Data validation and classification in optical analysis systems

• US 9,170,154 B2
• Filed: 06/26/2007
• Issued: 10/27/2015
• Est. Priority Date: 06/26/2006
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Myrick, Michael L., Priore, Ryan J., Freese, Robert P., Blackburn, John C.
• Primary Examiner(s): Gaffin, Jeffrey A
• Assistant Examiner(s): Bharadwaj, Kalpana
• Application Number:
  US12/295,631
• Publication Number:
  US 20090299946A1
• Time in Patent Office: 3,045 Days
• Field of Search: 706/52
• US Class Current: 1/1
• CPC Class Codes: G01J 2003/1213 Filters in general, e.g. dichroic, band
• CPC Class Codes: G01J 2003/2866 Markers; Calibrating of scan
• CPC Class Codes: G01J 3/02 Details
• CPC Class Codes: G01J 3/0291 Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/28 Investigating the spectrum using colour filters G01J3/51
• CPC Class Codes: G01N 2201/129 Using chemometrical methods

Abstract

A method of classifying information in an optical analysis system includes obtaining calibration data defining a plurality of data points, each data point representing values for two or more detectors when sampling a material used to construct a multivariate optical element. Based on the calibration data, one or more validation models can be developed to indicate one or more ranges of expected results. Validation data comprising the models can be used to compare data points representing values for two or more detectors when performing a measurement of a material to determine if the data points fall within an expected range. Classification data can be generated based on the comparison and, in some embodiments, one or more indicators, such as a confidence level in a measurement, can be provided.

Claims

1. A method of classifying measurement results in a multivariate optical computing system, the method comprising:

receiving a first signal based on a first portion of an illumination light that has interacted with a sample, the first signal modified by at least one spectral element;

receiving a second signal based on the first portion of the illumination light;

separating a second portion of the illumination light from a first portion of the illumination light before the first portion of the illumination light has interacted with the sample;

determining a baseline for the first signal and the second signal using a calibration signal from the second portion of the illumination light, the calibration signal modified by the at least one spectral element; and

providing classifying information based on determining if the first signal and the second signal lie in a range of expected results.

2. The method as set forth in claim 1, wherein the at least one spectral element comprises a multivariate optical element.

3. The method as set forth in claim 2, wherein the first signal represents the dot product of a spectrum of light with a weighted regression vector.

4. The method as set forth in claim 1, wherein providing classifying information is further based on validation data indicating a range of expected results.

6. The method as set forth in claim 1, wherein providing classifying information comprises indicating whether a measurement is valid.

7. The method as set forth in claim 1, wherein providing classifying information comprises indicating a confidence interval in which a measurement lies.

8. The method as set forth in claim 1, further comprising providing at least one measurement result based on data including the first and second signals and providing at least one indicator alongside or as part of the at least one measurement.

19. The method of claim 1 wherein the sample comprises oil contained in water or water contained in oil.

5. A method of classifying measurement results in a multivariate optical computing system, the method comprising:

receiving a first signal based on light that has interacted with a material of interest and at least one spectral element;

receiving a second signal based on light that has interacted with the material of interest; and

providing classifying information based on determining if the first signal and the second signal lie in a range of expected results;

wherein the validation data comprises data indicating at least one boundary that defines expected results as a function of the value of the first and second signal; and

wherein providing classifying information comprises determining where a given pair of simultaneous values for the first and second signal lie relative to the at least one boundary.

22. The method of claim 5 wherein the material of interest comprises oil contained in water or water contained in oil.

23. The method of claim 5 wherein the classifying information comprises an octane rating or a lead content in a gasoline sample.

9. An optical computing system comprising at least one computing device, the at least one computing device adapted to:

receive data from a first detector indicative of a first portion of an illumination light that has interacted with a sample, the first signal modified by at least one spectral element;

receive data from a second detector indicative of the first portion of the illumination light;

separating a second portion of the illumination light from a first portion of the illumination light before the first portion of the illumination light has interacted with the sample;

determining a baseline for the data from the first and second detectors using a calibration signal from the second portion of the illumination light, the calibration signal modified by the at least one spectral element; and

produce classification data based on determining if the data from the first and second detectors lie in a range of expected results.

10. The system as set forth in claim 9, wherein the at least one computing device is further adapted to access validation data and to produce classification data based on evaluating the data from the first and second detectors and the validation data.

12. The system as set forth in claim 9, wherein the classification data comprises an indicator of whether a measurement based on data from at least one of the first and second detectors is valid.

13. The system as set forth in claim 9, wherein the classification data comprises an indicator of a confidence interval of a measurement based on data from at least one of the first and second detectors.

14. The system as set forth in claim 9, wherein the at least one computing device is further adapted to:

provide at least one measurement result based on data from the first and second detectors; and

provide at least one indicator of the classification data alongside or as part of the at least one measurement result.

15. The system as set forth in claim 9, further comprising:

at least one light source configured to illuminate a material of interest;

first and second broadband detectors each configured to detect light over a wavelength range and to provide data to the at least one computing device; and

a multivariate optical element positioned to interact with light from the material of interest;

wherein said first broadband detector is positioned to receive light that has interacted with the material of interest and the multivariate optical element; and

wherein said second broadband detector is positioned to receive light that has interacted with the material of interest, but not the multivariate optical element.

16. The system as set forth in claim 9, wherein the at least one computing device comprises a computer adapted by software to receive data and produce classification data.

11. An optical computing system comprising at least one computing device, the at least one computing device adapted to:

receive data from a first detector indicative of light that has interacted with a material of interest and at least one spectral element;

receive data from a second detector indicative of light that has interacted with the material of interest; and

produce classification data based on determining if the data from the first and second detectors lie in a range of expected results;

wherein the at least one computing device is further adapted to access validation data and to produce classification data based on evaluating the data from the first and second detectors and the validation data;

wherein the validation data comprises data indicating at least one boundary that defines expected results as a function of the value of the first and second signal; and

wherein producing classification data comprises determining where a given pair of simultaneous values for the first and second signal lie relative to the at least one boundary.

24. The optical computing system of claim 11 wherein the material of interest comprises oil contained in water or water contained in oil.

25. The optical computing system of claim 11 wherein the classifying information comprises an octane rating or a lead content in a gasoline sample.

17. A method of configuring a measurement system, the method comprising:

obtaining calibration data, the calibration data comprising a plurality of data points;

based on the calibration data, constructing at least one multivariate optical element based on the data points;

based on the data points, preparing a validation model, the validation model comprising a boundary of values dividing an area into a valid result area and an invalid result area;

including the at least one multivariate optical element in a measurement system comprising at least one controller; and

configuring the at least one controller to validate measurement results based on the validation model.

18. The method of claim 17, wherein validation model further comprises a two-dimensional area defined by the plurality of data points, the two-dimensional area comprising one or more boundaries.

20. A method of classifying measurement results in a multivariate optical computing system, the method comprising:

receiving a first signal based on a first portion of an illumination light that has interacted with a material of interest, the first signal modified by at least one spectral element;

receiving a second signal based on the first portion of the illumination light;

providing classifying information based on determining if the first signal and the second signal lie in a range of expected results; and

determining a baseline of at least one of the first signal and the second signal using a second portion of the illumination light, wherein;

the second portion of the illumination light is separated from the first portion of the illumination light before the first portion of the illumination light has interacted with the sample.

26. The method of claim 20 wherein the sample comprises oil contained in water or water contained in oil.

27. The method of claim 20 wherein the classifying information comprises an octane rating or a lead content in a gasoline sample.

21. An optical computing system comprising at least one computing device, the at least one computing device adapted to:

receive data from a first detector indicative of a first portion of an illumination light that has interacted with a sample, the first signal modified by at least one spectral element;

receive data from a second detector indicative of the first portion of the illumination light;

determine a baseline for at least one of the data from a first detector and the second detector using data indicative of a second portion of the illumination light, wherein;

the second portion of the illumination light is separated from the first portion of the illumination light before the first portion of the illumination light has interacted with the sample; and

produce classification data based on determining if the data from the first and second detectors lie in a range of expected results.

28. The optical computing system of claim 21 wherein the material of interest comprises oil contained in water or water contained in oil.

29. The optical computing system of claim 21 wherein the classifying information comprises an octane rating or a lead content in a gasoline sample.