Electrolyzer

• US 9,222,178 B2
• Filed: 03/24/2015
• Issued: 12/29/2015
• Est. Priority Date: 01/22/2013
• Status: Active Grant

• Current Assignee: GTA, Inc.
• Original Assignee: GTA, Inc.
• Inventors: Greenbaum, Elias Stanley
• Primary Examiner(s): Smith, Nicholas A
• Application Number:
  US14/667,453
• Publication Number:
  US 20150197864A1
• Time in Patent Office: 280 Days
• US Class Current: 1/1
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 11/02 characterised by shape or form
• CPC Class Codes: C25B 13/00 Diaphragms; Spacing elements
• CPC Class Codes: C25B 13/02 characterised by shape or form
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
• CPC Class Codes: C25B 9/05 Pressure cells
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: C25B 9/65 Means for supplying current; Electrode connections; Electric inter-cell connections
• CPC Class Codes: C25B 9/73 of the filter-press type
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

The electrolytic production of high purity hydrogen and oxygen may include regulating gas pressure in the cathode and anode compartments of the electrolysis apparatus. The supply of water to the apparatus may be through at least one opening on the surface of the apparatus. High pressure hydrogen and oxygen gas may be produced without subjecting the electrolysis apparatus to large pressure differences between the interior and exterior of the apparatus. This may be accomplished by substantially immersing the entire electrolysis apparatus in a high pressure fluid thus making the interior and exterior pressures of the apparatus substantially equal. Two example structures for accomplishing this goal are disclosed. First, the apparatus may be placed in and encapsulated by a fluid-containing vessel that is itself pressurized. Second, the apparatus may be immersed in a deep water environment. Part of the electrical energy used to perform electrolysis may be recovered by capturing the kinetic energy and momentum in high pressure gas flowing in a tube, oxygen for example, and converting it to electricity by causing it to rotate an impeller that is coupled to an electric generator.

Claims

1. An electrolysis apparatus for splitting water into hydrogen and oxygen gases using electrolysis, the apparatus comprising:

a first hemi-enclosure having a facing edge;

a second hemi-enclosure having a facing edge that is separable from and not integral with the first hemi-enclosure;

a diaphragm that passes ions and impedes the passage of gas comprising a first side and a second opposing side, the diaphragm positioned between the facing edges of the first hemi-enclosure and the second hemi-enclosure, whereby the first hemi-enclosure and one side of the diaphragm form a first compartment and the second hemi-enclosure and the other side of the diaphragm form a second compartment;

one or more electrodes in the first compartment that emerge from the apparatus in a first interface defined by abutting edges of the first hemi-enclosure and the first side of the diaphragm to form one or more electrical contacts;

one or more electrodes in the second compartment that emerge from the apparatus in a second interface defined by abutting edges of the second hemi-enclosure and the second side of the diaphragm to form one or more electrical contacts;

a first pipe that allows gas within the first compartment to escape;

a second pipe that allows gas within the second compartment to escape;

a fastener that fastens the first hemi-enclosure, the diaphragm, the one or more electrodes, and the second hemi-enclosure together; and

electrical contacts that receive energy from an external source and deliver it to the electrodes.

2. The apparatus of claim 1 wherein the electrodes are wire electrodes.

3. The apparatus of claim 1 further comprising a headspace barrier that abuts an edge of the diaphragm and is impermeable to ions, gases and water.

4. The apparatus of claim 1 wherein the diaphragm has a perimeter edge and at least a portion of this perimeter edge is fastened to a strip that is impermeable to gas, water and ions.

5. The apparatus of claim 1 wherein the apparatus causes pressure of gas in the first compartment and pressure of the gas in the second compartment to be substantially equal.

6. The apparatus of claim 5 further comprising at least one back pressure regulator connected to the first compartment and at least one back pressure regulator connected to the second compartment, both back pressure regulators being set to cause the back pressures of gases in the first and the second compartments to be substantially equal.

7. The apparatus of claim 5 further comprising:

a first variable orifice valve connected to the first compartment;

a second variable orifice valve connected to the second compartment; and

a differential pressure gauge that detects a difference between the pressure of gas in the first compartment and the pressure of gas in the second compartment and controls the first and the second variable orifices so as to substantially equalize the pressures of gases in the first and the second compartments.

8. The apparatus of claim 5 further comprising a back pressure regulator that receives gas pressure data from the first compartment and uses the data to maintain the gas pressure in the second compartment equal to the gas pressure in the first compartment.

9. The apparatus of claim 1, further comprising at least one location on a surface of the apparatus through which external ions in fluid surrounding the apparatus can pass from the exterior of the apparatus into the first and second compartments.

10. The apparatus of claim 9 wherein the at least one location is between the first hemi-enclosure and the second hemi-enclosure.

11. The apparatus of claim 10 wherein the at least one location is on the diaphragm.

12. The apparatus of claim 9 further comprising a one-way valve at the at least one location.

13. The apparatus of claim 9 further comprising:

an electrical conductor passing from the outside to the inside of the first fluid-tight compartment in a leak tight manner and in electrical contact with the one or more electrodes in the first compartment; and

an electrical conductor passing from the outside to the inside of the second fluid-tight compartment in a leak tight manner and in electrical contact with the one or more electrodes in the second compartment.

14. The apparatus of claim 9 further comprising a fluid containing vessel that substantially surrounds the fastened together first hemi-enclosure, diaphragm, electrodes, and second hemi-enclosure.

15. The apparatus of claim 14 further comprising a pressure-transmitting tube passing between the outside and inside of the fluid containing vessel.

16. The apparatus of claim 14 wherein the electrodes that emerge from the electrolysis apparatus also emerge from the vessel and wherein the apparatus further comprises:

a first electrode compartment oxygen gas removal pipe that channels oxygen gas formed within the first electrode compartment outside of the vessel and that prevents the oxygen from entering the area of the vessel that surrounds the hemi-enclosures; and

a second electrode compartment hydrogen gas removal pipe that channels hydrogen gas formed within the second compartment outside of the vessel,

wherein the apparatus prevents;

liquid from escaping the first or the second electrode compartments, and

mixing of the oxygen gas and the hydrogen gas.

17. An apparatus for the production of hydrogen and oxygen from water, the apparatus comprising:

an electrolysis apparatus comprising;

at least one first electrode inside of a first electrode compartment;

at least one second electrode inside of a second electrode compartment;

a diaphragm that passes ions and impedes the passage of gas positioned between the at least one first electrode and the at least one second electrode and that forms a common barrier of the first and second electrode compartments;

a leak tight vessel completely surrounding the electrolysis apparatus that is capable of holding fluid in an interior region that completely surrounds the first electrode compartment and the second electrode compartment in a leak tight manner;

one or more fluid communication channels between an interior region of the vessel and the insides of the first and second electrode compartments;

a first electrode compartment oxygen gas removal pipe that channels oxygen gas formed within the first electrode compartment outside of the vessel and prevents the oxygen gas from entering the area of the vessel that surrounds the electrolysis apparatus; and

a second electrode compartment hydrogen gas removal pipe that channels hydrogen gas formed within the second compartment outside of the vessel,

wherein the apparatus prevents;

liquid from escaping the first or the second electrode compartments, and mixing of the oxygen gas and the hydrogen gas;

a first electrical conductor that conducts electricity from outside of the vessel to the at least one first electrode;

a second electrical conductor that conducts electricity from outside of the vessel to the at least one second electrode.

18. The apparatus of claim 17 further comprising at least one back pressure regulator that causes the pressures in the first and second compartments to be equal.

19. The apparatus of claim 17 wherein the first and the second gas removal pipes run from within the electrolysis apparatus into the vessel.

20. The apparatus of claim 17 wherein the first and second gas removal pipes extend outside of the vessel.

21. The apparatus of claim 17, wherein:

the at least one first electrode includes multiple first electrodes;

the at least one second electrode includes multiple second electrodes;

the multiple first electrodes emerge from the electrolysis apparatus and penetrate the vessel to form multiple first electrode contacts external to the vessel; and

the multiple second electrodes emerge from the electrolysis apparatus and penetrate the vessel to form multiple second electrode contacts external to the vessel.

22. The apparatus of claim 17 wherein that apparatus has a configuration that causes gas in the first and second gas removal pipes to be substantially free of liquid.

23. The apparatus of claim 17 further comprising a fluid-conducting tube that permits fluid outside of the vessel to be transmitted into an interior region of the vessel and, in turn, into the electrode compartments.