Flexible strained sensor with protective coating

• US 9,212,895 B2
• Filed: 11/09/2012
• Issued: 12/15/2015
• Est. Priority Date: 11/14/2011
• Status: Active Grant

• Current Assignee: National University Corporation Shizuoka University, Yamaha Corporation
• Original Assignee: National University Corporation Shizuoka University, Yamaha Corporation
• Inventors: Suzuki, Katsunori, Sakakibara, Shingo, Yataka, Koji, Okumiya, Yasuro, Terada, Yoshiki, Inoue, Yoku
• Primary Examiner(s): Caputo, Lisa
• Assistant Examiner(s): Cotey, Philip
• Application Number:
  US13/673,186
• Publication Number:
  US 20130118267A1
• Time in Patent Office: 1,131 Days
• Field of Search: 737/74, 737/63, 737/67, 977/742
• US Class Current: 1/1
• CPC Class Codes: G01B 7/18 using change in resistance

Abstract

A strain sensor includes a flexible substrate, a CNT film made of a plurality of CNT fibers aligned in an orientation direction, a pair of electrodes, and a protective coat. The electrodes are formed at the opposite ends of the CNT film in a perpendicular direction to the orientation direction of the CNT fibers. The protective coat protecting the CNT film is made of a resin, a water-based emulsion, or an oil-based emulsion. The protective coat is placed in contact with at least part of the CTN fibers on the surface of the CNT film. The strain sensor including the protective coat is able to prevent damage/breakage of the CNT film and to prevent foreign matters from entering into gaps between CNT fibers, thus improving durability in maintaining adequate sensing functionality.

Claims

1. A strain sensor comprising:

a substrate which is flexible along a first axis;

a CNT film which is made of a plurality of CNT fibers aligned in an orientation direction which is transverse to the first axis and which are formed on a surface of the substrate, the CNT film, and with it the contact between the CNT fibers, being expanded or compressed along the first axis as the substrate is expanded or compressed along the first axis;

a pair of electrodes which are formed at opposite ends of the CNT film along the first axis; and

a protective coat, made of a water based emulsion containing resin, protecting the CNT film, wherein the protective coat is placed in contact with at least part of the CNT fibers on the surface of the CNT film but is not impregnated in the CNT film, and

wherein the plurality of CNT fibers includes a first group of CNT fibers and a second group of CNT fibers, and the second group of CNT fibers is arranged over the first group of CNT fibers, such that the plurality of CNT fibers forms a two-sided beam structure, the first group of CNT fibers being located at one side of the beam structure, the second group of CNT fibers being located at another side of the beam structure, and the sides of the beam structure being opposed to each other in a direction that is perpendicular to the first axis.

2. The strain sensor according to claim 1, wherein the protective coat is laminated on the surface of the CNT film.

3. The strain sensor according to claim 1, wherein the protective coat includes a plurality of conductive additives.

4. The strain sensor according to claim 1, wherein the CNT film includes at least one cleavable part which is cleavable in the orientation direction of the CNT fibers.

5. The strain sensor according to claim 1, wherein each of the CNT fibers is made of a plurality of CNT monofilaments which are elongated in a longitudinal direction and which are partially connected together via at least one coupler.

6. The strain sensor according to claim 5, wherein the plurality of monofilaments is mutually connected together in a network structure.

7. The strain sensor according to claim 1, wherein the protective coat is formed by applying hydrophilic latex to the surface of the CNT film.

8. The strain sensor according to claim 1, wherein the protective coat includes a plurality of resin particles insoluble in a hydrophobic organic solvent.

9. The strain sensor according to claim 1, wherein the protective coat is made of oil-based emulsion including a hydrophobic organic solvent as a dispersion medium and a plurality of resin particles as dispersoids.

10. The strain sensor according to claim 9, wherein the oil-based emulsion has solid concentration of particles ranging from 5 weight-percent to 10 weight-percent.

11. The strain sensor according to claim 1 wherein the axis is perpendicular to the orientation direction of the CNT fibers.

12. The strain sensor according to claim 1, wherein the protective coat with a thickness ranging from 10 μ

m to 3 mm is formed on the CNT file with a thickness ranging from 10 μ

m to 1 mm.