Solid state catholytes and electrolytes for energy storage devices
First Claim
1. An energy storage device comprising a cathode region, the cathode region comprising:
- an active material region comprising an active material that expands or contracts from a first volume to a second volume during a period of charge and discharge;
a catholyte material spatially confined in spatial regions not occupied by the active material region, wherein the catholyte material comprises;
a lithium element from 30 to 50 atomic % of the catholyte material;
a silicon element from greater than 0 to 10 atomic % of the catholyte material;
a tin element from greater than 0 to 10 atomic % of the catholyte material;
a phosphorous element from 5 to 17 atomic % of the catholyte material;
a sulfur element from 35 to 60 atomic % of the catholyte material; and
an oxygen element from greater than 0 to 15 atomic % of the catholyte material,wherein the atomic amounts of silicon and tin are equal, andwherein the catholyte material is characterized by primary CuKα
XRD peaks at 2θ
=30°
±
1°
, 2θ
=33°
±
1°
, and 2θ
=43°
±
1°
.
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0 Petitions
Accused Products
Abstract
The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiaMPbSc (LMPS) [M=Si, Ge, and/or Sn] containing material.
18 Citations
21 Claims
-
1. An energy storage device comprising a cathode region, the cathode region comprising:
-
an active material region comprising an active material that expands or contracts from a first volume to a second volume during a period of charge and discharge; a catholyte material spatially confined in spatial regions not occupied by the active material region, wherein the catholyte material comprises; a lithium element from 30 to 50 atomic % of the catholyte material; a silicon element from greater than 0 to 10 atomic % of the catholyte material; a tin element from greater than 0 to 10 atomic % of the catholyte material; a phosphorous element from 5 to 17 atomic % of the catholyte material; a sulfur element from 35 to 60 atomic % of the catholyte material; and an oxygen element from greater than 0 to 15 atomic % of the catholyte material, wherein the atomic amounts of silicon and tin are equal, and wherein the catholyte material is characterized by primary CuKα
XRD peaks at 2θ
=30°
±
1°
, 2θ
=33°
±
1°
, and 2θ
=43°
±
1°
. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)
-
Specification