Flue gas treatment system

• US 9,174,168 B2
• Filed: 11/11/2010
• Issued: 11/03/2015
• Est. Priority Date: 11/12/2009
• Status: Active Grant

• Current Assignee: General Electric Technology GmbH (GE Vernova, Inc.)
• Original Assignee: Alstom Technology Ltd. (Alstom SA)
• Inventors: Koss, Peter Ulrich
• Primary Examiner(s): Orlando, Amber
• Assistant Examiner(s): PRECHT, BRITANNY E.
• Application Number:
  US13/508,591
• Publication Number:
  US 20130042759A1
• Time in Patent Office: 1,818 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2251/2062 Ammonia
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/507 by treating the gases with other liquids
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The present invention relates to a gas cleaning system for cleaning a gas stream containing carbon dioxide and sulfur dioxide, said gas cleaning system comprising: a pre-conditioning section (3); a CO₂ removal stage (5); and a post-conditioning section (4); said pre-conditioning section comprising at least two gas-liquid contacting devices (19,20) arranged upstream of the CO₂ removal stage (5) with respect to the flow direction of the gas; and said post-conditioning section comprising at least two gas-liquid contacting devices (30,31) arranged downstream of the CO₂ removal stage with respect to the flow direction of the gas. The present invention further relates to a method for cleaning a gas stream containing carbon dioxide and sulfur dioxide, said method including removing, at least partly, carbon dioxide from the gas stream in a carbon dioxide removal step by bringing the gas stream into contact with a liquid comprising ammonia; contacting the gas stream with liquid in at least two steps upstream of the carbon dioxide removal step; and contacting the gas stream with liquid in at least two steps downstream of the carbon dioxide removal step.

Claims

1. A method for cleaning a gas stream containing carbon dioxide and sulfur dioxide, said method including removing, at least partly, carbon dioxide from the gas stream in a carbon dioxide removal step by bringing the gas stream into contact with a liquid comprising ammonia such that the gas stream is depleted in carbon dioxide and enriched in ammonia, said method comprising the steps of:

a) bringing the gas stream into direct contact with a liquid stream in a first upstream gas-liquid contacting device upstream of the carbon dioxide removal step, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate,

b) bringing the gas stream depleted in sulfur dioxide into direct contact with a liquid stream in a second upstream gas-liquid contacting device upstream of the carbon dioxide removal step, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate,

c) removing, at least partly, carbon dioxide from the gas stream by bringing the gas stream depleted in sulfur dioxide into contact with a liquid comprising ammonia such that the gas stream is depleted in carbon dioxide,

d) bringing the gas stream depleted in carbon dioxide into contact with a liquid stream enriched in sulfate in a first downstream gas-liquid contacting device downstream of the carbon dioxide removal step, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia,

e) bringing the gas stream depleted in ammonia into contact with a liquid stream enriched in sulfate in a second downstream gas-liquid contacting device downstream of the carbon dioxide removal step, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia,

f) withdrawing at least a portion of the liquid stream used in the second upstream gas-liquid contacting device and reusing the withdrawn liquid in a downstream gas-liquid contacting device and forwarding the remaining portion to the first upstream gas-liquid contacting device, or withdrawing at least a portion of the liquid stream used in the second downstream gas-liquid contacting device and reusing the withdrawn liquid in an upstream gas-liquid contacting device and forwarding the remaining portion to the first downstream gas-liquid contacting device.

2. The method according to claim 1, wherein in step f) at least a portion of the liquid stream used in the second upstream gas-liquid contacting device, is reused in the first downstream gas-liquid contacting device.

3. The method according to claim 1, wherein in step f) at least a portion of the liquid stream used in the second downstream gas-liquid contacting device, is reused in the first upstream gas-liquid contacting device.

4. The method according to claim 1, further comprising the steps:

b1) bringing the gas stream depleted in sulfur dioxide from step b) into direct contact with a liquid stream in a third upstream gas-liquid contacting device upstream of the carbon dioxide removal, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate, and

e1) bringing the gas stream depleted in ammonia from step e) into contact with a liquid stream enriched in sulfate in a third downstream gas-liquid contacting device downstream of the carbon dioxide removal, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia,

and wherein step f) comprises withdrawing at least a portion of the liquid stream used in the second upstream gas-liquid contacting device and reusing the withdrawn liquid in a downstream gas-liquid contacting device, and withdrawing at least a portion of the liquid stream used in the second downstream gas-liquid contacting device and reusing the withdrawn liquid in an upstream gas-liquid contacting device.

6. The method according to claim 4, wherein used liquid from the first upstream gas-liquid contacting device is reused in the third downstream gas-liquid contacting device.

7. The method according to claim 4, wherein used liquid from the first downstream gas-liquid contacting device is reused in the third upstream gas-liquid contacting device.

8. The method according to claim 4, wherein the liquid stream which is brought into contact with the gas stream in e1) has a pH of <

6.5.

9. The method according to claim 4, wherein the liquid stream which is brought into contact with the gas stream in step b1) has a pH of >

6.5.

10. The method according to claim 4, wherein the liquid flow rate in steps b1) and/or d) is controlled such that in at least one of the steps b1) and/or d) the integral heat capacities of the gas stream and the liquid stream entering the gas-liquid contacting device differ by less than 10%.

5. A method for cleaning a gas stream containing carbon dioxide and sulfur dioxide, said method including removing, at least partly, carbon dioxide from the gas stream in a carbon dioxide removal step by bringing the gas stream into contact with a liquid comprising ammonia such that the gas stream is depleted in carbon dioxide and enriched in ammonia, said method comprising the steps of:

a) bringing the gas stream into direct contact with a liquid stream in a first upstream gas-liquid contacting device upstream of the carbon dioxide removal step, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate,

b) bringing the gas stream depleted in sulfur dioxide into direct contact with a liquid stream in a second upstream gas-liquid contacting device upstream of the carbon dioxide removal step, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate,

c) removing, at least partly, carbon dioxide from the gas stream by bringing the gas stream depleted in sulfur dioxide into contact with a liquid comprising ammonia such that the gas stream is depleted in carbon dioxide,

d) bringing the gas stream depleted in carbon dioxide into contact with a liquid stream enriched in sulfate in a first downstream gas-liquid contacting device downstream of the carbon dioxide removal step, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia,

e) bringing the gas stream depleted in ammonia into contact with a liquid stream enriched in sulfate in a second downstream gas-liquid contacting device downstream of the carbon dioxide removal step, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia,

f) withdrawing at least a portion of the liquid stream used in the second upstream gas-liquid contacting device and reusing the withdrawn liquid in a downstream gas-liquid contacting device, or withdrawing at least a portion of the liquid stream used in the second downstream gas-liquid contacting device and reusing the withdrawn liquid in an upstream gas-liquid contacting device; and

further comprising the steps of;

b1) bringing the gas stream depleted in sulfur dioxide from step b) into direct contact with a liquid stream in a third upstream gas-liquid contacting device upstream of the carbon dioxide removal, cooling the gas stream, and absorbing into the liquid at least a part of the sulfur dioxide of the gas stream such that the gas stream is depleted in sulfur dioxide and said liquid stream is enriched in sulfate, and

e1) bringing the gas stream depleted in ammonia from step e) into contact with a liquid stream enriched in sulfate in a third downstream gas-liquid contacting device downstream of the carbon dioxide removal, cooling the liquid stream, and absorbing into the liquid at least a part of the ammonia of the gas stream such that the gas stream is depleted in ammonia and said liquid stream is enriched in ammonia; and

wherein in step f) a major portion of the liquid stream used in the second upstream gas-liquid contacting device is withdrawn and reused in the second downstream gas-liquid contacting device and a minor portion of the liquid stream used in the upstream second gas-liquid contacting device is reused in the first upstream gas-liquid contacting device, and a major portion of the liquid stream used in the second downstream gas-liquid contacting device is withdrawn and reused in the second upstream gas-liquid contacting device and a minor portion of the liquid stream used in the second downstream gas-liquid contacting device is reused in the first downstream gas-liquid contacting device.