Small scale microencapsulated pigments and uses thereof

• US 9,175,175 B2
• Filed: 10/16/2014
• Issued: 11/03/2015
• Est. Priority Date: 03/15/2013
• Status: Active Grant

• Current Assignee: ChromaticTechnologies lncoporated
• Original Assignee: ChromaticTechnologies lncoporated
• Inventors: Clayton, Terrill Scott, Owen, Timothy J., Small, Lyle
• Primary Examiner(s): Ahvazi, Bijan
• Application Number:
  US14/515,754
• Publication Number:
  US 20150076423A1
• Time in Patent Office: 383 Days
• Field of Search: 106/31.32, 106/31.33, 106/31.64, 106/31.65, 106/31.13, 252/583, 252/586, 427/401, 523/400
• US Class Current: 1/1
• CPC Class Codes: B01J 13/14 Polymerisation; cross-linking
• CPC Class Codes: B01J 13/18 In situ polymerisation with all reactants being present in the same phase
• CPC Class Codes: B41M 5/287 using microcapsules or microspheres only
• CPC Class Codes: C09B 67/0013 with polymeric coatings
• CPC Class Codes: C09B 67/0084 Dispersions of dyes
• CPC Class Codes: C09B 67/0097 Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09D 5/26 Thermosensitive paints

Abstract

A method is provided for making thermochromic pigments in microcapsules having unusually small particle sizes.

Claims

1. A method of making a dewatered slurry ready for industrial use, said method comprising:

producing a slurry including encapsulated thermochromic systems by combining;

an internal phase including a leuco dye and a developer for said leuco dye;

a resin; and

an aqueous phase including an anionic surfactant in an amount which constitutes greater than 2% of said slurry by weight;

wherein said amount of said anionic surfactant is effective to produce said encapsulated thermochromic systems which have a mean by volume particle size diameter of less than 1 micron; and

combining an amount of a chemical additive with said slurry;

wherein said amount of said chemical additive is effective to facilitate dewatering of said slurry with said anionic surfactant in place to provide said dewatered slurry comprising less than 60% water by weight.

2. The method of claim 1, wherein said effective amount of said anionic surfactant is in a range of 1% to 10% of said aqueous phase by weight.

3. The method of claim 1, wherein said anionic surfactant is selected from the group consisting of:

polystyrenesulfonate, styrene copolymers, polyvinylsulfonatester salts, polyvinylsulfonates, maleic anhydridestyrene copolymer, maleic anhydride-isobutylene copolymer, maleic anhydride-ethylene copolymer, maleic anhydride-methyl vinyl ether copolymer, polyvinyl alcohol (saponified product), carboxymethyl-modified polyvinyl alcohol, gum arabic, polyacrylates, polyacrylate derivatives, acrylate copolymers, carboxymethyl cellulose, gelatin, pectin, pullulan, phtahalated gelatin, succinated gelatin, cellulose sulfate ester salt, and alginic acid.

4. The method of claim 1, wherein said anionic surfactant comprises ethylene maleic anhydride.

5. The method of claim 1, wherein said resin comprises amine formaldehyde resin.

6. The method of claim 1, wherein said dewatered slurry comprises 20% to 40% water by weight.

7. The method of claim 1, further comprising combining said dewatered slurry with an ink vehicle to generate an ink.

8. The method of claim 1, further comprising combining said dewatered slurry with a coating vehicle to generate a coating.

9. The method of claim 8, wherein said coating comprises a metal decoration coating.

10. The method of claim 9, further comprising coating a beverage container with said metal decoration coating.

11. The method of claim 1, wherein said encapsulated thermochromic systems, upon activation, achieve a color selected from the group consisting of:

blue, green, yellow, and cyan.

12. The method of claim 1, wherein said dewatered slurry further comprises a photochromic dye.

13. The method of claim 1, wherein said aqueous phase is in a range of 40% to 70% of said slurry by weight.

14. The method of claim 1, wherein said internal phase is in a range of 23% to 35% of said slurry by weight.

15. The method of claim 1, wherein said leuco dye is in a range of 1% to 10% of said internal phase by weight.

16. The method of claim 1, wherein said resin is a resin solution in a range of 15% to 28% of said slurry by weight.

17. The method of claim 16, wherein said resin solution comprises amine formaldehyde resin in a range of 40% to 60% of said resin solution by weight.