 1, wherein the polyurethane cover composition has a Shore D hardness of from 45 to 60.

5. The golf ball of claim 1, wherein the cover has a thickness of from 0.02 inches to 0.04 inches.

6. The golf ball of claim 1, wherein the center composition has a Shore D hardness of from 42 to 51.

7. The golf ball of claim 1, wherein the cation source is selected from the group consisting of metal cations of lithium, sodium, potassium, magnesium, calcium, barium, lead, tin, zinc, aluminum, and combinations thereof.

8. The golf ball of claim 1, wherein the cation source comprises magnesium.

9. The golf ball of claim 1, wherein the compression of the center is 80 or greater.

10. The golf ball of claim 1, wherein the salt of an organic acid comprises an organic acid selected from the group consisting of aliphatic organic acids, aromatic organic acids, saturated mono- or multi-functional organic acids, unsaturated mono- or multi-functional organic acids, and multi-unsaturated mono- or multi-functional organic acids.

11. The golf ball of claim 1, wherein the salt of an organic acid comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.

12. The golf ball of claim 1, wherein the salt of an organic acid comprises oleic acid.

13. The golf ball of claim 1, wherein the salt of an organic acid comprises a cation selected from the group consisting of barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, and calcium.

14. The golf ball of claim 1, wherein the salt of an organic acid comprises magnesium.

15. The golf ball of claim 1, wherein the golf ball additionally comprises an inner cover layer.

16. The golf ball of claim 15, wherein the inner cover layer is formed from a thermoplastic composition comprising a polymer selected from the group consisting of ionomeric copolymers and terpolymers, ionomer precursors, grafted metallocene-catalyzed polymers, high-crystalline acid polymers and their ionomers, and cationic ionomers.

17. The golf ball of claim 1, wherein the thickness of the outer core layer is from 0.090 inches to 0.180 inches.