Apparatuses and methods for removing acid gas from sour gas

• US 9,192,888 B2
• Filed: 06/26/2013
• Issued: 11/24/2015
• Est. Priority Date: 06/26/2013
• Status: Expired due to Fees

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Pandya, Keyur Y., Wegerer, David A., Sadler, Clayton Colin
• Primary Examiner(s): Smith, Duane
• Assistant Examiner(s): HOLECEK, CABRENA L
• Application Number:
  US13/928,244
• Publication Number:
  US 20150000525A1
• Time in Patent Office: 881 Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2252/103 Water
• CPC Class Codes: B01D 2252/2021 Methanol
• CPC Class Codes: B01D 2252/2026 Polyethylene glycol, ethers or esters thereof, e.g. Selexol
• CPC Class Codes: B01D 2252/20468 containing a pyrrolidone-ring
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32

Abstract

Embodiments of apparatuses and methods for removing acid gas from sour gas are provided. In one example, an apparatus comprises an absorption zone. The absorption zone is configured for contacting the sour gas with an absorbent solvent that is at a first predetermined temperature of less than about 0° C. to remove the acid gas and form a treated gas stream that includes entrained absorbent solvent. A heat exchanger or heater is configured to heat the treated gas stream to a second predetermined temperature of greater than about 0° C. to form a partially heated treated gas stream. A water wash zone is configured for contacting the partially heated treated gas stream with water to remove the entrained absorbent solvent and form a solvent-depleted treated gas stream.

Claims

1. A method for removing acid gas from sour gas, the method comprising the steps of:

separating the acid gas from the sour gas with an absorbent solvent in an absorption zone to form a treated gas stream that includes entrained absorbent solvent and that is at a first predetermined temperature of less than about 0°

C.;

heating the treated gas stream to a second predetermined temperature of greater than about 0°

C. to form a partially heated treated gas stream;

introducing the partially heated treated gas stream to a water wash zone to remove the entrained absorbent solvent with water and form a solvent-depleted treated gas stream;

cooling a sour gas stream to a third predetermined temperature using the solvent-depleted treated gas stream, the treated gas stream, a cooler, or a combination thereof to form a cooled sour gas stream; and

introducing the cooled sour gas stream to the absorption zone;

wherein the step of cooling comprises indirect heat exchanging from the sour gas stream to the treated gas stream in a first heat exchanger to form the cooled sour gas stream and the partially heated treated gas stream and wherein the step of cooling comprises indirect heat exchanging from the sour gas stream to the solvent-depleted treated gas stream in a second heat exchanger upstream from the first heat exchanger to form a partially cooled sour gas stream and a heated solvent-depleted treated gas stream, and wherein the step of indirect heat exchanging from the sour gas stream to the treated gas stream comprises indirect heat exchanging from the partially cooled sour gas stream to the treated gas stream to form the cooled sour gas stream.

2. A method for removing acid gas from sour gas, the method comprising the steps of:

separating the acid gas from the sour gas with an absorbent solvent in an absorption zone to form a treated gas stream, wherein said treated gas stream includes entrained absorbent solvent and is at a first predetermined temperature of less than about 0°

C.;

heating the treated gas stream to a second predetermined temperature of greater than about 0°

C. to form a partially heated treated gas stream;

introducing the partially heated treated gas stream to a water wash zone to remove the entrained absorbent solvent with water and form a solvent-depleted treated gas stream;

cooling a sour gas stream to a third predetermined temperature using the solvent-depleted treated gas stream, the treated gas stream, a cooler, or a combination thereof to form a cooled sour gas stream; and

introducing the cooled sour gas stream to the absorption zone, wherein the step of introducing the cooled sour gas stream comprises introducing the cooled sour gas stream to a first absorber, wherein the first absorber is configured to contact the cooled sour gas stream with a partially loaded absorbent solvent stream at a fourth predetermined temperature of less than about 0°

C. to remove the acid gas including H₂S to form a H₂S-depleted sour gas stream and a spent absorbent solvent stream;

wherein the step of introducing the cooled sour gas stream further comprises introducing the H₂S-depleted sour gas stream to a second absorber downstream from the first absorber and that is configured to contact the H₂S-depleted sour gas stream with a lean absorbent solvent stream that is at a fifth predetermined temperature of less than about 0°

C. to remove the acid gas including CO₂ to form the treated gas stream and the partially loaded absorbent solvent stream.

3. The method of claim 2, wherein the step of introducing the H₂S-depleted sour gas stream comprises contacting the H₂S-depleted sour gas stream with the lean absorbent solvent stream that is at the fifth predetermined temperature of from about −

15 to about −

0.1°

C.