Encapsulated white OLEDs having enhanced optical output

• US 9,184,410 B2
• Filed: 12/22/2008
• Issued: 11/10/2015
• Est. Priority Date: 12/22/2008
• Status: Active Grant

• Current Assignee: Samsung Display Company Limited (Samsung Electronics Co. Ltd.)
• Original Assignee: Samsung Display Company Limited (Samsung Electronics Co. Ltd.)
• Inventors: Visser, Robert Jan, Moro, Lorenza
• Primary Examiner(s): Bowman, Mary Ellen
• Application Number:
  US12/341,251
• Publication Number:
  US 20100159792A1
• Time in Patent Office: 2,514 Days
• Field of Search: 313498-512, 445/24, 445/25
• US Class Current: 1/1
• CPC Class Codes: H10K 2102/00 Constructional details relating to the organic devices covered by this subclass
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/00 Organic light-emitting devices integrated devices or assemblies of multiple devices H10K59/00, H10K65/00; organic semiconductor lasers H01S5/36
• CPC Class Codes: H10K 50/81 Anodes
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 50/84 Passivation; Containers; Encapsulations
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 50/85 Arrangements for extracting light from the devices
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses

Abstract

Methods of making an integrated barrier stack and optical enhancement layer for protecting and improving the light out coupling of encapsulated white OLEDs are described. The method includes optimizing the thickness of various layers including one or more of the plasma protective layer, the initial organic layer, the initial inorganic barrier layer, and the inorganic barrier layer and polymeric decoupling layer for the barrier stack. The thickness is optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated OLED has enhanced light outcoupling compared to the bare OLED.

Claims

1. A method of making an integrated barrier and optical enhancement stack for protecting and improving the light out coupling of encapsulated white OLEDs comprising;

providing a co-doped white OLED having a transparent electrode;

selecting a plasma protective layer having a refractive index in a range of about 1.1 to about 1.9, the plasma protective layer adjacent to the transparent electrode of the white OLED;

optimizing a thickness of the plasma protective layer for the white OLED within a range of about 20 nm to about 50 nm;

selecting an initial inorganic barrier layer having a refractive index in a range of about 1.55 to about 2, the initial inorganic barrier layer adjacent to the transparent electrode in the white OLED;

optimizing a thickness of the initial inorganic barrier layer for the white OLED within a range of about 40 nm to about 240 nm;

selecting a barrier stack comprising at least a pair of inorganic barrier layers and a polymeric decoupling layer between the inorganic barrier layers, the inorganic barrier layer having a refractive index in a range of about 1.55 to about 2, and the polymeric decoupling layer having a refractive index in a range of about 1.4 to about 1.65, the barrier stack adjacent to the initial inorganic barrier layer;

optimizing a thickness of the inorganic barrier layer within a range of about 20 nm to about 80 nm and the polymeric decoupling layer of the barrier stack within in a range of about 0.2 μ

m to about 4 μ

m, wherein the thickness of at least one of the plasma protective layer, initial inorganic barrier layer, the inorganic barrier layer, or the polymeric decoupling layer are optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to a bare white OLED;

depositing the plasma protective layer having the optimized thickness adjacent to the transparent electrode of the white OLED;

depositing the initial inorganic barrier layer having the optimized thickness adjacent to the plasma protective layer; and

depositing the barrier stack having the optimized thickness for the inorganic barrier layer and the polymeric decoupling layer adjacent to the initial inorganic barrier layer, wherein the initial inorganic barrier layer is different from the inorganic barrier layer of the barrier stack and further wherein the improving the light out coupling of the encapsulated OLED is achieved without either (a) a scattering layer placed adjacent the OLED, initial inorganic barrier layer or barrier stack or (b) a quarter-wave stack placed adjacent the OLED, initial inorganic barrier layer or barrier stack.

2. The method of claim 1 wherein the plasma protective layer is an inorganic layer.

3. The method of claim 1 wherein the transparent electrode is a transparent cathode.

4. The method of claim 3 wherein providing the co-doped white OLED includes:

selecting a transparent cathode layer material, the transparent cathode layer material having a refractive index in a range of about 1.6 to about 2; and

optimizing a thickness of the transparent cathode layer within a range of about 20 to about 300 nm, and wherein thickness of the cathode layer is optimized for at least one of total efficiency, or intentional color point shift.

5. The method of claim 1 wherein the total efficiency is increased by at least about 20%.

6. The method of claim 1 wherein the total efficiency is increased by at least about 40%.

7. The method of claim 1 wherein the total efficiency is increased by at least about 50%.

8. The method of claim 1 wherein the transparent electrode in the OLED is a transparent anode.

17. The product made by the method of claim 1.

18. The product made by the method of claim 4.

9. A method of making an integrated barrier and optical enhancement stack for protecting and improving the light out coupling of encapsulated white OLEDs comprising;

providing a vertically stacked white OLED having a transparent electrode;

selecting an initial organic layer having a refractive index in a range of about 1.4 to about 1.65, the initial organic layer adjacent to the transparent electrode of the white electrode;

optimizing a thickness of the initial organic layer for the white OLED within range of about 0.2 μ

m to about 1 μ

m;

selecting an initial inorganic barrier layer having a refractive index in a range of about 1.55 to about 2, the initial inorganic barrier layer adjacent to a transparent electrode in the white OLED;

optimizing a thickness of the initial inorganic barrier layer for the white OLED within a range of about 40 nm to about 240 nm;

selecting a barrier stack comprising at least a pair of inorganic barrier layers and a polymeric decoupling layer between the inorganic barrier layers, the inorganic barrier layer having a refractive index in a range of about 1.55 to about 2, and the polymeric decoupling layer having a refractive index in a range of about 1.4 to about 1.65, the barrier stack adjacent to the initial inorganic barrier layer;

optimizing a thickness of the inorganic barrier layer within a range of about 20 nm to about 80 nm and the polymeric decoupling layer of the barrier stack within a range of about 0.2 μ

m to about 4 μ

m, wherein the thickness of at least one of the initial organic layer, initial inorganic barrier layer, the inorganic barrier layer, or the polymeric decoupling layer are optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to a bare white OLED;

depositing the initial organic layer having the optimized thickness adjacent to the transparent electrode of the white OLED;

depositing the initial inorganic barrier layer having the optimized thickness adjacent to the initial organic layer; and

depositing the barrier stack having the optimized thickness for the inorganic barrier layer and the polymeric decoupling layer adjacent to the initial inorganic barrier layer, wherein the initial inorganic barrier layer is different from the inorganic barrier layer of the barrier stack and further wherein the improving the light out coupling of the encapsulated OLED is achieved without either (a) a scattering layer placed adjacent the OLED, initial inorganic barrier layer or barrier stack or (b) a quarter-wave stack placed adjacent the OLED, initial inorganic barrier layer or barrier stack.

10. The method of claim 9 further comprising:

selecting a plasma protective layer having a refractive index in a range of about 1.1 to about 1.9;

optimizing a thickness of the inorganic plasma protective layer for the white OLED within a range of about 20 nm to about 50 nm, wherein the thickness of the plasma protective layer is optimized for at least one of total efficiency, or intentional color point shift so that the encapsulated white OLED has enhanced light outcoupling compared to the bare white OLED; and

depositing the plasma protective layer having the optimized thickness adjacent to the transparent electrode of the white OLED before the initial organic layer is deposited.

11. The method of claim 10 wherein the plasma protective layer is an inorganic layer.

12. The method of claim 9 wherein the transparent electrode is a transparent cathode.

13. The method of claim 9 wherein the total efficiency is increased by at least about 20%.

14. The method of claim 9 wherein the total efficiency is increased by at least about 40%.

15. The method of claim 9 wherein the total efficiency is increased by at least about 50%.

16. The method of claim 9 wherein the transparent electrode in the OLED is a transparent anode.

19. The product made by the method of claim 9.

20. The product made by the method of claim 10.