Steam generating slurry gasifier for the catalytic gasification of a carbonaceous feedstock

• US 9,234,149 B2
• Filed: 03/04/2015
• Issued: 01/12/2016
• Est. Priority Date: 12/28/2007
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Lau, Francis S., Robinson, Earl T.
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): Woodard, Joye L
• Application Number:
  US14/637,578
• Publication Number:
  US 20150175914A1
• Time in Patent Office: 314 Days
• Field of Search: 482/02, 482/06, 48/73, 48/87, 48D/IG.2, 48D/IG.7
• US Class Current: 1/1
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/094 Char
• CPC Class Codes: C10J 2300/0943 Coke
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/0973 Water
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 2300/1823 for synthesis gas
• CPC Class Codes: C10J 2300/1846 Partial oxidation, i.e. injection of air or oxygen only
• CPC Class Codes: C10J 2300/1853 Steam reforming, i.e. injection of steam only
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 3/463 in stationary fluidised beds
• CPC Class Codes: C10J 3/721 Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10J 3/82 Gas withdrawal means
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/101 with water only
• CPC Class Codes: C10K 1/122 containing only carbonates, bicarbonates, hydroxides or oxides of alkali-metals (including Mg)
• CPC Class Codes: C10K 1/143 containing amino groups
• CPC Class Codes: C10K 1/16 with non-aqueous liquids
• CPC Class Codes: C10K 1/165 : at temperatures below zero degrees Celsius
• CPC Class Codes: C10K 3/02 : by catalytic treatment
• CPC Class Codes: C10L 3/08 : Production of synthetic natural gas
• CPC Class Codes: C10L 3/102 : of acid contaminants

Abstract

Steam generating gasification reactors for providing high-pressure and high-temperature steam for catalytic gasification of a carbonaceous feedstock can be based on oxygen blown gasification reactors adapted for processing a slurry feedstock comprising at least 40% water. The exhaust from the slurry gasifier comprises at least steam, carbon monoxide and hydrogen. The slurry composition and the oxygen to fuel ratio can be varied to control the ratio of carbonaceous gases in the generator exhaust. By directing substantially all of exhaust gases produced from the slurry gasification reactor through the catalytic gasifier and subsequent gas separation and sequestration processes, a greatly higher energy efficiency and decreased carbon footprint can be realized. The subsequent gas separation process produces a syngas stream which is recycled and directed into the slurry gasifier.

Claims

1. A process for converting a carbonaceous material into a first plurality of gases comprising methane, hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia and other higher hydrocarbons, the process comprising the steps of:

(a) providing a gasifier apparatus comprising;

(1) a fluidized bed gasifier configured to receive a catalyzed carbonaceous feedstock and a second plurality of gases comprising steam, hydrogen, carbon monoxide, and carbon dioxide, and to exhaust the first plurality of gases; and

(2) a slurry gasifier configured to supply to the fluidized bed gasifier the second plurality of gases, wherein the slurry gasifier comprises;

a gasifier chamber;

a syngas conduit in communication with a syngas source and the gasifier chamber for supplying a syngas to the gasifier chamber;

an oxygen gas conduit for supplying enriched oxygen gas as a reactant to the gasifier chamber;

a slurry conduit for supplying an aqueous carbonaceous slurry as a reactant to the gasifier chamber; and

a heated gas conduit for exhausting the second plurality of gases;

wherein the heated gas conduit of the slurry gasifier is in communication with the fluidized bed gasifier for supplying the second plurality of gases from the slurry gasifier to the fluidized bed gasifier;

(b) supplying a particulate composition comprising the carbonaceous material and a gasification catalyst to the fluidized bed gasifier, wherein the gasification catalyst, in the presence of steam and under suitable temperature and pressure, exhibits gasification activity whereby the first plurality of gases is formed;

(c) supplying an aqueous carbonaceous slurry via the slurry conduit, an enriched oxygen gas via the oxygen gas conduit, and a syngas via the syngas conduit, to the slurry gasifier;

(d) reacting the aqueous carbonaceous slurry in the slurry gasifier in the presence of oxygen and under suitable temperature and pressure so as to generate the second plurality of gases;

(e) introducing the second plurality of gases into the fluidized bed gasifier via the heated gas conduit;

(f) reacting the particulate composition in the fluidized bed gasifier in the presence of the second plurality of gases, at a temperature of at least about 450°

C. to about 750°

C. and a pressure of at least about 50 psig to about 1000 psig, to form the first plurality of gases; and

(g) at least partially separating the first plurality of gases to produce a recycle syngas stream;

(h) supplying the recycle syngas stream to the gasifier chamber of the slurry gasifier as the syngas;

wherein;

(i) the gasification catalyst comprises a source of at least one alkali metal and is present in an amount sufficient to provide, in the particulate composition, a ratio of alkali metal atoms to carbon atoms ranging from about 0.01 to about 0.08; and

(ii) the aqueous carbonaceous slurry comprises a mixture of carbonaceous material and water at a weight ratio ranging from about 5;

95 to about 40;

60.

2. The process according to claim 1, wherein the alkali metal comprises potassium and/or sodium.

3. The process according to claim 1, wherein the steam and other of the second plurality of gases are generated at a molar ratio ranging from about 70:

30 to about 30;

70 (steam;

other gases).

4. The process according to claim 1, wherein the carbon dioxide in the first plurality of gases is recovered.

5. The process according to claim 4, wherein the carbon dioxide is generated in step (d), step (f) or both.

6. The process according to claim 4, wherein the carbon dioxide is generated in both step (d) and step (f).

7. The process according to claim 1, wherein the operating temperature and pressure of the slurry gasifier is greater than the fluidized bed gasifier.

8. The process according to claim 1, wherein the particulate composition is prepared by crushing a carbonaceous material, fines are generated in the crushing of the carbonaceous material, and the aqueous carbonaceous slurry comprises the fines.

9. The process according to claim 1, wherein a char is formed in step (f), and the char is removed from the fluidized bed gasifier and sent to a catalyst recovery and recycle process.

10. The process according to claim 9, wherein the aqueous carbonaceous slurry comprises char from the catalyst recovery and recycle process that is substantially free of gasification catalyst.