Apparatus and process for treatment of water

• US 9,180,411 B2
• Filed: 09/21/2012
• Issued: 11/10/2015
• Est. Priority Date: 09/22/2011
• Status: Active Grant

• Current Assignee: Chevron USA Incorporated (Chevron Corp.)
• Original Assignee: Chevron USA Incorporated (Chevron Corp.)
• Inventors: Prakash, Prakhar, Pauley, James Craig, Pruet, Randall B.
• Primary Examiner(s): Zalasky, Katherine
• Application Number:
  US13/624,853
• Publication Number:
  US 20130075332A1
• Time in Patent Office: 1,145 Days
• Field of Search: 210/640, 210/702, 210/703, 210/738, 210/650, 210/651, 210/652
• US Class Current: 1/1
• CPC Class Codes: B01D 61/002 Forward osmosis or direct osmosis
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B01D 61/364 Membrane distillation
• CPC Class Codes: B01D 61/58 Multistep processes
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 71/024 Oxides
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 1/445 by forward osmosis
• CPC Class Codes: C02F 1/447 by membrane distillation distillation and evaporation without the use of membranes C02F1/04
• CPC Class Codes: C02F 1/463 by electrocoagulation
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2209/10 Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
• CPC Class Codes: C02F 2209/20 Total organic carbon [TOC]
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage
• CPC Class Codes: Y10T 29/494 Fluidic or fluid actuated device making

Abstract

The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation or forward osmosis (FO), may be combined with a subsequent process of ceramic ultra-filtration (UF filtration) employed to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.

Claims

1. A method for treating produced water for steam generation, the method comprising:

providing a source of produced water to be treated, the water having contaminants selected from the group of total organic content (TOC) and total dissolved solids (TDS) as silica and hardness ions;

removing at least a portion of the silica and hardness ions as suspended solids by subjecting the produced water to an electrocoagulation process;

removing at least a substantial portion of the suspended solids in a polymer filtration unit, the filtration unit operating at a temperature of at least about 50 degrees Centigrade;

lowering the water temperature of the produced water while the produced water is in the filtration unit;

further treating the produced water within the filtration unit, further wherein the filtration unit comprises at least one membrane selected from the following;

polyethersulfone (PES) membrane, polyacrylonitrile (PAN) membrane, polvvinylidene difluoride (PVDF) membrane, sulfonated polyether ether ketone (PEEK) membrane, Nafion membranes (sulfonated tetrafluoroethylene based fluoropolymer-copolymer), poly(phthalazinone ether sulfone) membrane (PPES), poly(phthalazinone ether ketone) membrane (PPEK), poly(phthalazinone ether fulfone ketone) membrane (PPESK);

generating a pre-treated water;

treating the pre-treated water in a direct contact membrane distillation (DCMD) unit, wherein the DCMD unit employs a composite membrane comprising a hydrophilic polymer layer and a hydrophobic polymer layer.

2. The method of claim 1, wherein no heat energy is added to or removed from the pre-treated water prior to treating the pre-treated water in the DCMD unit.

3. The method of claim 1, wherein the electrocoagulation process employs sacrificial electrodes.

4. The method of claim 1, wherein the pH of the produced water is adjusted to a pre-select pH prior to removing at least a portion of the silica and hardness ions by the electrocoagulation process.

5. The method of claim 4, wherein the pre-select pH ranges from 7.2 to 11.5.

6. The method of claim 1, wherein the polymer filtration unit removes at least 70% of the total organic content from the produced water prior to treatment in a DCMD unit.

7. The method of claim 1, wherein the filtration unit operates at water temperature of at least 80°

C.

8. The method of claim 1, wherein the DCMD unit hydrophobic polymer layer comprises hydrophobic hollow fiber.

9. The method of claim 8, wherein the hydrophobic hollow fiber comprises individual fibers having a length ranging from 1 to 200″

and a wall thickness ranging from 2 to 100 μ

m.

10. The method of claim 1, wherein the hydrophilic polymer layer comprises any of polysulfone, polyether sulfone, polyetherimide polyvinylidenefluoride, and cellulose acetate.

11. The method of claim 1, wherein the hydrophobic polymer layer comprises fluorinated surface-modifying macromolecule (SMM).