Color matched coating for bus bars

• US 9,158,172 B2
• Filed: 03/13/2013
• Issued: 10/13/2015
• Est. Priority Date: 11/14/2012
• Status: Expired due to Fees

• Current Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Original Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Inventors: Sbar, Neil L., Savary, Jean-Philippe
• Primary Examiner(s): Lester, Evelyn A
• Application Number:
  US13/798,520
• Publication Number:
  US 20140133005A1
• Time in Patent Office: 944 Days
• Field of Search: 359265-275, 174/70.B, 174/71.B, 174/72.B, 174/88.B, 174/99.B, 174/68.2
• US Class Current: 1/1
• CPC Class Codes: B32B 17/10055 with at least one intermediate air space
• CPC Class Codes: B32B 17/10513 Electrochromic layer
• CPC Class Codes: E06B 2009/2464 featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• CPC Class Codes: E06B 9/24 Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blindsoperating, guiding or securing devices or arrangements for roll-type closures E06B9/56; free-hanging flexible screens A47H23/00
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell
• CPC Class Codes: G02F 2001/1555 Counter electrode
• CPC Class Codes: G02F 2202/00 Materials and properties

Abstract

In one aspect, the present invention is a system comprising an electrochromic device having at least one bus bar and a color obscuration material wherein the at least one bus bar is coated with an over-coating material that is 1) substantially non-porous; and 2) substantially color-matched to one of said color obscuration material, a spacer, or a polymer seal.

Claims

1. A system comprising an electrochromic device comprising:

a polymer seal;

a bus bar; and

an over-coating material, wherein the over-coating material is;

disposed between the bus bar and the polymer seal;

substantially non-porous; and

substantially color matched to one of an obscuration material, a spacer, or the polymer seal.

2. The system of claim 1, wherein said over-coating material is an ink.

3. The system of claim 2, further comprising a spacer, wherein said ink provides electrical insulation between said spacer and the bus bar.

4. The system of claim 3, wherein said ink masks a porosity of the bus bar and increases an inert gas retention performance.

5. The system of claim 4 wherein the over-coating material has an inert gas retention rate of at least about 90% over a period of about 30 days.

6. The system of claim 4, further comprising a solder pad, wherein said ink acts as a solder stop by not covering said solder pad.

7. The system of claim 6, wherein said ink completely covers all exposed surfaces of the bus bar in an insulated area of an IGU, under the spacer, and for a distance beyond said spacer.

8. The system of claim 7, wherein a distance that said ink covers the bus bar beyond said spacer is between 0.5 mm and 1.5 mm.

9. The system of claim 6, wherein said ink is selected from the group consisting of an organic acrylate ink and a modified silicone ink.

10. The system of claim 9, wherein said ink has an optical density greater than about 2 for thin sections less than about 0.005″

thick.

11. The system of claim 6, wherein said bus bar comprises a material that includes silver.

12. The system of claim 11, wherein said bus bar is metallic or silver in color.

13. The system of claim 12, wherein said bus bar is substantially color matched to said spacer.

14. The system of claim 13, wherein said bus bar is porous.

15. The system of claim 13, wherein said bus bar is centrally located within an IGU.

16. An insulated glass unit comprising an electrochromic device having at least two bus bars, a polymer seal, and a color obscuration material, wherein:

said at least two bus bars are porous and coated with an over-coating material that is substantially non-porous and substantially color-matched to the color obscuration material; and

the over-coating material is disposed between the polymer seal and the at least two bus bars.

17. The insulated glass unit of claim 16, wherein said non-porous color-matched over-coating material is an ink.

18. The insulated glass unit of claim 17, further comprising at least one spacer, wherein said ink provides electrical insulation between said at least two bus bars and at least one of said at least one spacer.

19. The insulated glass unit of claim 18, wherein said ink masks the porosity of the at least two bus bars and increases an inert gas retention performance.

20. The insulated glass unit of claim 19, wherein said ink is black or a shade of black.

21. The insulated glass unit of claim 19, further comprising a solder pad, wherein said ink acts as a solder stop by not covering said solder pad.

22. The insulated glass unit of claim 21, wherein said ink completely covers all exposed surfaces of the at least two bus bars in an insulated area of an IGU, under the spacer, and for a distance beyond the spacer.

23. The insulated glass unit of claim 22, wherein said distance that said ink covers beyond said spacer is between 0.5 mm and 1.5 mm.

24. The insulated glass unit of claim 21, wherein said ink selected from the group consisting of an organic acrylate ink and a modified silicone ink.

25. The insulated glass unit of claim 24, wherein said ink has an optical density greater than about 2 for thin sections less than about 0.005″

thick.

26. The insulated glass unit of claim 21, wherein said at least two bus bars comprise a material that includes silver.

27. The insulated glass unit of claim 26, wherein said at least two bus bars are metallic or silver in color.

28. The insulated glass unit of claim 27, wherein said at least two bus bars are centrally located within the IGU.

29. A method of increasing an inert gas retention performance of an electrochromic device including a bus bar and a color obscuration material comprising:

at least partially coating said bus bar with an over-coating material that is substantially non-porous; and

substantially color-matched to said color obscuration material; and

placing a polymer seal adjacent to the over-coating material, such that the bus bar and over-coating layer extend from a sealed interior portion to locations outside the interior region and spaced apart from the polymer seal.

30. The method of claim 29, wherein said substantially non-porous over-coating material is selected from the group consisting of an organic acrylate based ink and a modified silicone ink.

31. The method of claim 30, wherein said inert gas retention is at least about 90% over about 30 days.

32. The method of 30, wherein said electrochromic device further includes a spacer, and wherein said over-coating material is substantially color-matched to said spacer.

33. The method of claim 32, wherein the step of partially coating said bus bar with a substantially non-porous over-coating material comprises printing the ink using an inkjet printing method.

34. The method of claim 33, wherein said inkjet printing method uses a piezoelectric membrane.

35. The method of claim 34, further comprising the step of curing the ink with UV lamps.

36. The method of claim 32, wherein the step of partially coating said bus bar with a substantially non-porous over-coating material comprises printing the ink using a nozzle printing method.

37. The method of claim 36, wherein said nozzle printing method dispenses the ink through a circular or slot nozzle.

38. The method of claim 37, wherein printing the ink is performed using a program such that printing follows the bus bar configuration.

39. The method of claim 38, further comprising the step of curing the ink in a furnace so that a temperature of the glass and EC films does not exceed about 200°

C.

40. A system comprising an electrochromic device comprising:

a substrate;

a polymer seal having a first end at a gas filled cavity and a second end opposite the first end;

a bus bar disposed between the substrate and polymer seal, wherein the bus bar extends from within the gas filled cavity to beyond the second end of the polymer seal;

an over-coating material coated over the bus bar, wherein the over-coating material is substantially non-porous and substantially black or a shade of black or grey.

41. The system of claim 40, wherein the bus bar includes pores.

42. The system of claim 40, further comprising a solder joint attached to the bus bar, wherein the solder joint is:

spaced part from the over-coating material and the polymer seal; and

closer to the second end of the polymer seal than the first end of the polymer seal.