Solid state lighting devices including quantum confined semiconductor nanoparticles, an optical component for a solid state lighting device, and methods

• US 9,167,659 B2
• Filed: 11/05/2010
• Issued: 10/20/2015
• Est. Priority Date: 05/06/2008
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: QD Vision, Inc. (Samsung Electronics Co. Ltd.)
• Inventors: Coe-Sullivan, Seth, Linton, John R., Sadasivan, Sridhar, Squires, Emily M.
• Primary Examiner(s): CARIASO, ALAN B
• Application Number:
  US12/940,355
• Publication Number:
  US 20110103064A1
• Time in Patent Office: 1,810 Days
• Field of Search: 362/84, 362/230, 362/231, 362/260, 362/311.02, 257/100, 257/103, 313/485, 313/486, 313/498, 313/503
• US Class Current: 1/1
• CPC Class Codes: F21V 13/14 the elements being filters or photoluminescent elements, reflectors and refractors
• CPC Class Codes: F21V 3/0625 the material diffusing light, e.g. translucent plastics
• CPC Class Codes: F21V 3/08 the material comprising photoluminescent substances
• CPC Class Codes: F21V 3/12 the coatings comprising photoluminescent substances
• CPC Class Codes: F21V 9/32 characterised by the arrangement of the photoluminescent material
• CPC Class Codes: F21V 9/38 Combination of two or more photoluminescent elements of different materials
• CPC Class Codes: F21Y 2115/10 Light-emitting diodes [LED]
• CPC Class Codes: H01L 2933/0091 Scattering means in or on the semiconductor body or semiconductor body package H01L33/22 takes precedence
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H05B 33/145 Arrangements of the electroluminescent material

Abstract

A solid state lighting device including a light source capable of emitting white light including a blue spectral component and having a deficiency in a spectral region, and an optical component that is positioned to receive at least a portion of the light generated by the light source, the optical component comprising an optical material for converting at least a portion of the blue spectral component of the light to one or more predetermined wavelengths such that light emitted by the solid state lighting device includes light emission from the light source supplemented with light emission at one or more predetermined wavelengths, wherein the optical material comprises quantum confined semiconductor nanoparticles. Also disclosed is lighting fixture, a cover plate for a lighting fixture and a method.

Claims

1. A solid state lighting device comprising a phosphor converted LED light source that emits white light including a blue spectral component and having a deficiency in at least one spectral region, and an optical component that is positioned to receive at least a portion of the white light generated by the light source and supplement the spectrum of the white light passing through the optical component, the optical component comprising an optical material for converting at least a portion of the blue spectral component of the white light to one or more predetermined wavelengths such that light emitted by the solid state lighting device includes white light emission from the light source supplemented with light emission at one or more predetermined wavelengths in a deficient spectral region of the light source, wherein the optical material comprises quantum confined semiconductor nanoparticles distributed in a host material, wherein the optical material is fully encapsulated by one or more barrier materials, and wherein the optical component is not in direct contact with the light source.

2. A solid state lighting device in accordance with claim 1 wherein at least one predetermined wavelength is in a range from about 575 nm to about 650 nm.

3. A solid state lighting device in accordance with claim 1 wherein at least one predetermined wavelength is in a range from about 450 nm to about 500 nm.

4. A solid state lighting device in accordance with claim 1 wherein the light emitted by the light source has a General Color Rendering Index (R_a) less than 80.

5. A solid state lighting device in accordance with claim 4 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (R_a) greater than 80.

6. A solid state lighting device in accordance with claim 4 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (R_a) greater than 85.

7. A solid state lighting device in accordance with claim 4 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (R_a) greater than 90.

8. A solid state lighting device in accordance with claim 4 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (R_a) greater than 95.

9. A solid state lighting device in accordance with claim 1 wherein the General Color Rendering Index (R_a) of the light emitted by the solid state lighting device is at least 10% higher than the General Color Rendering Index (R_a) of the light emitted by the light source.

10. A solid state lighting device in accordance with claim 1 wherein the solid state lighting device maintains greater than 70% of the light source lumens per watt efficiency.

11. A solid state lighting device in accordance with claim 1 wherein the solid state lighting device maintains greater than 100% of the light source lumens per watt efficiency.

12. A solid state lighting device in accordance with claim 1 wherein the solid state lighting device maintains greater than 110% of the light source lumens per watt efficiency.

13. A solid state lighting device in accordance with claim 1 wherein the lumens per watt efficiency of the solid state lighting device does not substantially vary as a function of the color temperature of the solid state lighting device.

14. A solid state lighting device in accordance with claim 1 wherein quantum confined semiconductor nanoparticles are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.

15. A solid state lighting device in accordance with claim 1 wherein the optical material further comprises light scatterers.

16. A solid state lighting device in accordance with claim 15 wherein light scattering particles are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.

17. A solid state lighting device in accordance with claim 1 wherein the optical component further includes a support element and the optical material comprising quantum confined semiconductor nanoparticles is disposed over a surface of the support element.

18. A solid state lighting device in accordance with claim 17 wherein the support element is optically transparent to the light output from the solid state lighting device.

19. A solid state lighting device in accordance with claim 17 wherein the support element comprises a cover plate for the solid state lighting device.

20. A solid state lighting device in accordance with claim 1 wherein the temperature at the location of the nanoparticles during operation of the solid state lighting device is less than 90°

C.

21. A solid state lighting device in accordance with claim 1 wherein the light source comprises a blue light emitting semiconductor LED including a phosphor material for converting the blue LED light output to white light.

22. A solid state lighting device in accordance with claim 21 wherein optical material comprises quantum confined semiconductor nanoparticles capable of emitting red light.

23. A solid state lighting device in accordance with claim 1 wherein the optical material comprises quantum confined semiconductor nanoparticles capable of emitting red light.

24. A solid state lighting device in accordance with claim 1 wherein the quantum confined semiconductor nanoparticles comprise a semiconductor nanocrystal including a core comprising a semiconductor material and an inorganic shell disposed on at least a portion of a surface of the core.

25. A solid state lighting device in accordance with claim 1 wherein the light emitted from the solid state lighting device has a correlated color temperature that is at least about 1000K less than that of light emitted from the light source.

26. A solid state lighting device in accordance with claim 1 wherein the light emitted from the solid state lighting device has a correlated color temperature that is at least about 2000K less than that of light emitted from the light source.

27. A solid state lighting device in accordance with claim 1 wherein the light emitted from the solid state lighting device has a correlated color temperature that is at least about 3000K less than that of light emitted from the light source.

28. A solid state lighting device in accordance with claim 1 wherein the light emitted from the solid state lighting device has a correlated color temperature that is at least about 4000K less than that of light emitted from the light source.

29. A solid state lighting device in accordance with claim 1 wherein the optical component comprises two or more different types of quantum confined semiconductor nanoparticles, wherein each different type of quantum confined semiconductor nanoparticles emits light at predetermined wavelength that is different from the predetermined wavelength emitted by at least one of another type of quantum confined semiconductor nanoparticles included in the optical material, and wherein two or more different predetermined wavelengths are selected such that the optical material will compensate for two or more spectral deficiencies of the light source.

30. A solid state lighting device in accordance with claim 1 wherein the optical component is fully encapsulated.

31. A solid state lighting device comprising a phosphor converted LED light source that emits white light including emission in the blue spectral region and having a deficiency in the orange to red spectral region;

and an optical component that is positioned to receive and supplement the spectrum of white light emitted by the LED and passing through the optical component, the optical component comprising an optical material for converting at least a portion of the emission in the blue spectral region to light in the spectral region with a wavelength in a range from about 575 nm to about 650 nm such that light emitted by the solid state lighting device includes white light emission from the LED light source supplemented with converted light emission, wherein the optical material comprises quantum confined semiconductor nanoparticles and light scatterers distributed in a host material, wherein the optical material is fully encapsulated by one or more barrier materials, and wherein the optical component is not in direct contact with the light source.

32. A solid state lighting device in accordance with claim 31 wherein the quantum confined semiconductor nanoparticles comprise a semiconductor nanocrystal including a core comprising a semiconductor material and an inorganic shell disposed on at least a portion of a surface of the core.

33. An optical component for use with a light source that emits white light including a blue spectral component and at least one spectral deficiency in another region of the spectrum of the white light emitted by the light source, the optical component comprising an optically transparent substrate comprising a diffuser and an optical material for converting at least a portion of the blue spectral component of white light output from the light source passing through the optical component to one or more predetermined wavelengths, wherein the optical material comprises quantum confined semiconductor nanoparticles and light scatterers distributed in a host material, wherein the optical material is disposed over a surface of the optically transparent substrate, and wherein the optical material is fully encapsulated by one or more barrier materials.

34. An optical component in accordance with claim 33 wherein one or more of the predetermined wavelengths is selected to compensate for the deficiency in the spectral region of the white light emitting source.

35. An optical component in accordance with claim 33 wherein one or more of the predetermined wavelengths are in a range from about 575 nm to 650 nm.

36. An optical component in accordance with claim 33 wherein the light source emits white light with a spectral deficiency in the cyan spectral region and the predetermined wavelength can be in a range from about 450 nm to about 500 nm.

37. An optical component in accordance with claim 33 wherein the optical component comprises two or more different types of quantum confined semiconductor nanoparticles, wherein each different type of quantum confined semiconductor nanoparticles emits light at predetermined wavelength that is different from the predetermined wavelength emitted by at least one of another type of quantum confined semiconductor nanoparticles included in the optical material, and wherein two or more different predetermined wavelengths are selected such that the optical material will compensate for one or more spectral deficiencies of the white light emitting source.

38. An optical component in accordance with claim 33 wherein the optical component includes two or more different types of quantum confined semiconductor nanoparticles that emit at different predetermined wavelengths, wherein the different types of quantum confined semiconductor nanoparticles are included in two or more different optical materials.

39. An optical component in accordance with claim 33 wherein the quantum confined semiconductor nanoparticles have a solid state quantum efficiency of at least 40%.

40. An optical component in accordance with claim 33 wherein the quantum confined semiconductor nanoparticles maintain at least 40% efficiency during use of the optical component.

41. An optical component in accordance with claim 33 wherein the optical component is fully encapsulated.