Self-etching cementitious substrate coating composition

• US 9,175,187 B2
• Filed: 08/13/2009
• Issued: 11/03/2015
• Est. Priority Date: 08/15/2008
• Status: Active Grant

• Current Assignee: Swimc, LLC (The Sherwin-Williams Company)
• Original Assignee: Valspar Sourcing, Inc. (Sherwin-Williams Company)
• Inventors: Killilea, T. Howard, Wildman, Michael C., Johnson, Bruce A., Weber, Carl H.
• Primary Examiner(s): PAK, HANNAH J
• Application Number:
  US13/058,679
• Publication Number:
  US 20110151265A1
• Time in Patent Office: 2,273 Days
• Field of Search: 523/201
• US Class Current: 1/1
• CPC Class Codes: C08K 5/54 Silicon-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: C09D 143/04 Homopolymers or copolymers of monomers containing silicon
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

Coating compositions for cementitious substrates may be made from a multistage latex polymer; silane; and a water-soluble acid, acid anhydride or acid salt capable of etching or otherwise reacting with the surface of the substrate to provide improved coating adhesion. The silane may be present as a silane coupling agent distinct from the multistage latex polymer, or may be present as silane functionality on the multistage latex polymer. The coating compositions adhere well to cementitious substrates and have a self-etching capability which improves coating adhesion, especially near edges and corners.

Claims

1. A coating composition, comprising a multistage latex polymer;

silane; and

a water-soluble inorganic, or a water-soluble monomeric or oligomeric organic, acid, acid anhydride or acid salt capable of etching or otherwise reacting with the surface of a cementitious substrate;

with such acid, acid anhydride or salt being in an amount of about 1 to about 40 wt. % of the composition and providing improved coating adhesion to such substrate compared to a coating composition that does not contain such acid, acid anhydride or salt, and wherein the composition has a minimum film forming temperature of about 0 to about 55°

C. and contains less than 10 wt. % volatile organic compounds.

2. The composition of claim 1, wherein the multistage latex polymer comprises at least one soft stage having a Tg between about −

65 and 30°

C. and at least one hard stage having a Tg between about 30 and 230°

C.

3. The composition of claim 2, wherein the multistage latex polymer comprises 50 to 90 weight % soft stage polymer morphology having a Tg between about −

5 and 25°

C. and 10 to 50 weight % hard stage polymer morphology having a Tg between about 30 and 105°

C., based on total polymer weight.

4. The composition of claim 1, wherein the composition contains at least 10 weight % multistage latex polymer, based on total solids of the composition.

5. The composition of claim 1, wherein the multistage latex polymer has acetoacetoxy functionality.

6. The composition of claim 5, wherein the multistage latex polymer is made using from 0.5 to 10 weight % acetoacetoxy functional monomer based on the total weight of the multistage latex polymer.

7. The composition of claim 1, wherein the silane comprises an olefinic silane, allyl silane or mercapto silane.

8. The composition of claim 1, wherein the multistage latex polymer has silane functionality.

9. The composition of claim 8, wherein the silane functionality is derived from 3-acryloxypropyl trimethoxysilane, γ

-methacryloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane, s-(octanoyl)mercaptopropyltriethoxysilane, 3-thiocyanatopropyltriethoxysilane, 3-mercaptopropylmethyldimethoxysilane, bis[3-(triethoxysilyl)propyl]-tetrasulfide, bis[3-(triethoxysilyl)propyl]-disulfide triethoxysilane, vinyltriacetoxysilane, vinyl trimethoxysilane, vinyltriethoxysilane, vinyl-tris-(2-methoxyethoxy) silane, γ

-methacryloxypropyltrimethoxysilane, or vinyl methyldimethoxysilane.

10. The composition of claim 1, wherein the silane is not reacted with or reactive with the multistage latex polymer.

11. The composition of claim 10, wherein the silane is bis(triethoxysilyl)ethane, 1,2-bis(trimethoxysilyl)decane, (trimethoxysilyl)ethane, bis[(3-methyldimethoxysilyl)propyl]polypropylene oxide, carboxyethylsilanetriol sodium salt, bis(2-hydroxyethyl)-3-aminopropyltriethoxysilane, triethoxysilylmethanol, N-(triethoxysilylpropyl)-o-polyethylene oxide urethane, N-(3-triethoxysilylpropyl)gluconamide, diethylphosphatoethyltriethoxysilane, 3-trihydroxysilylpropylmethylphosphonate sodium salt, 3-(trihydroxysilyl)-1-propane sulfonic acid, triethoxysilyl modified poly-1,2-butadiene or aminoalkyl silsesquioxane oligomer.

12. The composition of claim 1, wherein the silane is epoxy-functional or amino-functional.

13. The composition of claim 1, wherein the silane has the formula:

R₁Si(R₂)_3-n(OR₃)_n

where n is 1, 2 or 3;

the R₁ group is alkyl, cycloalkyl, phenyl, cycloalkylalkyl, alkenylcycloalkyl, alkenylphenyl, or phenylalkyl, wherein R₁ contains at least one functional group and can optionally include a silane oligomer;

each R₂ group is independently hydrogen, alkyl, cycloalkyl, phenyl, cycloalkylalkyl, alkenylcycloalkyl, alkenylphenyl, phenylalkyl, or a silane oligomer, wherein each R₂ group can optionally include OR₃ groups or a functional group; and

each R₃ group is independently hydrogen, alkyl, cycloalkyl, phenyl, cycloalkylalkyl, alkenylcycloalkyl, alkenylphenyl, or phenylalkyl.

14. The composition of claim 1, wherein the silane is β

-(3,4 epoxycyclohexyl)-ethyltrimethoxysilane, γ

-glycidoxypropyltrimethoxysilane, γ

-glycidoxypropylmethyldiethoxysilane, γ

-glycidoxypropyltriethoxysilane, γ

-glycidoxypropylmethyldimethoxysilane, 5,6-epoxyhexyltriethoxysilane, or a hydrolyzate or mixture thereof.

15. The composition of claim 1, wherein the silane is trimethoxysilylpropyldiethylenetriamine, N-methylaminopropyltrimethoxysilane, aminoethylaminopropylmethyldimethoxysilane, aminoethylaminopropyltrimethoxysilane, aminopropylmethyldimethoxysilane, aminopropyltrimethoxysilane, polymeric aminoalkylsilicone, aminoethylaminoethylaminopropyl-trimethoxysilane, aminopropylmethyldiethoxysilane, aminopropyltriethoxysilane, 4-aminobutyltriethoxysilane, oligomeric aminoalkylsilane, m-aminophenyltrimethoxysilane, phenylaminopropyltrimethoxysilane, 1,1,2,4-tetramethyl-1-sila-2-azacyclopentane, aminoethylaminopropyltriethoxysilane, aminoethylaminoisobutylmethyldimethoxysilane, benzylethylenediaminepropyltrimethoxysilane, or a hydrolyzate or mixture thereof.

16. The composition of claim 1, wherein the silane is a silane coupling agent.

17. The composition of claim 1, wherein the silane has an average molecular weight of from about 140 to about 500 g/mole.

18. The composition of claim 1, wherein the silane is at least about 0.2% and less than about 10% of the latex polymer weight.

19. The composition of claim 1, wherein the water-soluble acid or salt has a water solubility of at least 5 wt. %.

20. The composition of claim 1, wherein the water-soluble acid or salt is completely water miscible.

21. The composition of claim 1, wherein the acid, acid anhydride or salt is inorganic.

22. The composition of claim 1, wherein the acid, acid anhydride or salt is an organic monomer or oligomer.

23. The composition of claim 1, wherein the water-soluble acid or salt is a carboxylic, sulfonic, phosphorus, nitric, nitrous, hydrogen halide or mineral acid or salt thereof.

24. The composition of claim 1, comprising a sodium, potassium or ammonium salt of the water-soluble acid.

25. The composition of claim 1, comprising a magnesium, calcium or iron salt of the water-soluble acid.

26. The composition of claim 1, comprising a mixture of water-soluble acid, acid anhydride or salt which buffers the coating composition pH.

27. The composition of claim 1, wherein the composition contains about 7 to about 20 wt. % acid, acid anhydride or salt.

28. The composition of claim 1, wherein the composition has a pH of about 5 to about 9.

29. The composition of claim 1, wherein the composition is alkaline.

32. The composition of claim 1, wherein the composition contains less than 4 wt. % volatile organic compounds.

33. The composition of claim 1, wherein the composition has a minimum film forming temperature of about 0 to about 20°

C.

34. The composition of claim 1, wherein the composition contains about 5 to about 30 wt. % acid, anhydride or salt.

30. A method for preparing a coated article, which method comprises (i) providing a cementitious substrate;

(ii) applying to a surface portion of the substrate an aqueous coating composition comprising a multistage latex polymer;

silane; and

a water-soluble inorganic, or a water-soluble monomeric or oligomeric organic, acid, acid anhydride or acid salt capable of etching or otherwise reacting with the surface of such substrate, with such acid, acid anhydride or salt being in an amount of about 1 to about 40 wt. % of the composition and providing improved coating adhesion to such substrate compared to a coating composition that does not contain such acid, acid anhydride or salt, and wherein the composition has a minimum film forming temperature of about 0 to about 55°

C. and contains less than 10 wt. % volatile organic compounds; and

(iii) allowing the coating composition to harden.

31. A coated article comprising a cementitious substrate having at least one major surface on which is coated a layer comprising an aqueous coating composition comprising a multistage latex polymer;

silane; and

a water-soluble inorganic, or a water-soluble monomeric or oligomeric organic, acid, acid anhydride or acid salt capable of etching or otherwise reacting with the surface of such substrate;

with such acid, acid anhydride or salt being in an amount of about 1 to about 40 wt. % of the composition and providing improved coating adhesion to such substrate compared to a coating composition that does not contain such acid, acid anhydride or salt, and wherein the composition has a minimum film forming temperature of about 0 to about 55°

C. and contains less than 10 wt. % volatile organic compounds.