Compositions containing fluorine substituted olefins and methods and systems using same
CAFCFirst Claim
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1. A method for producing an automobile air conditioning system for use with 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising:
- (a) providing an automobile vapor compression air conditioning system usable with refrigerant 1,1,1,2-tetrafluoroethane (HFC-134a) and having at least one compressor and at least one condenser; and
(b) providing a heat transfer composition in said system, said heat transfer composition consisting essentially of;
(i) at least about 50% by weight of a low toxicity refrigerant suitable for use in automobile air conditioning systems, said refrigerant consisting essentially of HFO-1234yf; and
(ii) lubricant consisting essentially of polyalkylene glycol(s), andwherein (1) said condenser is operable with said refrigerant in a temperature range that includes 150°
F. and (2) said system when operating at a condenser temperature of 150°
F. achieves a capacity relative to HFC-134a of about 1 and a Coefficient of Performance (COP) relative to HFC-134a of about 1.
1 Assignment
3 Petitions
Accused Products
Abstract
Disclosed are the use of fluorine substituted olefins, including tetra- and penta-fluoropropenes, in a variety of applications, including in methods of depositing catalyst on a solid support, methods of sterilizing articles, cleaning methods and compositions, methods of applying medicaments, fire extinguishing/suppression compositions and methods, flavor formulations, fragrance formulations and inflating agents.
15 Citations
20 Claims
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1. A method for producing an automobile air conditioning system for use with 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising:
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(a) providing an automobile vapor compression air conditioning system usable with refrigerant 1,1,1,2-tetrafluoroethane (HFC-134a) and having at least one compressor and at least one condenser; and (b) providing a heat transfer composition in said system, said heat transfer composition consisting essentially of; (i) at least about 50% by weight of a low toxicity refrigerant suitable for use in automobile air conditioning systems, said refrigerant consisting essentially of HFO-1234yf; and (ii) lubricant consisting essentially of polyalkylene glycol(s), and wherein (1) said condenser is operable with said refrigerant in a temperature range that includes 150°
F. and (2) said system when operating at a condenser temperature of 150°
F. achieves a capacity relative to HFC-134a of about 1 and a Coefficient of Performance (COP) relative to HFC-134a of about 1. - View Dependent Claims (2, 3, 4, 5)
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6. A method of conditioning the air in an automobile using an automobile air conditioning system including at least one compressor, at least one condenser and at least one evaporator, said method comprising:
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(a) utilizing in said system a heat transfer composition consisting essentially of; (i) at least about 50% by weight of a low toxicity refrigerant suitable for use in automobile air conditioning systems, said refrigerant consisting essentially of 2,3,3,3-tetrafluoropropene (HFO-1234yf); and (ii) lubricant consisting essentially of polyakylene glycol(s); and (b) removing heat from said HFO-1234yf by condensing said refrigerant in said condenser when said condenser is operating over a temperature range that that includes about 150°
F. - View Dependent Claims (7, 8, 9, 10, 11)
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12. A stable heat transfer composition for use in an automobile air conditioning system of the type having a condenser operating in a temperature range that includes about 150°
- F., said heat transfer composition consisting essentially of;
(i) at least about 50% by weight of a low toxicity refrigerant suitable for use in automobile air conditioning systems, said refrigerant consisting essentially of 2,3,3,3-tetrafluoropropene (HFO-1234yf); and (ii) lubricant consisting essentially of polyakylene glycol(s), wherein said refrigerant under the conditions of said condenser operating at about 150°
F. in said automobile air conditioning system has a capacity relative to HFC-134a of about 1 and a Coefficient of Performance (COP) relative to HFC-134a of about 1, and wherein said heat transfer composition is stable in contact with aluminum, steel and copper. - View Dependent Claims (13, 14, 15, 16, 17, 18)
- F., said heat transfer composition consisting essentially of;
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19. A method for providing a system for cooling air in an automobile comprising:
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(a) providing in the automobile a vapor compression air conditioning system having at least one compressor and at least one condenser; and (b) providing in said system a heat transfer composition consisting essentially of; (i) at least about 50% by weight of a low toxicity refrigerant suitable for use in automobile air conditioning systems, said refrigerant consisting essentially of 2,3,3,3-tetrafluoropropene (HFO-1234yf); and (ii) lubricant consisting essentially of polyakylene glycol(s), and wherein (1) said condenser is operable with said refrigerant in a temperature range that includes 150°
F. and (2) said system operating at a condenser temperature of 150°
F. achieves a capacity relative to HFC-134a of about 1 and a Coefficient of Performance (COP) relative to HFC-134a of about 1. - View Dependent Claims (20)
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Specification