Purification of carbon dioxide from a mixture of gases

• US 9,222,179 B2
• Filed: 06/21/2013
• Issued: 12/29/2015
• Est. Priority Date: 03/19/2010
• Status: Active Grant

• Current Assignee: Avantium Knowledge Centre B.V. (Avantium NV)
• Original Assignee: Liquid Light, Inc. (Avantium NV)
• Inventors: Teamey, Kyle, Cole, Emily Barton, Sivasankar, Narayanappa, Bocarsly, Andrew B.
• Primary Examiner(s): Wong, Edna
• Application Number:
  US13/923,940
• Publication Number:
  US 20130292262A1
• Time in Patent Office: 921 Days
• Field of Search: 205/413, 205/440, 205/443, 205/464, 205/555
• US Class Current: 1/1
• CPC Class Codes: B01D 2256/22 Carbon dioxide
• CPC Class Codes: B01D 53/326 in electrochemical cells
• CPC Class Codes: C25B 1/22 Inorganic acids

Abstract

A method for purification of carbon dioxide from a mixture of gases is disclosed. The method generally includes steps (A) and (B). Step (A) may bubble the gases into a solution of an electrolyte and a catalyst in an electrochemical cell. The electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode generally reduces the carbon dioxide into one or more compounds. The anode may oxidize at least one of the compounds into the carbon dioxide. Step (B) may separate the carbon dioxide from the solution.

Claims

1. A method for purification of carbon dioxide from a mixture of gases including carbon dioxide, comprising the steps of:

(A) bubbling said mixture of gases including carbon dioxide into a solution of an electrolyte and a catalyst in an electrochemical cell, wherein (i) said electrochemical cell comprises an anode in a first cell compartment and a cathode in a second cell compartment, (ii) said cathode reducing said carbon dioxide into at least one compound and (iii) said anode oxidizing said at least one compound into said carbon dioxide; and

(B) separating said carbon dioxide from said solution.

2. The method according to claim 1, wherein said cathode includes at least one of Al, Au, Ag, C, Cd, Co, Cr, Cu, Cu alloys, Ga, Hg, In, Mo, Nb, Ni, Ni alloys, Ni—

Fe alloys, Sn, Sn alloys, Ti, V, W, Zn, elgiloy, Nichrome, austenitic steel, duplex steel, ferritic steel, martensitic steel, stainless steel, degenerately doped p-Si, degenerately doped p-Si;

As or degenerately doped p-Si;

B.

3. The method according to claim 1, wherein said electrolyte is at least one of Na₂SO₄, KCl, NaNO₃, NaCl, NaF, NaClO₄, KClO₄, K₂SiO₃, CaCl₂, a H cation, a Li cation, a Na cation, a K cation, a Rb cation, a Cs cation, a Ca cation, an ammonium cation, an alkylammonium cation, a F anion, a Cl anion, a Br anion, an I anion, an At anion, an alkyl amine, borates, carbonates, nitrites, nitrates, phosphates, polyphosphates, perchlorates, silicates, sulfates, or a tetraalkyl ammonium salt.

4. The method according to claim 1, wherein said catalyst is at least one of amino-thiazole, aromatic heterocyclic amines with an aromatic 5-member heterocyclic ring, aromatic heterocyclic amines with 6-member heterocyclic ring, azoles, benzimidazole, bipyridines, furan, imidazoles, imidazole related species with at least one five-member ring, indoles, pyridines, pyridine related species with at least one six-member ring, pyrrole, thiophene or thiazoles.

5. The method according to claim 1, wherein an energy consumed is less than 500,000 watt hours per ton of carbon dioxide.

6. The method according to claim 1, wherein approximately no additional water is consumed after said solution has been established in said electrochemical cell.

7. The method according to claim 1, wherein said at least one compound is oxalate, oxalate salts, organic acids, oxalic acid, glyoxylic acid or glyoxal.