Consolidating agent emulsions and associated methods

• US 9,222,014 B2
• Filed: 04/27/2012
• Issued: 12/29/2015
• Est. Priority Date: 02/10/2006
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Rickman, Richard D., Dusterhoft, Ronald G., Nguyen, Philip D., Welton, Thomas D., Weaver, Jimmie D., Sanders, Mike W., Fitzpatrick, Harvey J.
• Primary Examiner(s): DiTrani, Angela M
• Application Number:
  US13/457,715
• Publication Number:
  US 20120205107A1
• Time in Patent Office: 1,341 Days
• Field of Search: None
• US Class Current: 1/1
• CPC Class Codes: C09K 8/68 containing organic compounds
• CPC Class Codes: C09K 8/80 Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
• CPC Class Codes: C09K 8/805 Coated proppants

Abstract

Method of treating a subterranean formation comprising providing a consolidation fluid, introducing the resin consolidation fluid into a subterranean formation comprising unconsolidated particulates; and, curing the resin to at least partially consolidate the unconsolidated particulates. The consolidation fluid comprises a resin in emulsified form with an aqueous external phase and an organic internal phase wherein the emulsified resin does not comprise a hardening agent and an aqueous base fluid that further comprises a hardening agent. The consolidation fluid may further comprise an emulsifying agent.

Claims

1. A method of treating a subterranean formation comprising:

providing a foamed consolidation fluid comprising;

a resin in emulsified form comprising an aqueous external phase, and an organic internal phase, and wherein the emulsified resin does not comprise a hardening agent;

a hardening agent component; and

,

an emulsifying agent comprising a mixture of an amphoteric surfactant present in an amount from about 30% to about 45% by weight of the surfactant mixture and an anionic surfactant in an amount from about 55% to about 70% by weight of the surfactant mixture;

introducing the consolidation fluid into a subterranean formation comprising unconsolidated particulates; and

,

curing the resin to at least partially consolidate the unconsolidated particulates.

2. The method of claim 1 further comprising introducing a preflush fluid into the subterranean formation prior to the introduction of the consolidation fluid.

3. The method of claim 2 wherein the preflush fluid comprises aqueous fluids, solvents, surfactants, or combinations thereof.

4. The method of claim 2 wherein the hardening agent component further comprises a silane coupling agent selected from the group consisting of N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, 3-glycidoxypropyltrimethoxysilane, and mixtures thereof.

5. The method of claim 1 further comprising introducing a postflush fluid into the subterranean formation after the introduction of the consolidation fluid.

6. The method of claim 5 wherein the postflush fluid comprises aqueous fluids, solvents, gases, or combinations thereof.

7. The method of claim 1 wherein the emulsified resin is selected from the group consisting of epoxy-based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins, polyester resins, urethane resins, and mixtures thereof.

8. The method of claim 1 wherein the hardening agent component further comprises a surfactant selected from the group consisting of an alkyl phosphonate surfactant, an ethoxylated nonyl phenol phosphonate ester, a cationic surfactant, a nonionic surfactant, and mixtures thereof.

9. The method of claim 1 wherein the emulsifying agent further comprises materials selected from the group consisting of proteins, hydrolyzed proteins, lipids, glycolipids, nano-sized particulates, and fumed silica.

10. A method of claim 1 wherein the hardening agent component further comprises a diluent or liquid carrier fluid.

11. A method of treating a subterranean formation, the method comprising:

providing a consolidation fluid comprising;

a resin in emulsified form comprising an aqueous external phase, and an organic internal phase, and wherein the emulsified resin does not comprise a hardening agent;

a hardening agent component; and

,

an emulsifying agent comprising a mixture of an amphoteric surfactant present in an amount from about 30% to about 45% by weight of the surfactant mixture and an anionic surfactant in an amount from about 55% to about 70% by weight of the surfactant mixture;

introducing a preflush fluid into a subterranean formation comprising unconsolidated particulates;

introducing the consolidation fluid into the subterranean formation comprising unconsolidated particulates;

introducing a postflush fluid into a subterranean formation comprising unconsolidated particulates; and

,

curing the resin to at least partially consolidate the unconsolidated particulates.

12. The method of claim 11 wherein the emulsified resin is selected from the group consisting of epoxy-based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins, polyester resins, urethane resins, and mixtures thereof.

13. The method of claim 11 wherein the hardening agent component further comprises a silane coupling agent selected from the group consisting of N-2-(aminoethyl)-3-aminopropyl trimethoxysilane, 3-glycidoxypropyltrimethoxysilane, and mixtures thereof.

14. The method of claim 11 wherein the hardening agent component further comprises a surfactant selected from the group consisting of alkyl phosphonate surfactants, ethoxylated nonyl phenol phosphonate esters, cationic surfactants, nonionic surfactants, and mixtures of one or more cationic and nonionic surfactants.

15. The method of claim 11 wherein the consolidation fluid is foamed.

16. The method of claim 11 wherein the emulsifying agent further comprises materials selected from the group consisting of proteins, hydrolyzed proteins, lipids, glycolipids, nano-sized particulates, and fumed silica.

17. The method of claim 11 wherein the emulsified resin is present in the consolidation fluid in an amount from about 1% w/v to about 10% w/v.

18. A method of claim 11 wherein the hardening agent component further comprises a diluent or liquid carrier fluid.