Method of manufacture of a metal hydride fuel supply

• US 9,169,976 B2
• Filed: 11/21/2012
• Issued: 10/27/2015
• Est. Priority Date: 11/21/2011
• Status: Active Grant

• Current Assignee: Ardica Technologies Incorporated
• Original Assignee: Ardica Technologies Incorporated
• Inventors: Peterson, Andrew Philip Gust, Wooley, Eric Allen, Braithwaite, Daniel, Galvan, Sergio Morales
• Primary Examiner(s): Akram, Imran
• Application Number:
  US13/683,973
• Publication Number:
  US 20130126013A1
• Time in Patent Office: 1,070 Days
• US Class Current: 1/1
• CPC Class Codes: C01B 3/0005 Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes purification of hydrogen C01B3/508; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
• CPC Class Codes: C01B 3/04 by decomposition of inorganic compounds, e.g. ammonia C01B3/0005 takes precedence
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: F17C 11/005 for hydrogen
• CPC Class Codes: F17D 1/00 Pipe-line systems conveying articles or materials through a pipe- line by means of a fluid carrier B65G51/00, B65G53/00; liquids B67D; special devices for transferring liquids from bulk storage containers into vehicles or boats or vice versa, e.g. loading or unloading vehicles or portable containers B67D7/00; conveying material which has been excavated by a dredger or soil shifter through a pipe-line E02F7/10; sewer pipe-line systems E03F3/00; thermal insulation of pipe-lines F16L59/00; central heating systems F24D
• CPC Class Codes: H01M 8/04208 Cartridges, cryogenic media or cryogenic reservoirs
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/065 by dissolution of metals or alloys; by dehydriding metallic substances
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 137/6416 With heating or cooling of the system

Abstract

A high energy density fuel source that reduces hydride expansion during hydrogen release, including a rigid, thermally insulated container defining an internal volume, a heater mechanism disposed within the internal volume, and a metal hydride rod thermally connected to the heater mechanism, wherein the heater mechanism and metal hydride rod substantially occupying the entirety of the internal volume. The metal hydride rod preferably includes a malleable encapsulation compressed about, thermally coupled to, and substantially encapsulating a volume of compressed metal hydride powder, the malleable encapsulation defined by a first, thermally conductive, malleable cup inverted over a second, thermally conductive, malleable cup, the compressed malleable encapsulation defining a tortuous fluid flow path from the metal hydride to the internal volume of the container.

Claims

1. A method of manufacturing a metal hydride fuel source that reduces fuel source expansion during fuel release, comprising:

providing a first and a second malleable repository, each defining an open end and a closed end opposing the open end;

depositing metal hydride powder into the first repository;

encapsulating the metal hydride powder between the first and second repository by nesting the second repository with the first repository;

applying a compressive force to the closed ends of the first and second deformable repositories, the compressive force sufficient to compress the powder into a substantially cohesive pellet; and

encapsulating the pellet between the first repository and a cap and then nesting the second repository over the first repository such that the cap and the pellet are encapsulated between the first and second repositories.

2. The metal hydride fuel source of claim 1, wherein encapsulating the metal hydride powder further comprises sealing the metal hydride powder between the first and second repositories by folding an edge defining the open end of the second repository over the closed end of the first repository.

3. The metal hydride fuel source of claim 1, further comprising compacting and regrinding the metal hydride powder prior to depositing the metal hydride powder into the first repository.

4. The metal hydride fuel source of claim 1, wherein applying a compressive force to the closed ends of the first and second repository comprises compressing an uncompressed fuel source with a die press.

5. The metal hydride fuel source of claim 1, wherein the compressive force is sufficient to fuse one or more particulates of the metal hydride powder to the first repository.

6. The metal hydride fuel source of claim 1, wherein the compressive force is sufficient to change the crystal structure of the metal hydride.

7. A method of manufacturing a metal hydride fuel source comprising:

manufacturing an encapsulated metal hydride pellet, comprising;

providing a first and a second malleable repository, each repository defining an open end and a closed end opposing the open end;

depositing loose metal hydride powder into the first repository;

encapsulating the metal hydride powder between the first and second repository by nesting the second repository with the first repository; and

applying a compressive force to the closed ends of the first and second deformable repositories, the compressive force sufficient to compress the powder into a substantially cohesive pellet;

inserting the encapsulated pellet into an internal volume defined by a substantially rigid carrier, the internal volume having substantially the same perimeter as the encapsulated pellet;

thermally coupling a heating mechanism to the encapsulated pellet within the carrier; and

encapsulating the encapsulated pellet and heating mechanism within the internal carrier by a cap, the encapsulated pellet and heater substantially filling the volume defined between the carrier and the cap.

8. The metal hydride fuel source of claim 7, wherein the cap forms a substantially fluid impermeable seal with the carrier, the cap further comprising a fuel outlet fluidly connecting the carrier exterior to the internal volume.

9. The metal hydride fuel source of claim 7, further comprising applying a thermal interface between the heating mechanism and the pellet.

10. The metal hydride fuel source of claim 9, wherein the thermal interface comprises metal hydride.

11. The metal hydride fuel source of claim 9, wherein the thermal interface comprises thermal grease.

12. The metal hydride fuel source of claim 7, wherein the second repository nests over the first repository, the open end of the second repository proximal the closed end of the first repository.

13. The metal hydride fuel source of claim 7, wherein applying a compressive force comprises compressing the encapsulated metal hydride pellet within the carrier, wherein the carrier applies a compressive force to the closed end of the first repository.

14. The metal hydride fuel source of claim 7, wherein inserting the encapsulated pellet into the internal volume comprises inserting into the internal volume a plurality of planar resistive heating mechanisms alternating with a plurality of encapsulated pellets.

15. The metal hydride fuel source of claim 7, wherein the carrier comprises thermal insulation.